Suppose a 0.042M aqueous solution of phosphoric acid (H3PO4) is prepared. Calculate the equilibrium molarity of HPO4^−2.

Answers

Answer 1

Answer:

2.89x10⁻⁵M = [HPO₄²⁻]

Explanation:

The equilibrium of H3PO4 in water occurs H2PO4-:

H3PO4(aq) + H2O(l) ⇄ H3O⁺(aq) + H2PO4⁻(aq)

pKa = 2.16. And as pKa = -log Ka; Ka = 10^-2.16

Ka = 6.9183x10⁻³ = [H3O⁺] [H2PO4⁻] / [H3PO4]

As both [H3O⁺] and [H2PO4⁻] comes from the same equilibrium,

[H3O⁺]=[H2PO4⁻] :

[H3O⁺] = X

[H2PO4⁻] = X

[H3PO4] = 0.042 - X

Where X is reaction coordinate

Replacing:

6.9183x10⁻³ = [X] [X] / [0.042 - X]

6.9183x10⁻³ = X² / 0.042 - X

2.905686x10⁻⁴ - 6.9183x10⁻³X - X² = 0

Solving for X:

X = -0.02M. False solution. There is no negative concentration.

X = 0.014M. Right solution

[H2PO4⁻] = 0.014M

In the second equilibrium:

H2PO4⁻(aq) + H2O(l) ⇄ HPO4-(aq) + H3O+(aq)

Based on the same principles of the last equilibrium:

pKa2 = 7.21

Ka2 = 6.166x10⁻⁸ = [HPO4-] [H3O+] / [H2PO4⁻]

[HPO4-] = X

[H3O+] = X

[H2PO4⁻] = 0.014M - X

6.166x10⁻⁸ = X² / [0.014M - X]

8.3623x10⁻¹⁰ - 6.166x10⁻⁸X - X² = 0

Solving for X:

X = -0.0000289485. False solution.

X =

2.89x10⁻⁵M = [HPO₄²⁻]

Related Questions

which of the following is not an instance of benefit in from gases ?

1) filling thermometers
2) inflating tyres
3) in LP gas cylinders
4) in pressure cookers​

Answers

Answer:

1) filling thermometers

Explanation:

thermometers are filled with liquid mercury

An electron-dot structure is a convenient method of representing

A. The complete electron configuration of the atom.
B. all electrons of the atom.
C. valence electrons of an atom.
D. core electrons of an atom.

Answers

Answer:

all electrons of the atom

I mix together 50.0 mL of 0.100 M NaIO3, 50.00 mL of 0.100 M NaOH, and 10.0 mL of 0.100 M HIO3. What is the pH of the mixture

Answers

Answer:

pH = 12.66

Explanation:

The HIO3 reacts with NaOH as follows:

HIO3 + NaOH → H2O + NaIO3

The moles of HIO3 and NaOH added are:

Moles HIO3:

0.0100L * (0.100mol / L) = 0.00100 moles HIO3

Moles NaOH:

0.05000L * (0.100mol / L) = 0.00500 moles NaOH

As moles NaOH > Moles HIO3, the moles of NaOH that remain are:

0.00500mol - 0.00100mol = 0.00400 moles NaOH.

After the reaction you will have only NaOH and NaIO3. As NaIO3 is a salt, the pH of the solution is determined by only NaOH. Its concentration is:

Moles NaOH: 0.00500 moles NaOH

Volume: 50.0mL + 50.0mL + 10.0mL = 110.0mL = 0.110L

Molarity: 0.0455M NaOH = [OH-]

pOH = -log [OH-] = 1.34

pH = 14 - pOH

pH = 12.66

pH is the measure of the hydrogen or the hydronium ion in an aqueous solution. The pH of the mixture containing sodium hydroxide is 12.66.

What is pH?

pH is the potential of the hydrogen and is given as a negative log of the hydrogen concentration in the aqueous solution.

The balanced chemical reaction can be shown as:

[tex]\rm HIO_{3} + NaOH \rightarrow H_{2}O + NaIO_{3}[/tex]

Moles of iodic acid are calculated as:

[tex]\begin{aligned} \rm moles &= \rm molarity \times volume\\\\&= 0.100 \;\rm M \times 0.0100 \;\rm L \\\\&= 0.00100\;\rm moles\end{aligned}[/tex]

Moles of sodium hydroxide are calculated as:

[tex]\begin{aligned} \rm moles &= \rm molarity \times volume\\\\&= 0.100 \;\rm M \times 0.05000 \;\rm L \\\\&= 0.00500\;\rm moles\end{aligned}[/tex]

The remaining moles of sodium hydroxide are 0.00500mol - 0.00100mol = 0.00400 moles.

The pH of the mixture will be determined by sodium hydroxide, as sodium iodate is a salt.

The molar concentration of sodium hydroxide is calculated as:

[tex]\begin{aligned} \rm M &= \rm \dfrac{moles}{volume}\\\\&= \dfrac{0.00500}{0.110}\\\\&= 0.0455 \;\rm M\end{aligned}[/tex]

pH is calculated as:

[tex]\begin{aligned} \rm pOH &= \rm -log[OH^{-}] = 1.34\\\\\rm pH &= \rm 14 - pOH\\\\\rm pH &= 12.66\end{aligned}[/tex]

Therefore, 12.66 is the pH of the mixture.

Learn more about pH here:

https://brainly.com/question/13539106

20. What intermolecular forces would affect the interactions of water molecules? Explain why.

Answers

Answer:

Water has strong hydrogen bond dipole-dipole intermolecular forces that give water a high surface tension and a high heat of vaporization and that make it a strong solvent

PLEASE HELP FAST!!

