Under certain conditions the rate of this reaction is zero order in ammonia with a rate constant of :
0.0067·Ms−1: 2N2O(g)→2N2(g)+O2(g)
Suppose a flask is charged under these conditions with of ammonia. After how much time is there only left? You may assume no other reaction is important. Be sure your answer has a unit symbol, if necessary, and round it to significant digits.

Answers

Answer 1

Answer:

Explanation:

From the given information:

[tex]2NO_2_{(g)} \to 2N_{2(g)} + O_{2(g)}[/tex]

The above reaction is a zero-order reaction.

The rate constant = 0.0067 M-s⁻¹

Suppose the volume of the flask = 4L

Initial Mol of dinitrogen monoxide = 300 mmol

The final mol of dinitrogen monoxide = 150 mmol

The molarity of dinitrogen monoxide = [tex]\dfrac{ \text{number of moles of dinitrogen monoxide }}{\text{volume of flask}}[/tex]

[tex]= \dfrac{300 \ m}{ 4 L}[/tex]

= 0.0075 mmol/L

= 0.0075 L

The final concentration  [tex]= \dfrac{150 \ m}{ 4 L}[/tex]

= 0.0375 L

By applying zero order equation

[tex]kt = [A_o] -[At][/tex]

[tex](0.0067)(t) = 0.075 - 0.0375[/tex]

[tex](0.0067)(t) = 0.0375[/tex]

[tex]\mathbf{t = 5.59 \ seconds}[/tex]


Related Questions


The simplest chemical substance are composed of only what types of atom

Answers

The simplest chemical substance are composed of only the atoms known as elements

Here, we are required to determine what types of atoms are present in the simplest chemical substance.

The simplest chemical substances are composed of only the atoms of one kind of Element.

Chemical substances are generally classified as either;

ElementsCompoundsMixtures.

Definition of terms;

Elements and Compounds are collectively termed Pure Substances.

Elements: An element is a chemical substance that is composed of a specific kind of atom and cannot be broken down or transformed by means of a chemical reaction.

Elements: An element is a chemical substance that is composed of a specific kind of atom and cannot be broken down or transformed by means of a chemical reaction.Compound: A compound is a chemical substance formed by the combination of two or more elements or group of elements by means of a chemical reaction.

Elements: An element is a chemical substance that is composed of a specific kind of atom and cannot be broken down or transformed by means of a chemical reaction.Compound: A compound is a chemical substance formed by the combination of two or more elements or group of elements by means of a chemical reaction.Mixture: A mixture put simply is a chemical substance that consists of diverse, nonbonded elements, molecules or compounds as the case may be.

Therefore, inference drawn from the premises above point to the fact that the simplest chemical substances are composed of the atoms of one type of element.

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What is the molecular formula of the molecule that has an empirical formula of C2H40 and a molar mass of 176.21 g/mol?
Type your answer using the following format:
CuCl2 for CuCl2.

Answers

Answer:

C8H16O4

Explanation:

C2H4O= 24+4+16

44

n=molar mass/empirical formula

n=176.21/44

=4

Therefore

Molar Formula= (C2H4O)4=C8H16O4

Binary compounds are formed by ............... ............... elements.

Answers

Answer: i think its A diatomic compound..

Explanation: hope i helped! sorry if im wrong!

how many grams of water produced if we react 3 moles of hydrogen with 3 moles of oxygen

Answers

I don’t know the molecular equation for water so I’ll just guess 3

How many grams of water at 0 degree c can be frozen into ice at zero degree c if 55 kj of heat is removed

Answers

Answer:

what is that's a question

According to specific heat capacity, 13.09 grams of water at 0 degree Celsius  can be frozen into ice at zero degree c if 55 kJ of heat is removed.

What is specific heat capacity?

Specific heat capacity is defined as the amount of energy required to raise the temperature of one gram of substance by one degree Celsius. It has units of calories or joules per gram per degree Celsius.

It varies with temperature and is different for each state of matter. Water in the liquid form has the highest specific heat capacity among all common substances .Specific heat capacity of a substance is infinite as it undergoes phase transition ,it is highest for gases and can rise if the gas is allowed to expand.

It is given by the formula ,

Q=mcΔT, substitution in formula gives Q/c=m which is m= 55/4.2=13.09 grams.

