Answer:
Slower
Explanation:
The reaction between alkyl halides and sodium iodide-in-acetone is an SN2 reaction. The rate of reaction depends on the concentration of the alkyl halide as well as the concentration of the sodium iodide. It is a bimolecular reaction.
This means that if the concentration of any of the reactants is halved, the rate of reaction decreases accordingly.
Therefore, if the iodide solution is half as concentrated, the reaction is observed to be slower in accordance with the rate law;
Rate = k[alkyl halide] [iodide]
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For groups 13 through 18, the number of valence electrons is equal to the group number
a. minus 10
b. minus the period number
c. plus 1
d. plus the period number
Answer:
a. minus 10
Explanation:
An element in group 13 = Boron ,valence electrons = 3 , therefore, valence electrons in group 13 = group no. -10
An element in group 18 = Neon, valence electrons = 8 , therefore, valence electrons in group 18 = group no. - 10
For groups 13 through 18, the number of valence electrons in an atom is equal to the group number minus 10. Therefore, option (A) is correct.
What is a valence electron?Valence electrons in an atom can be described as the electrons occupying the outer most electron shell of an atom while the electrons in the inner shell are core electrons. Lewis structures can be helpful to calculate the number of valence electrons.
Valence electrons can be filled in several electron shells as they are caused interaction between atoms and responsible for the formation of chemical bonds. Only valence electrons can contribute to the formation of a chemical bond and decide the reactivity of the element.
The general electronic configuration of group 13 is ns²np¹ has three valence electrons. It can be determined as group number - 10 = 13 - 10 = 3.
The general electronic configuration of group 18 is ns²np⁶ has eight valence electrons. It can be determined as group number - 10 = 18 - 10 = 8.
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Why the catalytic and optical properties of nanomaterial are different from bulk material
Answer:
The material properties of nanostructures are different from the bulk due to the high surface area over volume ratio and possible appearance of quantum effects at the nanoscale. ... Yu; they found that the structural distortions on the quantum dots depend both on the kind of dopant and on the size of the dots.
Explanation:
hope it helps
The majority of metals are found within
The majority of metals are found in ores.
But a few such as copper, gold, platinum, and silver frequently occur in the free state because they do not readily react with other elements.
Fill in the blanks with each titration term with its definition.
a. Solution of an unknown concentration that has another solution slowly added to it ________________
b. Process of slowly adding a solution to react with another solution and determine the concentration of one of the solutions based on the reaction between them ______________
c. A reagent added to the analyte solution that changes color when the reaction is complete ______________
d. Glassware that allows a solution to be precisely and slowly added to another solution _____________
e. Solution of known concentration that is slowly added to a solution of unknown concentration ________________
f. When the required amount of one solution has been added to the second solution to complete the reaction ____________
Answer:
Fill in the blanks with each titration term with its definition.
a. Solution of an unknown concentration that has another solution slowly added to it ________________
b. Process of slowly adding a solution to react with another solution and determine the concentration of one of the solutions based on the reaction between them ______________
c. A reagent added to the analyte solution that changes color when the reaction is complete ______________
d. Glassware that allows a solution to be precisely and slowly added to another solution _____________
e. Solution of known concentration that is slowly added to a solution of unknown concentration ________________
f. When the required amount of one solution has been added to the second solution to complete the reaction ____________
Explanation:
a. Solution of an unknown concentration that has another solution slowly added to it is called analyte.
b. Process of slowly adding a solution to react with another solution and determine the concentration of one of the solutions based on the reaction between them is called titration.
c. A reagent added to the analyte solution that changes color when the reaction is complete is called an indicator.
d. Glassware that allows a solution to be precisely and slowly added to another solution is called a pipette.
e. Solution of known concentration that is slowly added to a solution of unknown concentration is called titrant.
f. When the required amount of one solution has been added to the second solution to complete the reaction is called neutralization.
