Why the catalytic and optical properties of nanomaterial are different from bulk material

Answers

Answer 1

Answer:

The material properties of nanostructures are different from the bulk due to the high surface area over volume ratio and possible appearance of quantum effects at the nanoscale. ... Yu; they found that the structural distortions on the quantum dots depend both on the kind of dopant and on the size of the dots.

Explanation:

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Related Questions

Compound X has the same molecular formula as butane but has a different boiling point and melting point. What can be concluded about Compound X?


A It is a four-carbon alkene or alkyne.

B It is an optical isomer of butane.

C It is a geometric isomer of butane.

D It is a structural isomer of butane.
need this for gradpoint:)

Answers

Answer:

d

Explanation:

A sample of Br2(g) takes 12.0 min to effuse through a membrane. How long would it take the same number of moles of Ar(g) to effuse through the same membrane

Answers

Answer:

6 mins

Explanation:

The time taken for Ar to effuse can be obtained as follow:

Time for Br₂ (t₁) = 12 mins

Molar mass of Br₂ (M₁) = 2 × 80 = 160 g/mol

Molar mass of Ar (M₂) = 40 g/mol

Time for Ar (t₂) =?

t₂/t₁= √(M₂/M₁)

t₂ / 12 = √(40/160)

Cross multiply

t₂ = 12 × √(40/160)

t₂ = 12 × 0.5

t₂ = 6 mins

Therefore, it will take 6 mins for the same amount of Ar to effused out.

The volume of an ideal gas is held constant. Determine the ratio P2/P1 of the final pressure to the initial pressure when the temperature of the gas rises (a) from 46 to 92 K and (b) from 35.4 to 69.0 oC.

Answers

Answer:

A. P₂ / P₁ = 2

B. P₂ / P₁ = 1.1

Explanation:

A. Determination of the ratio P₂/P₁

Volume = constant

Initial temperature (T₁) = 46 K

Final temperature (T₂) = 92 K

Final pressure /Initial pressure (P₂/P₁) =?

P₁/T₁ = P₂/T₂

P₁/46 = P₂/92

Cross multiply

46 × P₂ = P₁ × 92

Divide both side by P₁

46 × P₂ / P₁ = 92

Divide both side by 46

P₂ / P₁ = 92 / 46

P₂ / P₁ = 2

B. Determination of the ratio P₂/P₁

Volume = constant

Initial temperature (T₁) = 35.4 °C = 35.4 + 273 = 308.4 K

Final temperature (T₂) = 69.0 °C = 69 + 273 = 342 K

Final pressure /Initial pressure (P₂/P₁) =?

P₁/T₁ = P₂/T₂

P₁/308.4 = P₂/342

Cross multiply

308.4 × P₂ = P₁ × 342

Divide both side by P₁

308.4 × P₂ / P₁ = 342

Divide both side by 308.4

P₂ / P₁ = 342 / 308.4

P₂ / P₁ = 1.1

Zn-64 = 48.63%
Zn-66 = 27.90%
Zn-67 = 4.10%
Zn-68 = 18.75%
Zn-70 = .62%
Calculate the average atomic mass/given their percent abundance

Answers

Answer:

A = 65.46 u

Explanation:

Given that,

The composition of zinc is as follows :

Zn-64 = 48.63%

Zn-66 = 27.90%

Zn-67 = 4.10%

Zn-68 = 18.75%

Zn-70 = .62%

We need to find the  average atomic mass of the given element. It can be solved as follows :

[tex]A=\dfrac{48.63\times 64+27.90\times 66+4.1\times 67+18.75\times 68+0.62\times 70}{100}\\A=65.46\ u[/tex]

So, the average atomic mass of zinc is 65.46 u.

Predict the products of each reaction, and whether the solution at equilibrium will be acidic, basic, or neutral.1. P4O10 + 6H2O (l)---->2. Na2O + H2O(l) ------>3. N2O5 + 3H2O (l)------>

Answers

Answer:

For 1: The product is phosphoric acid and the solution is acidic in nature.

For 2: The product is sodium hydroxide and the solution is basic in nature.

For 3: The product is nitric acid and the solution is acidic in nature.

Explanation:

For the given options:

(1): When diphosphorus pentoxide reacts with water, it leads to the formation of phosphoric acid, which makes the solution acidic in nature.

The chemical equation for the reaction follows:

[tex]P_4O_{10}+6H_2O(l)\rightarrow 4H_3PO_4(aq)[/tex]

(2): When disodium oxide reacts with water, it leads to the formation of sodium hydroxide, which makes the solution basic in nature.