Thus, 13.09 grams of water at 0 degree Celsius  can be frozen into ice at zero degree c if 55 kJ of heat is removed.

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It pulls everything down towards earth

Answers

The answer is gravity:
Explanation: an invisible force that pulls objects toward each other. Earth's gravity is what keeps you on the ground and what makes things fall. Anything that has mass also has gravity.

Predict how many H1 NMR signals (individual resonances, not counting splitting) are expected for the compound.

Answers

Answer:

3 H1 NMR signals

Explanation:

NB: kindly check the diagram of the chemical compound in the attached picture.

This particular Question is based on the part of chemistry which is known as spectroscopy. Spectroscopy is used in the Determination or in identifying chemical compounds. H'NMR works on the principle of nuclear magnetic resonance.

In order to solve this question, one has to count the number of hydrogen in unique location. The diagram in the attached show how hydrogen is been counted.

The numbers of signals is the number of different chemical environments in which hydrogen atoms are located.

NB: signals is also the same as peak in H'NMR.

Hence, the number of H1 NMR signals in this chemical compound is 3.

Can somebody PLEASE tell me the empirical formula for br2o6

Answers

Answer:

BrO3

Explanation:

The empirical formula is the smallest whole-number ratio, you find the greatest common factor (which is 2, in this case), then divide the subscripts by it.

So:

Br2 / 2 = Br1

O6 / 2 = O3

Calculate the kinetic energy of an electron ejected from a piece of sodium (Φ = 4.41x10–19 J) that is illuminated with 265 nm light.

in Joules

Answers

Answer:

Explanation:

Energy of falling radiation having wavelength of 265 nm

= h c / λ where h is plank's constant , c is velocity of light and λ is wavelength of radiation . Putting the values

Energy of light photon = 6.6 x 10⁻³⁴ x 3 x 10⁸ / 265 x 10⁻⁹

= .0747 x 10⁻¹⁷

= 7.47 x 10⁻¹⁹ J .

Work function of sodium is 4.41 x 10⁻¹⁹

So kinetic energy of ejected electron = energy of falling photon - work function

= 7.47 x 10⁻¹⁹ - 4.41 x 10⁻¹⁹

= 3.06 x 10⁻¹⁹ eV .

Which of the following elements has the largest atomic radius?
A. Ba
B.F
C. Ga
D. P

Answers

Answer:

A. Ba

Explanation:

Atomic radius increases as you go down and decreases as you go right.

A. ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎ ‎

What is the mass of 4.67 mol of Sulfuric Acid (H2SO4)

Answers

Answer:

458 g H₂SO₄

General Formulas and Concepts:

Math

Pre-Algebra

Order of Operations: BPEMDAS

Brackets Parenthesis Exponents Multiplication Division Addition Subtraction Left to Right

Chemistry

Atomic Structure

Reading a Periodic Table

Stoichiometry

Using Dimensional AnalysisExplanation:

Step 1: Define

4.67 mol H₂SO₄

Step 2: Identify Conversions

[PT] Molar Mass of H - 1.01 g/mol

[PT] Molar Mass of S - 32.07 g/mol

[PT] Molar Mass of O - 16.00 g/mol

Molar Mass of H₂SO₄ - 2(1.01) + 32.07 + 4(16.00) = 98.09 g/mol

Step 3: Convert

Set up:                              [tex]\displaystyle 4.67 \ mol \ H_2SO_4(\frac{98.09 \ g \ H_2SO_4}{1 \ mol \ H_2SO_4})[/tex]Multiply/Divide:                [tex]\displaystyle 458.08 \ g \ H_2SO_4[/tex]

Step 4: Check

Follow sig fig rules and round. We are given 3 sig figs.

458.08 g H₂SO₄ ≈ 458 g H₂SO₄

WILL MARK BRANLIEST FOR CORRECT ANSWER! Given the following equation, write the expression for its relative rate.