Give your familiarity for following terms
1. roasting 2. smelting 4. zone refining 5. polling
Answer:
The roasting process is a delicate combination of art and science . Roasters are familiar with how the beans look and the smells Well, familiarity with the machine makes things much easier to predict, but the best way is to do many different tests .Well, familiarity with the machine makes things much easier to predict, but the best way is to do many different tests.Smelting is a process of applying heat to ore in order to extract a base metal. It is a form of extractive metallurgy. It is used to extract many metals from their ores, including silver, iron, copper, and other base metals.In zone refining, solutes are segregated at one end of the ingot in order to purify the remainder, or to concentrate the impurities. For example, in the preparation of a transistor or diode semiconductor, an ingot of germanium is first purified by zone refining. In zone refining, solutes are segregated at one end of the ingot in order to purify the remainder, or to concentrate the impurities. ... For example, in the preparation of a transistor or diode semiconductor, an ingot of germanium is first purified by zone refining.Polling is the process where the computer or controlling device waits for an external device to check for its readiness or state, often with low-level hardware. For example, when a printer is connected via a parallel port, the computer waits until the printer has received the next character.Explanation:
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Consider the balanced chemical equation below.
3 A ⟶ C + 4 D
How many moles of C would be produced if 7 moles of A were used?
Answer:
2.33 mol C
Explanation:
Step 1: Write the balanced generic chemical equation
3 A ⟶ C + 4 D
Step 2: Establish the appropriate molar ratio
According to the balanced equation, the molar ratio of A to C is 3:1.
Step 3: Calculate the number of moles of C produced from 7 moles of A
We will use the previously established molar ratio.
7 mol A × 1 mol C/3 mol A = 2.33 mol C
Question 5: Energy Sources (12 points)
A. There are many ways to produce electricity. List two energy sources that generate electricity via a chemical reaction, and explain what kind of reaction each uses. (6 points)
B. Ethane is a common component of energy sources. Write the chemical formula for ethane. (2 points)
C. Write and balance the chemical equation for the combustion reaction of ethane. (4 points)
Answer:
See explanation
Explanation:
It is possible to generate electricity through a chemical reaction in two ways;
I) use of a voltaic cell where spontaneous chemical processes produce electrical energy.
ii) use of an electrolytic cell where non spontaneous chemical processes produce electrical energy.
The chemical formula of ethane is C2H6
The balanced chemical equation for the combustion of ethane is as follows;
C2H6 + 7/2 O2 ------> 2CO2 + 3H2O
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How many molecules in each sample?
64.7 g N2
83 g CCl4
19 g C6H12O6
Answer:
1.39x10²⁴ molecules N₂.25x10²³ molecules CCl₄6.38x10²² molecules C₆H₁₂O₆Explanation:
First we convert the given masses into moles, using the compounds' respective molar mass:
64.7 g N₂ ÷ 28 g/mol = 2.31 mol N₂83 g CCl₄ ÷ 153.82 g/mol = 0.540 mol CCl₄19 g C₆H₁₂O₆ ÷ 180 g/mol = 0.106 mol C₆H₁₂O₆Then we multiply each amount by Avogadro's number, to calculate the number of molecules:
2.31 mol N₂ * 6.023x10²³ molecules/mol = 1.39x10²⁴ molecules0.540 mol CCl₄ * 6.023x10²³ molecules/mol = 3.25x10²³ molecules0.106 mol C₆H₁₂O₆ * 6.023x10²³ molecules/mol = 6.38x10²² moleculesLiquid ethyl mercaptan, C2H6S, has a density of 0.84 g/mL. Assuming that the combustion of this compound produces only CO2 , H2O, and SO2 , what masses of each of these three products would be produced in the combustion of 3.15 mL of ethyl mercaptan