The chemical equation for the reaction follows:

[tex]Na_2O+H_2O(l)\rightarrow 2NaOH(aq)[/tex]

(3): When dinitrogen pentoxide reacts with water, it leads to the formation of nitric acid, which makes the solution acidic in nature.

The chemical equation for the reaction follows:

[tex]3N_2O_5+3H_2O(l)\rightarrow 6HNO_3(aq)[/tex]

A 15.4 mL aliquot of 0.204 MH3PO4(aq) is to be titrated with 0.17 MNaOH(aq). What volume (mL) of base will it take to reach the equivalence point?

Answers

Answer:

55.44L of the 0.17M NaOH are required

Explanation:

Phosphoric acid, H3PO4, reacts with NaOH as follows:

H3PO4 + 3NaOH → Na3PO4 + 3H2O

Where 1 mole of H3PO4 reacts with 3 moles of NaOH

To solve this question we need to find the moles of H3PO4 in the aliquot. Using the balanced equation we can find the moles of NaOH and its volume with the concentration (0.17M) as follows:

Moles H3PO4:

15.4mL = 0.0154L * (0.204mol/L) = 0.00314 moles H3PO4

Moles NaOH:

0.00314 moles H3PO4 * (3mol NaOH / 1mol H3PO4) = 0.009425moles NaOH

Volume NaOH:

0.009425moles NaOH * (1L/0.17moles NaOH) = 0.05544L 0.17M NaOH =

55.44L of the 0.17M NaOH are required

An element of the environment that causes a population the decrease is

A) the birthrate minus the death rate

B) the carrying capacity

C) a limiting factor

D) the death rate

Answers

It’s option c. When resources are limited competition will increase => one will survive while other dies=> population will decline.

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BLACKSHARK

If 2.18 g of sodium peroxide (Na2O2) react with water to produce sodium hydroxide abs oxygen, how many liters of oxygen will be produced at 17.7 Celsius abs 726 torr?

Answers

Answer:

0.350 L

Explanation:

2Na₂O₂ + 2H₂O → 4NaOH + O₂

First we convert 2.18 g of Na₂O₂ into moles, using its molar mass:

2.18 g ÷ 78 g/mol = 0.0279 mol Na₂O₂

Then we convert 0.0279 moles of Na₂O₂ into moles of O₂, using the stoichiometric coefficients of the reaction:

0.0279 mol Na₂O₂ * [tex]\frac{1molO_2}{2molNa_2O_2}[/tex] = 0.0140 mol O₂

Finally we use the PV=nRT formula to calculate the volume of oxygen produced:

P = 726 torrV = ?n = 0.0140 molR = 62.36 torr·L·mol⁻¹·K⁻¹T = 17.7 °C ⇒ 17.7 + 273.2 = 290.9 K

Inputting the data:

726 torr * V = 0.0140 mol * 62.36 torr·L·mol⁻¹·K⁻¹ * 290.9 KV = 0.350 L

After standardizing a NaOH solution, you use it to titrate an HCl solution known to have a concentration of 0.203 M. You perform five titrations and obtain the following results: 0.210, 0.204, 0.201, 0.202, and 0.197 M. a) What is the mean

Answers

Answer:

0.203 is the mean of the concentration of the HCl solution

Explanation:

You have 5 concentrations. The most appropiate result is the mean of those results. The mean is a statistical defined as the sum of each result divided by the total amount of results. For the results of the problem, the mean is:

0.210 + 0.204 + 0.201 + 0.202 + 0.197 = 1.014 / 5 =

0.203 is the mean of the concentration of the HCl solution

Draw the Lewis structure for BrCl3. What are the approximate bond angles about the central atom?
a. 60°.
b. 90°.
c. 109°.
d. 120°.
e. 180°.

Answers

Answer:

Explanation:

BrCl₃ is an interhalogen compound with a hybridization of sp³d. The approximate bond angles can be predicted from the structure (attached below). Although, the lewis structure might be predicted to be trigonal bipyramidal from the structure, it is however a T-shaped geometry because of it's two lone pairs.

Also, from the structure attached, it can be predicted that the approximate bond angles about the central atom is 120° (360 ÷ 3) since each of the three chlorine atoms is equally spaced about the central atom.

The Lewis structure for BrCl₃ is attached to the image below. The bond angles around the central atom, bromine (Br), are 90 degrees between the bromine and each chlorine atom. Therefore, option B is correct.