2N2O(g) — 2N2(g) + O2(9)

Answers

[tex]\tt -\dfrac{1}{2}\dfrac{d[N_2O]}{dt}=\dfrac{1}{2}\dfrac{d[N_2]}{dt}=\dfrac{1}{1}\dfrac{d[O_2]}{dt}[/tex]

Further explanation

Reaction

2N2O(g) — 2N2(g) + O2(g)

Required

relative rate

Solution

The reaction rate (v) shows the change in the concentration of the substance (changes in addition to concentrations for reaction products or changes in concentration reduction for reactants) per unit time.

so the relative rates for the reaction above are :

[tex]\tt -\dfrac{1}{2}\dfrac{d[N_2O]}{dt}=\dfrac{1}{2}\dfrac{d[N_2]}{dt}=\dfrac{1}{1}\dfrac{d[O_2]}{dt}[/tex]

Pls give a detailed explanation about what are enzyme mutations

Answers

Answer:

Enzyme mutations can lead to serious or fatal human disorders and are the consequence of inherited abnormalities in the affected individual's DNA. The mutation may be at a specific position in an enzyme encoded by a mutated gene, just like a single abnormal amino acid residue.

Explanation:

2. What is the difference between an investigation and a demonstration?

Answers

Answer:

An investigation is about collecting information, while an experiment is testing  something based off an investigation

Explanation:

Hope this helps

An experiment tests something based on an investigation, whereas an investigation pertains to gathering knowledge.

What are an investigation and a demonstration?

The operation of something is demonstrated. There are independent and dependent variables in an experiment. The control of variables distinguishes an experiment from a demonstration. Add an independent as well as a dependent variable to the project in order to convert a demonstration into an experiment.

An information resource's value to a particular professional group and its influence on the procedures and results of healthcare are just a few of the problems that demonstration studies address. An experiment tests something based on an investigation, whereas an investigation pertains to gathering knowledge.

Therefore, an experiment tests something based on an investigation, whereas an investigation pertains to gathering knowledge.

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What kind of intermolecular forces act between a hydrogen cyanide (HCN) molecule and a carbon monoxide molecule?

Answers

Answer:

Dispersion forces

Dipole-Dipole interaction

Explanation:

The London dispersion force refers to the temporary attractive force that acts between the electrons in two adjacent atoms when the atoms develop temporary dipoles. Dispersion forces act between any two molecules even when other intermolecular forces are in operation as long as the molecules are in close proximity to each other.

Now, CO is polar and the HCN is also polar molecule. Hence, dipole - dipole interaction forces  are also in operation and acts between the two molecules in close proximity to each other.

Dispersion forces and Dipole-Dipole interaction are intermolecular forces which act between a hydrogen cyanide (HCN) molecule and a carbon monoxide molecule

The transitory attractive force that exists between the electrons in two nearby atoms when the atoms form transient dipoles is known as the London dispersion force. As long as the molecules are close to one another, dispersion forces can exist between any two molecules, even when other intermolecular forces are active.

The HCN molecule and CO are both polar molecules right now. As a result, dipole-dipole interaction forces act between the two molecules when they are close to one another.

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Hello, could someone help me with this?

Answers

Answer:

c. bigger planets have more gravity and smaller planets have less gravity. i hope this helped :))

Asapp please
The percent composition of an unknown substance is 75.42% Carbon, 6.63 % Hydrogen,
8.38 % Nitrogen, and 9.57 % Oxygen. If its molar mass is 334.0 g/mol what is its empirical and
molecular formula?

Answers

The empirical and  molecular formula : C₂₁H₂₂N₂O₂

Further explanation

Given

The percent composition of an unknown substance is 75.42% Carbon, 6.63 % Hydrogen, 8.38 % Nitrogen, and 9.57 % Oxygen

Required

The empirical and  molecular formula

Solution

C : 75.42 : 12 = 6.285

H : 6.63 : 1 = 6.63

N : 8.38 : 14 = 0.599

O : 9.57 : 16 = 0.598

Divide by 0.598

C : H : N : O = 10.5 : 11 : 1 : 1 = 21 : 22 : 2 : 2

The empirical formula : C₂₁H₂₂N₂O₂

(C₂₁H₂₂N₂O₂)n = 334

(334)n=334

n = 1

From where do the placenta and umbilical cord develop?

Answers

Answer:

it develops from the womb

Answer:

outer cells of the blastocyst

Explanation:

on edg:)

What is the energy of an electron in the third energy level of hydrogen?

Answers

Answer:

Electrons in a hydrogen atom must be in one of the allowed energy levels. If an electron is in the first energy level, it must have exactly -13.6 eV of energy.

...

Energy Levels of Electrons.