Answer:
Mass CO2 = 3.75 grams
Mass H2O = 2.30 grams
Mass SO2 = 2.73 grams
Explanation:
Step 1: Data given
Density of Liquid ethyl mercaptan, C2H6S = 0.84 g/mL
Volume of ethyl mercaptan = 3.15 mL
Step 2: The reaction
2C2H6S + 9O2 → 4CO2 + 6H2O + 2SO2
Step 3: Calculate mass of ethyl mercaptan
Mass = Volume * density
Mass ethyl mercaptan = 3.15 mL * 0.84 g/mL
Mass ethyl mercaptan = 2.646 grams
Step 4: Calculate moles ethyl mercaptan
Moles = mass / molar mass
Moles ethyl mercaptan = 2.646 grams / 62.13 g/mol
Moles ethyl mercaptan = 0.04259 moles
Step 5: Calculate moles of other products
For 2 moles ethyl mercaptan we need 9 moles O2 to produce 4 moles CO2, 6 moles H2O and 2 moles SO2
For 0.04259 moles we need 0.1917 moles O2 to produce:
2*0.04259 = 0.08518 moles CO2
3*0.04259 = 0.1278 moles H2O
1*0.04259 = 0.04259 moles SO2
Step 6: Calculate mass produced
Mass = moles * molar mass
Mass CO2 = 0.08518 moles * 44.01 g/mol
Mass CO2 = 3.75 grams
Mass H2O = 0.1278 moles * 18.02 g/mol
Mass H2O = 2.30 grams
Mass SO2 = 0.04259 moles * 64.07 g/mol
Mass SO2 = 2.73 grams
The following statements either define or are closely related to the terms periodic law, period, or group. Match the terms to the appropriate statements.1. This is a vertical arrangement of elements in the periodic table. 2. This is a horizontal arrangement of elements in the periodic table. 3. The properties of the elements repeat in a regular way as the atomic numbers increase. 4. Element 19 begins this arrangement in the periodic table 5. The chemical properties of elements 12, 20, and 38 demonstrate this principle.
Answer:
Please find the complete solution in attached file.
Explanation:
Periodic law is the the properties of the elements that repeat in a regular way as the atomic numbers increase.
What is periodic table?Periodic chart organized collection of all chemical elements arranged roughly according to increasing atomic weight. The periodic recurrence of several features in the elements was originally identified by Dmitry I. Mendeleyev in 1869.
1. This is a vertical arrangement of elements in the periodic table group
2. This is a horizontal arrangement of elements in the periodic table period
3. The properties of the elements repeat in a regular way as the atomic numbers increase periodic law
4. Element 19 begins this arrangement in the periodic table period
5. The chemical properties of elements 12, 20, and 38 demonstrate this principle. periodic law
Therefore, periodic law is the the properties of the elements that repeat in a regular way as the atomic numbers increase.
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A Bronsted-Lowry acid is defined as a substance that ________. A Bronsted-Lowry acid is defined as a substance that ________. increases Ka when placed in H2O increases [OH-] when placed in H2O acts as a proton donor acts as a proton acceptor decreases [H ] when placed in H2O
Answer: A Bronsted-Lowry acid is defined as a substance that acts as a proton donor.
Explanation:
A substance that is able to donate a proton or hydrogen ion to another substance is a Bronsted-Lowry acid.
For example, HCl is a Bronsted-Lowry acid as it dissociates to give a hydrogen ion.
[tex]HCl \rightleftharpoons H^{+} + Cl^{-}[/tex]
Thus, we can conclude that a Bronsted-Lowry acid is defined as a substance that acts as a proton donor.
bio-chemisty of protain
Answer:
Protein biochemistry is the study of proteins. Protein biochemistry is a scientific field dedicated to the study of proteins, complex chains of amino acids which make up the building blocks of all living organisms.
Explanation:
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Copy and Pasted!
Answer:
Listen to what guy said on top.