A Lewis structure, also known as an electron-dot structure or Lewis dot structure is a diagram that represents the valence electrons of an atom or molecule.

Bromine (Br) is in Group 7A and has 7 valence electrons, while each chlorine (Cl) atom in Group 7A also has 7 valence electrons.

Br: 1 atom × 7 valence electrons = 7 valence electrons

Cl: 3 atoms × 7 valence electrons = 21 valence electrons

Total valence electrons = 7 + 21 = 28

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Enough of a monoprotic acid is dissolved in water to produce a 1.211.21 M solution. The pH of the resulting solution is 2.882.88 . Calculate the Ka for the acid.

Answers

Answer:

1.44 × 10⁻⁶

Explanation:

Step 1: Given data

Concentration of the acid (Ca): 1.21 MpH of the solution: 2.88

Step 2: Calculate the concentration of H⁺ ions

We will use the definition of pH.

pH = -log [H⁺]

[H⁺] = antilog -pH = antilog -2.88 = 1.32 × 10⁻³ M

Step 3: Calculate the acid dissociation constant of the acid (Ka)

For a weak monoprotic acid, we will use the following expression.

Ka = [H⁺]²/Ca

Ka = (1.32 × 10⁻³)²/1.21 = 1.44 × 10⁻⁶

(S)-CH3CH(N3)CH2CH2CH3 can be synthesized by an SN2 reaction. Draw the structures of the alkyl chloride and nucleophile that will give this compound in highest yield.

Answers

Answer:

See explanation and image attached

Explanation:

Let us recall that the reaction in question is expected to happen by SN2 mechanism. This is because, the reaction occurs at secondary carbon atom and the attacking nucleophile (N3^-) is a good nucleophile.

The reaction occurs via a backside attack of the N3^- ion on (R)-2-chloropentane. This backside attack leads to inversion of configuration at the reaction centre to yield (S)-CH3CH(N3)CH2CH2CH3.

The images of the alkyl halide and nucleophile are shown in the image attached to this answer.

What is the gravitational potential energy of a 1500-kg truck resting on top of a 550-m hill on earth?( earth’s gravitational pull is 9.8m/s2).

Answers

Answer:

E = 8085 kJ

Explanation:

Given that,

The mass of a truck, m = 1500 kg

Height, h = 550 m

We need to find the gravitational potential energy of the truck. It can be calculated as follows :

[tex]E=mgh[/tex]

Put all the values,

[tex]E=1500\times 9.8\times 550\\\\E=8085000\ J\\\\or\\\\E=8085\ kJ[/tex]

So, the gravitational potential energy is 8085 kJ.

Vocabulary: dipole, dipole-dipole force, dipole-induced dipole force, electronegativity, intermolecular force, ionic bond, London dispersion force, molecule, nonpolar, nonpolar covalent bond, partial charges, polar, polar covalent bond, valence electron Prior Knowledge Questions (Do these BEFORE using the Gizmo.) 1. A big bully is having a tug-of-war with a small child. There is a ball attached to the middle of the rope. Toward whom will the ball move

Answers

Answer:

Towards the big bully

Explanation:

If a big bully and a small child are involved in a thug of war, it is clear that the bully is stronger than the child and he/she will pull the rope used in the thug of war with a greater force.

By so doing, the ball attached at the centre of the rope will naturally be drawn towards the stronger bully.

A comparison analysis subjects a suspect specimen and a control specimen to the same tests and examinations for the ultimate purpose of determining: whether or not they have a common origin if they are identical in chemical composition if the same person handled them if they are alike in molecular structure All of these

Answers

Answer:

whether or not they have a common origin

Explanation:

During the scientific investigation of a crime, a forensic scientist might be required to perform a comparison analysis. A comparison analysis is an examination where specific physical properties are obtained from a suspect specimen and a standard which are then compared to identify their common origin. This type of analysis is important for it helps in narrowing down the crime to a particular person. It also enables accurate delivery of justice.

the Wavelength of a microwave is______than the wavelength of visible light
(Please help)

Answers

Answer:

The wavelength of a microwave is LONGER than the wavelength if visible light.

PLEASE HELP!!!!

Which of the following lists describes characteristics of an acid? (3 points)
Bitter taste, high pH, and caustic
Sour taste, low pH, and dissolves metals
Sour taste, high pH, and dissolves metals
Slippery, low pH, and caustic

Answers

Acids have sour taste, low pH and dissolves metals.