Energy Level Energy

1 -13.6 eV

2 -3.4 eV

3 -1.51 eV

4 -.85 eV

What is the density of an object with a mass of 8.7 g and a volume of 8.6 cm??

Answers

Answer:

1.01 grams/ cm^3

Explanation:

because that's just how it is

How many molecules of NaOH are there in 22 moles?

Answers

Answer:

i hope my answer help u :))

Explanation:

no , it will be 39.99711

What are the components of the system that influence its motion? *

Answers

Answer:

Motion control systems are any system that control one or more of the following of a machine: its position, velocity, force, and/or pressure. They generally consist of the follow components: Motion controller: the central part that operates the system (I.e. the brain)

One mole of a metallic oxide reacts with one mole of hydrogen to produce two moles of the pure metal
and one mole of water. 5.00 g of the metallic oxide produces 2.32 g of the metal. What is the metallic
oxide? (Use molar masses)

Answers

Answer:

Formulas

3.2 Determining Empirical and Molecular Formulas

Learning Objectives

By the end of this section, you will be able to:

Compute the percent composition of a compound

Determine the empirical formula of a compound

Determine the molecular formula of a compound

The previous section discussed the relationship between the bulk mass of a substance and the number of atoms or molecules it contains (moles). Given the chemical formula of the substance, one may determine the amount of the substance (moles) from its mass, and vice versa. But what if the chemical formula of a substance is unknown? In this section, these same principles will be applied to derive the chemical formulas of unknown substances from experimental mass measurements.

Percent Composition

The elemental makeup of a compound defines its chemical identity, and chemical formulas are the most succinct way of representing this elemental makeup. When a compound’s formula is unknown, measuring the mass of each of its constituent elements is often the first step in the process of determining the formula experimentally. The results of these measurements permit the calculation of the compound’s percent composition, defined as the percentage by mass of each element in the compound. For example, consider a gaseous compound composed solely of carbon and hydrogen. The percent composition of this compound could be represented as follows:

%H=mass Hmass compound×100%

%C=mass Cmass compound×100%

If analysis of a 10.0-g sample of this gas showed it to contain 2.5 g H and 7.5 g C, the percent composition would be calculated to be 25% H and 75% C:

%H=2.5g H10.0g compound×100%=25%

%C=7.5g C10.0g compound×100%=75%

EXAMPLE 3.9

Calculation of Percent Composition

Analysis of a 12.04-g sample of a liquid compound composed of carbon, hydrogen, and nitrogen showed it to contain 7.34 g C, 1.85 g H, and 2.85 g N. What is the percent composition of this compound?

Solution

To calculate percent composition, divide the experimentally derived mass of each element by the overall mass of the compound, and then convert to a percentage:

%C=7.34g C12.04g compound×100%=61.0%%H=1.85g H12.04g compound×100%=15.4%%N=2.85g N12.04g compound×100%=23.7%

The analysis results indicate that the compound is 61.0% C, 15.4% H, and 23.7% N by mass.

Check Your Learning

A 24.81-g sample of a gaseous compound containing only carbon, oxygen, and chlorine is determined to contain 3.01 g C, 4.00 g O, and 17.81 g Cl. What is this compound’s percent composition?

ANSWER:

12.1% C, 16.1% O, 71.8% Cl

Determining Percent Composition from Molecular or Empirical Formulas

Percent composition is also useful for evaluating the relative abundance of a given element in different compounds of known formulas. As one example, consider the common nitrogen-containing fertilizers ammonia (NH3), ammonium nitrate (NH4NO3), and urea (CH4N2O). The element nitrogen is the active ingredient for agricultural purposes, so the mass percentage of nitrogen in the compound is a practical and economic concern for consumers choosing among these fertilizers. For these sorts of applications, the percent composition of a compound is easily derived from its formula mass and the atomic masses of its constituent elements. A molecule of NH3 contains one N atom weighing 14.01 amu and three H atoms weighing a total of (3 × 1.008 amu) = 3.024 amu. The formula mass of ammonia is therefore (14.01 amu + 3.024 amu) = 17.03 amu, and its percent composition is:

%N=14.01amu N17.03amuNH3×100%=82.27%%H=3.024amu H17.03amuNH3×100%=17.76%

This same approach may be taken considering a pair of molecules, a dozen molecules, or a mole of molecules, etc. The latter amount is most convenient and would simply involve the use of molar masses instead of atomic and formula masses, as demonstrated Example 3.10. As long as the molecular or empirical formula of the compound in question is known, the percent composition may be derived from the atomic or molar masses of the

Given 450.98 g of Cu(NO3)2, how many moles of Ag can be made? Provide your final answer rounded to two decimal places.
Cu + 2 AgNO3 → Cu(NO3)2 + 2 Ag

Answers

Answer:

4.82 moles of Ag.