Explanation:
polypeptide structures consisting of one or more long chains of amino acids residue.....
or my answer
What mass of NaOH would need to be dissolved in 500.0 mL of water to produce a solution with a pH of 12.40
Answer:
0.5024 g
Explanation:
Step 1: Calculate the concentration of H⁺
We will use the definition of pH.
pH = -log [H⁺]
[H⁺] = antilog -pH = antilog -12.40 = 3.981 × 10⁻¹³ M
Step 2: Calculate the concentration of OH⁻
We will use the ionic product of water expression.
[H⁺] [OH⁻] = 10⁻¹⁴
[OH⁻] = 10⁻¹⁴/[H⁺] = 10⁻¹⁴/3.981 × 10⁻¹³ = 0.02512 M
Step 3: Calculate the initial concentration of NaOH
NaOH is a strong base and the molar ratio of NaOH to OH⁻is 1:1. Thus, the initial concentration of NaOH is 1/1 × 0.02512 M = 0.02512 M.
Step 4: Calculate the moles of NaOH
We will use the definition of molarity.
M = moles of NaOH/liters of solution
moles of NaOH = M × liters of solution
moles of NaOH = 0.02512 mol/L × 0.5000 L = 0.01256 mol
Step 5: Calculate the mass of 0.01256 moles of NaOH
The molar mass of NaOH is 40.00 g/mol.
0.01256 mol × 40.00 g/mol = 0.5024 g
A scientist is conducting a Sanger's sequencing experiment to determine the number of polypeptides present in an oligomeric protein. The molecular weight of the protein is 18000 g/mol . After the reaction of 520 mg of the protein with 1‑fluoro‑2,4‑dinitrobenzene, the peptide bonds were hydrolyzed with an acid. As a result, the scientist obtained 39 mg of 2,4‑dinitrophenyl serine. What is the number of the polypeptide chains present in the oligomer?
Answer:
Depends on molecule.
Explanation:
The number of the polypeptide chains present in the oligomer depends on the molecule. Some molecules have more polypeptide chains whereas some of them have less polypeptide chains. For example, Hemoglobin is a oligomer that consists of four Polypeptide Chains, two of these Polypeptide Chains are α-globin molecules, each comprise of 141 amino acids, and the other two are (β, γ, δ, or ε) globins, each consist of 146 amino acids.
Whate the mass percentage of Sulphure in Na2so4 ?
Answer:
Water H2O + SULPHATE OXIDE
Which Group is in the second column of the periodic table?
O A. Noble gases
O B. Alkaline earth metals
O C. Alkali metals
O D. Halogens
Answer:
O B. Alkaline earth metals
Explanation:
Noble gases → 8th column.
Alkali metal → first column.
Halogen → 7th
Answer:
B. Alkaline earth metals
Explanation:
Alkaline-earth metals: The alkaline-earth metals make up Group 2 of the periodic table, from beryllium (Be) through radium (Ra). Each of these elements has two electrons in its outermost energy level, which makes the alkaline earths reactive enough that they're rarely found alone in nature. But they're not as reactive as the alkali metals. Their chemical reactions typically occur more slowly and produce less heat compared to the alkali metals.
The pKa of an acid can be determined through _____ (reduction, titration, filtration) with a strong base.
Gradually increase the volume of the base, stopping _____ (before, as, after) the equivalence point is reached.
The pKa of the acid is equal to the pH at the _____ (equivalence point, midway volume to the equivalence point, maximum volume).
Answer:
The pKa of an acid can be determined through titration with a strong base.
Gradually increase the volume of the base, stopping before the equivalence point is reached.
The pKa of the acid is equal to the pH at the midway volume to the equivalence point.