The list that describes the characteristics of an acid is that it has sour taste, low pH, and dissolves metals.

Characteristics of an acid

An acid is a chemical substance that has the ability to donate hydrogen ions when involved in a chemical reaction.

The following are the characteristics or features of an acid:

They have a sour taste when tasted.

When measured using a pH scale it is less than 7(low pH).

They react with active metals to yield hydrogen gas.

Therefore, the list that describes the characteristics of an acid is that it has sour taste, low pH, and dissolves metals.

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What is the law of multiple proportions?
A. The proportion of elements to compounds is constant.
B. All elements are found in equal proportions in nature.
C. Different compounds may contain the same elements but may have different ratios of those elements.
D. All compounds contain the same elements in the same proportions.

Answers

Answer:

a. the proportion of elements to compounds is constant.

I don’t want to fail help
I need correct answer if u don’t know I will report

When the researcher compiled information which research method did they most likely utilize?

a) documentary
b) survey
c) participant observation
d) case study

Answers

Answer:

a

Explanation:

documentary is best researcher!.


A cation is a

negative electrode.
negatively charged ion.
positively charged ion.
positive electrode

Answers

Answer:

Each electrode attracts ions that are of the opposite charge. Positively charged ions, or cations, move toward the electron-providing cathode, which is negative; negatively charged ions, or anions, move toward the positive anode.

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Write the symbol for every chemical element that has atomic number less than 14 and atomic mass greater than 23.2 u.

Answers

Answer:

8 oxygen. 9 flourine. 10. Neon. 5 Boron

A physical chemist measures the temperature inside a vacuum chamber. Here is the result.

T= - 35.903°C

Convert T to SI units.

Answers

This is an acronym of the word Systeme International in French. Its International System of Units (SI) is a metric system that would be universally acknowledged as a measurement standard, and the further discussion can be defined as follows:

SI units play an important function in research and innovation in science and technology. In this, the temperature will be measure in the kelvin.

Conversion [tex]^{\circ} \ to \ K[/tex]:

let,

[tex]\to 0^{\circ}\ C + 273.15 = 273.15\ K\\\\[/tex]

So,

[tex]\to -35.903+273.15=237.247\ K[/tex]

Therefore, the final answer is "237.247".

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Ammonium phosphate is an important ingredient in many solid fertilizers. It can be made by reacting aqueous phosphoric acid with liquid ammonia. Calculate the moles of phosphoric acid needed to produce 1.80 mol of ammonium phosphate. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits.

Answers

Answer:

Explanation:

The reaction is

H3Po4+3NH3\to→ (NH4)3PO4

Given,7.10g NH3=7.10g/molar mass of NH3

=7.10g/(17.031g/mol)

=0.416mol

From the reaction

3 mol ammonia reacted and produced 1 mole of ammoniam phosphate

So,One mole ammonia reacted and produced 1/ 3 mole ammonium phosphate.

And Also,0.416 mole ammonium reacted and produced (1/3)0.416=0.138 mole ammonium phosphate.

Hence 0.138mole=0.138mole*149.08 g/mole

               =20.573gm ammonium phosphate produced.

Hence 20.573g of ammonium phosphate is produced by the reaction of 7.10 g of ammonia.

How much energy is required to melt 2 kg of gold? Use the table below and this equation.
a. 125.6 kJ
b. 1729 kJ
c. 10.4 kJ
d. 3440kJ

Answers

The equation for the energy required to melt 2 kg of gold is 3440 kJ.

What is energy?

Energy is the ability to do work or cause change. It is an essential part of everyday life and is present in many forms, such as thermal energy, electrical energy, chemical energy, and mechanical energy. Energy can be converted from one form to another in order to do work.


The equation for calculating the energy required to melt a certain mass of material is Q = m x Lf, where Q is the energy required (in joules), m is the mass of the material (in kilograms), and Lf is the latent heat of fusion (in joules per kilogram).
Using the table below, we can see that the latent heat of fusion for gold is 1760 kJ/kg. Therefore, the equation for the energy required to melt 2 kg of gold is: Q = 2 kg x 1760 kJ/kg = 3440 kJ.

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Br NaOCH2CH3 + CH3CH-OH + NaBr CH3 CH3 a. Identify the mechanism of the reaction. b. Suggest steps for the mechanism of this reaction. Use curved arrows to show the electron motions. c. How would the rate be affected if the concentration of sodium ethoxide, NaOCH CH3 is increased? Justify your answer.​

Answers

Answer:

a) The mechanism of the reaction is the Elimination Bimolecular or E2.

b) Steps for the mechanism of this reaction is given as follows,

c) Reaction rate = K[Organic compound][[tex]NaoCH_{2} CH_{3}[/tex]].  