Explanation:

We'll begin by calculating the number of mole in 450.98 g of Cu(NO₃)₂. This can be obtained as follow:

Molar mass of Cu(NO₃)₂ = 63.5 + 2[14 + (16×3)]

= 63.5 + 2[14 + 48]

= 63.5 + 2[62]

= 63.5 + 124

= 187.5 g/mol

Mass of Cu(NO₃)₂ = 450.98 g

Mole of Cu(NO₃)₂ =?

Mole = mass /Molar mass

Mole of Cu(NO₃)₂ = 450.98 / 187.5

Mole of Cu(NO₃)₂ = 2.41 moles

Next, we shall determine the number of mole of Cu needed to produce 450.98 g (i.e 2.41 moles) of Cu(NO₃)₂. This can be obtained as follow:

Cu + 2AgNO₃ —> Cu(NO₃)₂ + 2Ag

From the balanced equation above,

1 mole of Cu reacted to produce 1 mole of Cu(NO₃)₂.

Therefore, 2.41 moles of Cu will also react to produce 2.41 moles of Cu(NO₃)₂.

Thus, 2.41 moles of Cu is needed for the reaction.

Finally, we shall determine the number of mole of Ag produced from the reaction. This can be obtained as follow:

From the balanced equation above,

1 mole of Cu reacted to produce 2 moles of Ag.

Therefore, 2.41 moles of Cu will react to produce = 2× 2.41 = 4.82 moles of Ag.

Thus, 4.82 moles of Ag were obtained from the reaction.

18. What is one of the three things that cause the surface currents of the oceans?
A.differences in salinity
B.temperature differences
C. density differences
D. Coriolis effect

Answers

Answer:

b. temperature difference

In Purdue's Chemistry department, the chemists have found that in a water based solution containing 1616 grams of certain undissolved chemicals, the rate of change of the amount of chemicals dissolved in the solution is proportional to the amount of the undissolved chemicals. Let Q(t)Q(t) (in grams) be the amount of dissolved chemicals at time tt and let kk be the positive proportionality constant. The differential equation describing the given situation is:

Answers

Answer:

The differential equation describing the given situation is dQ/dt = k( 16 - Q )

Explanation:

Given the data in the question;

Initially, the water based solution contains 16 grams of undissolved chemicals;

Assume Q(t) is the amount of dissolved chemical at time L

then the amount of undissolved chemicals at time t is ( 16 - Q)

The rate of change of amount of chemicals dissolved in the solution is proportional to the amount of undissolved chemicals

this means;

dQ/dt ∝ ( 16 - Q)

dQ/dt = k( 16 - Q )

where k is the positive proportionality constant.

Therefore, The differential equation describing the given situation is dQ/dt = k( 16 - Q )

Can anyone help me? Plsss

Answers

#9

A) tetrahedral
B) linear
C) regional pyramid
D) trigonal planar
E) trigonal planar
F) tetrahedral

Open the Molecule Shapes interactive and select Real Molecules. Check the box to Show Bond Angles. Classify each molecule by whether its real bond angles are the same as or different than its model (ideal) bond angles. In other words, do the bond angles change when you switch between Real and Model mode at the top of the page? Same (angles do not change) Different (angles change) Answer Bank H0 00, 50, XP, BF, CIF, NH, CH, SP, XF, BF, PCI, SF,

Answers

Answer:

Same bond angle-CO2, CH4, SF6, PCl5, BF3, BeF2, XeF4,XeF2

Different bond angle- H2O, SO2, NH3, ClF3,SF4

Explanation:

We know that the shape of molecules and and bond angles between atoms in molecules are predicted on the basis of the valence shell electron pair repulsion theory.