Explanation:
An acid HA dissociates in water as follows:
HA ⇄ H⁺ + A⁻ Ka
So, it produces hydrogen ions (H⁺) and a conjugate base (A⁻). The concentrations of HA, H⁺ and A⁻ at equilibrium determine the constant Ka. The pKa is calculated as:
pKa = -log Ka
The relationship between the pH of the solution and the pKa of the acid is described by the Henderson-Hasselbalch equation:
pH = pKa + log ([A⁻]/[HA])
The pKa can be experimentally determined by acid-base titration, in which a strong base is added to the acid solution. As the base is added, the acid HA is neutralized and the conjugate base A⁻ is formed. Thus, the concentration of the acid ([HA]) increases and the concentration of the conjugate base ([A⁻] decreases. The equivalence point is reached when the total amount of acid is neutralized with the added base. Before reaching the equivalence point, at the halfway point, half of the acid is neutralized and converted into the conjugate base. Thus:
[A-] = [HA] ⇒ log [A-]/[HA] = log 1 = 0 ⇒ pH = pKa
We measure the pH at that point and it is equal to the pKa of the acid.
Classify each cation as a weak acid or pH neutral (neither acidic nor basic).
a. Na+
b. Ni2+
c. NH4+
Answer:
a. Na+ is pH neutral
b. Ni2+ = weak acid
c. NH4+ = Weak acid
Explanation:
To know the nature of the cation we need to find the nature of its conjugate base.
If the conjugate base of the ion is a strong base, the ion is neutral.
If the conjugate base is a weak base, the ion is a weak acid:
a. Conjugate base Na+ = NaOH
Sodium hydroxide is a strong base:
Na+ is pH neutral
b. Conjugate base Ni²⁺: Ni(OH)2 is a weak base because is not completely soluble in water. That means:
Ni2+ = weak acid
c. Conjugate base NH4+: NH4OH. Weak base:
NH4+ = Weak acid
Calculate the percent dissociation of benzoic acid C6H5CO2H in a 1.3M aqueous solution of the stuff. You may find some useful data in the ALEKS Data resource. Round your answer to 2 significant digits.
Answer:
the percent dissociation is 0.69 %
Explanation:
Given the data in the question;
benzoic acid C₆H₅CO₂H
C₆H₅COOH[tex]_{(aq)[/tex] ⇔ C₆H₅COO[tex]_{-(aq)[/tex] + H[tex]_{+(aq)[/tex]
Ka = [C₆H₅COO- ][ H+ ] / [ C₆H₅COOH ] = 6.28 × 10⁻⁵
given that it dissociated in a 1.3 M aqueous solution.
so Initial concentration is;
[ C₆H₅COOH ] = 1.3
[C₆H₅COO- ] = 0
[ H+ ] = 0
Change in concentration
[ C₆H₅COOH ] = -x
[C₆H₅COO- ] = +x
[ H+ ] = +x
Concentration equilibrium
[ C₆H₅COOH ] = 1.3 - x
[C₆H₅COO- ] = +x
[ H+ ] = +x
Hence,
x² / ( 1.3 - x ) = 6.28 × 10⁻⁵
6.28 × 10⁻⁵( 1.3 - x ) = x²
8.164 × 10⁻⁵ - 6.28 × 10⁻⁵x = x²
x² + 6.28 × 10⁻⁵x - 8.164 × 10⁻⁵ = 0
solve for x
ax² + bx - c = 0
x = [ -b ± √( b² - 4ac ) ] / [ 2a ]
we substitute
x = [ -6.28 × 10⁻⁵ ± √( (6.28 × 10⁻⁵)² - (4 × 1 × -8.164 × 10⁻⁵ ) ) ] / [ 2 × 1 ]
x = [ -6.28 × 10⁻⁵ ± 0.01807 ] / [ 2]
x = [ -6.28 × 10⁻⁵ - 0.01807 ] / [ 2] or [ -6.28 × 10⁻⁵ + 0.01807 ] / [ 2]
x = -0.0090664 or 0.0090036
so x = 0.0090036
hence
[ H+ ] = +x = 0.0090036 M
[C₆H₅COO- ] = +x = 0.0090036 M
Initial concentration of [ C₆H₅COOH ] = 1.3 M
concentration of C₆H₅COOH dissociated = 0.0090036 M
percent dissociation of C₆H₅COOH will be;
⇒ ( 0.0090036 M / 1.3 M ) × 100 = 0.69 %
Therefore, the percent dissociation is 0.69 %
How many grams of h2o are needed to produce 45g of NO
One main difference between the heating of gases on the one hand and solids or liquids on the other is that ___________________. One main difference between the heating of gases on the one hand and solids or liquids on the other is that ___________________. heating of gases depends not only on the temperature difference, but also on the process as well as the amount of gas present. heating of gases depends on temperature difference as well as the amount of gas present. specific heat is not defined for gases. heat cannot be exchanged with gases.