Explanation:

a) The mechanism of the reaction is the Elimination Bimolecular or E2.

c) This is an E2 reaction, so it depends on the concentration of both substrate and reactant. If we increase the concentration of [tex]NaoCH_{2} CH_{3}[/tex], the reaction rate will be increased.

Reaction rate = K[Organic compound][[tex]NaoCH_{2} CH_{3}[/tex]].  

b) Steps for the mechanism of this reaction is given as follows,

Match the description with the type of precipitation being described.
1. Its formation requires very strong updrafts
2. Its formation requires falling through a layer of above freezing air
3. Precipitation from cumuliform clouds is typically of this nature
4. Precipitation from stratus clouds is typically of this nature
Options:
a. Hail
b. Drizzle
c. Shower
d. Freezing Rain

Answers

Answer:

1. Its formation requires very strong updrafts = a. Hail

2. Its formation requires falling through a layer of above-freezing air = d. Freezing Rain

3. Precipitation from cumuliform clouds is typically of this nature = c. Shower

4. Precipitation from stratus clouds is typically of this nature = Drizzle

Explanation:

Hail formation requires very strong updrafts, these updrafts are the upward moving air created in a thunderstorm. This period of noticeable thunderstorms creates hails.

Freezing rain requires the presence of warm air, it requires falling through a layer of above-freezing air to the colder air below to produce an ice coating on anything it drops on.

Showers are produced by cumuliform clouds which look like cotton balls. Since cumuliform clouds precipitate too, these clouds can have fluctuating rain in a day in the form of showers.

Drizzle which raises low visibility is considered a type of liquid precipitation since it also falls from a cloud. Drizzle which is obviously smaller in diameter when compared to that of raindrops, however, is common with stratus clouds.

It takes to break a carbon-hydrogen single bond. Calculate the maximum wavelength of light for which a carbon-hydrogen single bond could be broken by

Answers

The question is incomplete, the complete question is;

It takes 412. KJ/mol to break a carbon-hydrogen single bond. Calculate the maximum wavelength of light for which a carbon-hydrogen single bond could be broken by absorbing a single photon. Round your answer to significant digits.

Answer:

289 nm

Explanation:

The energy of the photon = 412 × 10^3/6.02 × 10^23 = 6.84 × 10^-19 J

From;

E = hc/λ

h= Plank's constant

c= speed of light

λ = wavelength

λ = hc/E

λ = 6.6 × 10^-34 × 3 × 10^8/6.84 × 10^-19

λ = 2.89 × 10^-7 m

λ = 289 nm

4.005 X 74 X 0.007 = 2.10049

Answers

Answer:

2.07459

Explanation:

this is the correct answer.

Calculate the volume in liters of a 1.60 mol/L sodium nitrate solution that contains of sodium nitrate . Round your answer to significant digits.

Answers

Answer:

1.5L of NaNO3 must be present

Explanation:

That contains 200g of sodium nitrate. Round to 2 significant digits

To solve this question we need to convert the mass of NaNO3 to moles using its molar mass (85g/mol). With the moles and the molar concentration we can find the volume in liters of the solution:

Moles NaNO3:

200g * (1mol / 85g) = 2.353 moles NaNO3

Volume:

2.353 moles NaNO3 * (1L / 1.60moles) =

1.5L of NaNO3 must be present

How many grams of boiling water must be added to an insulated cup containing 19 grams of ice, at 0oC, to completely melt the ice

Answers

Answer:

1900grams of boiling water

Explanation:

0,c=19

100,c=19×100

1900grams

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Credit terms are terms for a.when payments for merchandise are to be made with cash. b.when the payments for merchandise are to be made. c.when the returns of merchandise are to be made. d.when inventory is purchased. how are hailstones formed it is a 10 mark question Which statement best describes John Lockes view of human nature Brink of tears All my points Rhonda started a business. Her business made $30,000 in profits the first year. Her annual profits have increased by an average of 5% each year since then.A) Write an iterative rule to model the sequence formed by the profits of Rhondas business each year. B) Use the rule to determine what the annual profits of Rhondas business can be predicted to be 15 years from the start of her business. Round your answer to the nearest dollar. Do not round until the end. Show your work Christina has a stamp collection she is very proud of. She buys a frame to display her favorite stamps. 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