Most times, certain molecules deviate from the expected bond angles for different reasons. The most common reason is the presence of lone pairs on the molecule. This is the case in the molecules; H2O, SO2, NH3, ClF3 and SF4.

However, in XeF4 and XeF2, the lone pairs orient themselves in such a way that they do not distort the expected bond angle. For instance, in XeF2, the  three lone pairs occupy equatorial positions while the two bond pairs occupy apical positions. In XeF4, the bond pairs are directed at the corners of a square while the two lone pairs are positioned above and below the plane of the square.

Consider the following unknown solution analysis:
Flame test: red flame Solutions reactions: ammonium carbonate - white precipitate (ppt.) ammonium phosphate - white ppt. Halide test: purple hexane layer The complete chemical name for the unknown compound is______. The correct chemical formula of the compound is_______ .

Answers

Answer:

The answer is "Strontium iodide and [tex]SrI_2[/tex]".

Explanation:

In the flames test, two ionic metals give red fire. It was calcium (Ca, which gives a red brick flame) and strontium (Sr, which gives a persistent red flame). Both Ca and Sr respond to insoluble carbonate with ammonium carbonate. Ca and Sr produce insoluble ammonium phosphate phosphates. Even then, the water is reactive with calcium sulfate (CaSO4) whereas the strontium sulfate (SrSO4) is illiquid. Because the metal ion formed 3 precipitates, they can't get Ca, and we have Sr as its metal.

The hexane of its halide gives a violet color which would be typical of iodide (I-).

Strontium iodide is the chemical name of the unknown ionic compound.

Strontium iodide's chemical formula is [tex]SrI_2[/tex].

An electric circuit has an expected current of 80 amps An electrician measures the current in the circuit at 120 amps. Which
statement provides a possible explanation for this observation?

There is not enough voltage in the circuit.

The circuit has an extra resistor

A resistor in the circuit is broken

There is not enough electrical energy in the circuit.

Answers

The answer would be C
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The mass of the particles that a river can transport is proportional to the fifth power of the speed of the river. A certain river normally flows ata speed of 4 miles per hour. What must its speed be in order to transport particles that are 12 times as massive as usual? Round youranswer to the nearest hundredth. A cheesecake recipe says:Mix 12 ounces of cream cheese with 15 ounces of sugar.1. What is the unit rate of cream cheese for sugar?2. what is the unit rate of sugar for cream cheese?(CORRECT ANSWER GETS A GOOD 5 STARS AND BRAINLESST) Which main character lives in zazi Germany in 1938 The equation that Passes through the points (-4,2) and (5,-3) If you solved the equation y=kx for k, what would k be equal to?O k = xyk = y/xO k = x/yO k = x+yO k=y-XBackNort The scatter plot shows which type of correlation?A. No correlation B. Cant be determined C. Negative correlation D. Positive correlation 2. Order the steps of mineral formation from the first stage to the final stage. How do you solve -8r=240 One Newton is equivalent toA. 1 kg/s2B. 1 kg*m/sC. 1 kg*m/s2D. 1 kg/s Plz help i need answer fast i will mark brainliest and follow you The following statements describes which step in the criminal justice processMagistrate judge determines if a crime was committed AND If there is probable cause that the suspect was involved with the crimepreliminary hearingarraignmentappealbooking Only do what you know ! I know the answers thought but I wanna know what y'all know . the graph of y=f(x) is shown on the grid qu temas crees que se suelen abandonarse en una mesa redonda? what action did hongwu take that may have pleased the Chinese people Write one example about guaranteed. Triangle abc is equilateral, solve for x and y 1. What does Malcolm X think the goal of any revolution should be?2. How does Malcolm X justify violence as a means for black Americans to improve themselves?3. According to Malcolm X, what is the difference between a Negro revolution and a black revolution?4. According to Malcolm X, what are Uncle Toms and how do they slow progress for blacks in America? Having behind us the producing masses of this nation and the world, supported by the commercial interests, the laboring interests and the toilers everywhere, we will answer their demand for a gold standard by saying to them: You shall not press down upon the brow of labor this crown of thorns, you shall not crucify mankind upon a cross of gold. -William Jennings Bryan, Cross of Gold, July 9, 1896 20. Which group would share Bryan's opinion? (2.2.B) A Industrialists B Farmers C Republicans D Prohibitionists C i need help with this