Answer:
heating of gases depends not only on the temperature difference, but also on the process as well as the amount of gas present.
Explanation:
The work done when a gas is heated does not only depends on the initial and final states of the gas but also on the process used to achieve the change of state of the gas.
Several processes can be applied in changing the state of a gas such as; adiabatic process, isobaric process, isochoric process and isothermal process.
Hence, the heating of a gas, depends not only on the temperature difference, as well as the amount of gas present according to the ideal gas laws but also on the process used to achieve the change of state.
State two conditions necessary for an esterification reaction to take place
Explanation:
Esterification occurs when a carboxylic acid reacts with an alcohol. This reaction can only occur in the presence of an acid catalyst and heat. It takes a lot of energy to remove the -OH from the carboxylic acid, so a catalyst and heat are needed to produce the necessary energy.
Answer:
The Esterification ProcessThe Esterification ProcessEsterification occurs when a carboxylic acid reacts with an alcohol. This reaction can only occur in the presence of an acid catalyst and heat. It takes a lot of energy to remove the -OH from the carboxylic acid, so a catalyst and heat are needed to produce the necessary energy.
The Esterification ProcessEsterification occurs when a carboxylic acid reacts with an alcohol. This reaction can only occur in the presence of an acid catalyst and heat. It takes a lot of energy to remove the -OH from the carboxylic acid, so a catalyst and heat are needed to produce the necessary energy.Once the -OH has been removed, the hydrogen on the alcohol can be removed and that oxygen can be connected to the carbon. Because the oxygen was already connected to a carbon, it is now connected to a carbon on both sides, and an ester is formed.
The Esterification ProcessEsterification occurs when a carboxylic acid reacts with an alcohol. This reaction can only occur in the presence of an acid catalyst and heat. It takes a lot of energy to remove the -OH from the carboxylic acid, so a catalyst and heat are needed to produce the necessary energy.Once the -OH has been removed, the hydrogen on the alcohol can be removed and that oxygen can be connected to the carbon. Because the oxygen was already connected to a carbon, it is now connected to a carbon on both sides, and an ester is formed.The methyl acetate that was formed is an ester. In this image, the green circle represents what was the carboxylic acid (in this case acetic acid), and the red circle represents what was the alcohol (in this case methanol):
This reaction lost an -OH from the carboxylic acid and a hydrogen from the alcohol. These two also combine to form water. So any esterification reaction will also form water as a side product.
Suppose an enzyme and its substrate obey the lock and key model of enzyme catalysis. Which of the following would be true of the enzyme?
a. only one substrate could be converted to product by the enzyme
b. the active site of the enzyme must be rigid
c. the entire enzyme must be rigid
d. the active site of the enzyme must be flexible
e. the enzyme could bind different substrates if the substrates shared a common motif somewhere in their structures
Answer:
only one substrate could be converted to product by the enzyme
Explanation:
If an enzyme obeys the lock and key model, it then follows that the design of the enzyme is unique to a particular substrate.
Just as only the correct key can effectively fit into a lock, only the appropriate substrate whose design matches that of the enzyme can fit into the enzyme.
Owing to the lock and key model of enzyme activity, only one enzyme could interact with a substrate to yield particular product.
8.7 Two products are formed in the following reaction in a 50:50 mixture. Would the resulting solution be optically active
Answer:
Yes. The solution would be optically active.
Explanation:
Diastereomer are defined as the image that is non mirror and non -identical. It is made up of two stereoisomers. They are formed when the two stereoisomers or more than two stereoisomers of the compound have the same configuration at the equivalent stereocenters.
In the given context, as the product given is a diastereomeric mixture, the product would have an optical activity in total.
So the answer is Yes.
Which event would be impossible to explain by using John Dalton's model of the atom?
Answer:
That is, the atom is a solid and indivisible mass. However, the fenomenom by which an iron atom emits particles when it is struck by light (known as the photoelectric effect) can not be explaind by this indivisible atom model.
How is each triglyceride different from the others?
Each triglyceride is different from the others on the basis of presence of fatty acids in it.
What are triglycerides?Triglycerides is a kind of fat and derivative of ester which is formed by the combination of glycerol and three fatty acids.
So in the triglyceride molecule three sub divided parts are present due to the presence of three fatty acids groups and these fatty acids will make difference in each triglyceride molecules.
Hence of fatty acids in triglyceride molecule makes it different from other.
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Answer:
It has different fatty acids.
Explanation:
This is a signature of triglycerides
All of the orbitals in the 3d subshell have a principal quantum number value of 3, an angular momentum quantum number of:_____.
Answer:
According to the four quantum numbers; magnetic quantum number is the same as angular momentum quantum number. so the answer is 5
Explanation:
for d subshell angular momentum "d" is assigned a value of : m= 2(range from negative to positive i.e, -2 to 2) so we have [ -2, -1 ,0, 1 , 2] which concludes to 5.
One of the students in lab decided to use two fractionating columns (one on top of the other) instead of just one. How would this:_________.
a) affect the separation between hexane and heptane?
b) affect the yield of recovered pure hexane?
c) affect the yield of recovered pure heptane.
Explain your reasoning.
Answer:
See detailed explanation.
Explanation:
Hello there!
In this case, according to the given description, it turns out possible for us to infer that the second fractionating column on top of the first one will favor the light product, in this case hexane as it has the lowest boiling point and molar mass; in such a way, we can tell the following:
a) The separation between hexane and heptane will be increased as a purer hexane-rich product will be obtained on the top of the second column.
b) Will be increased as well, because the second column will remove more heptane.
c) Also, more pure heptane will be obtained on the bottom of the two columns, yet the most favored yield will be that of hexane.
All of the aforementioned is possible due to the fact that the second column will remove the amount of heptane that could not be removed on the top of the first column by taking the vapor-liquid equilibrium further from the first column's maximum separation, which is known as distillation sequences.
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When Hg2+ concentration is 6.35x10^-4 M, the observed cell potential at 298K for an electrochemical cell with the following reaction is 1.499V. What is the Cr3+ concentration?
3H^2+ (aq) + 2Cr(s)= 3Hg(l) + 2Cr^3+(aq)
Answer:
10.5 × 10^5 M
Explanation:
E°cell = E°cathode - E°anode
E°cell = 0.85 - (-0.74) = 1.59 V
From Nernst's equation;
Ecell = E°cell - 0.0592/n log Q
1.499 = 1.59 - 0.0592/6 log [Cr^3+]/6.35x10^-4
1.499 - 1.59 = - 0.0592/6 log [Cr^3+]/6.35x10^-4
-0.091 = -0.00987 log [Cr^3+]/6.35x10^-4
-0.091/ -0.00987 = log [Cr^3+]/6.35x10^-4
9.22 = log [Cr^3+]/6.35x10^-4
Antilog (9.22) = [Cr^3+]/6.35x10^-4
1.66 × 10^9 = [Cr^3+]/6.35x10^-4
[Cr^3+] = 1.66 × 10^9 × 6.35x10^-4
[Cr^3+] = 10.5 × 10^5 M