Which of the following ions is formed when an acid is dissolved in a solution?
H+
O−
OH−
SO42+

Answers

Answer:

H+

Explanation:

acid produce H+ when it is dissolved in a solution

If the volume of the gas is increased to 9.6 L , what will the pressure be?

Answers

The pressure will be 438 mm Hg

In some sheep, the presence of horns is produced by an autosomal allele that is dominant in males and recessive in females.A horned female is crossed with a hornless male. One of the resulting F1 females is crossed with a hornless male. What proportion of the male and female progeny from this cross will have horns?(5 marks)

Answers

Answer:

1/2 f1 will cross

Explanation:

answer it

What are the uses of Sulphuric acid?

Answers

Answer:

The major use of sulfuric acid is in the production of fertilizers, e.g., superphosphate of lime and ammonium sulfate. It is widely used in the manufacture of chemicals, e.g., in making hydrochloric acid, nitric acid, sulfate salts, synthetic detergents, dyes and pigments, explosives, and drugs.

The major use of sulfuric acid is in the production of fertilizers, e.g., superphosphate of lime and ammonium sulfate. It is widely used in the manufacture of chemicals, e.g., in making hydrochloric acid, nitric acid, sulfate salts, synthetic detergents, dyes and pigments, explosives, and drugs.

b) What is the change in entropy of the reaction if ΔH° = -3.2 kJ mol-1?

Answers

I would go w A I just took the test it was very way I got straight b on it

Methyl orange can change color by transitioning from one chromophore to another. When added to a clear solution and the solution turns red, it is determined to be a(n) __________ in its __________ stable form.

Answers

Answer:

acidic titration in its stable form

Explanation:

Methyl orange can change its color in titration solution. The yellow color is towards alkaline solution and red color is towards acidic solution. The Ph value of solution will change during this chemical process.

Acetic acid and water react to form hydronium cation and acetate anion, like this:

HCH3CO2(aq) + H2O → H3O+(l)(aq) + CH3CO2^-(aq)

Imagine 226 mmol of CH3CO2- are added to a flask containing a mixture of HCH3CO2, H2O, H3O + and CH3CO2- at equilibrium.

Required:
What is the rate of the reverse reaction before any CH3CO2^- has t:een added to the flask?

Answers

Answer:

The rate of the reverse reaction before any addition of CH3CO2- is zero

Explanation:

When the reaction is in equilibrium:

HCH3CO2(aq) + H2O ⇄ H3O+(l)(aq) + CH3CO2^-(aq)

The reaction quotient, Q = Ka and no more products or reactants are produced because their concentrations are in the right proportion.

Now, as no reaction occurs,

The rate of the reverse reaction before any addition of CH3CO2- is zero

HELP ME PLEASE!!!!!!
I WANT IT AS PARAGRAPHHHHH NOT POINT AND ANSWER THIS TWO QUESTIONS AS 1 PARAGRAPH

Answers

One of the lab safety rules being violated is that Jodi doesn't have her hair tied up. She should have her hair tied up. Having her long hair not tied up or away from her face is a safety hazard. Jodi is also not wearing glasses, which is essential when working with chemicals. One of the Bunsen Burners aren't being used but it's on, which is a fire hazard.

Answer:

Jodi should wear her hair up to avoid a mishap, such as lighting her hair on fire. Then, instead of using a fire extinguisher on Jodi, Kimberly should use a fire blanket to prevent additional damage. Mac is preoccupied with a second flame and maybe Jodi without her safety goggles?

the question is in the attachment

Answers

Answer:

About redox reaction which of the given statements are true?

Explanation:

Redox reaction is the one in which both oxidation and reduction reactions take place simultaneously.

For example:

[tex]C(s)+O_2(g)->CO_2(g)[/tex]

In this reaction, carbon undergoes oxidation and oxygen undergoes reduction simultaneously.

During this reaction, mutual exchange of electrosn take place between the oxidant and the reductant.

Among the given options,

Option B. electrons are transferred

and

option C.They include both oxidation and reduction takes place are the correct answers.

1. A 225-L barrel of white wine has an initial free SO2 concentration of 22 ppm and a pH of 3.70. How much SO2 (in grams) should be added to the barrel to result in the required SO2 level

Answers

Answer:

The appropriate answer is "9.225 g".

Explanation:

Given:

Required level,

= 63 ppm

Initial concentration,

= 22 ppm

Now,

The amount of free SO₂ will be:

= [tex]Required \ level -Initial \ concentration[/tex]

= [tex]63-22[/tex]

= [tex]41 \ ppm[/tex]

The amount of free SO₂ to be added will be:

= [tex]41\times 225[/tex]

= [tex]9225 \ mg[/tex]

∵ 1000 mg = 1 g

So,

= [tex]9225\times \frac{1}{1000}[/tex]

= [tex]9.225[/tex]

Thus,

"9.225 g" should be added.

In what kind of orbital do the lone-pair electrons on the nitrogen of dimethylacetamide reside, and is it in the same plane as the ch3 groups

Answers

Answer:

The lone pairs on nitrogen in dimethylacetamide reside in sp3 orbitals which are coplanar with the methyl groups

Explanation:

The compound dimethylacetamide consists of oxygen bearing two lone pairs of electrons and a nitrogen atom bearing a lone pair of electrons and has two methyl groups attached to the nitrogen atom.

The lone pair on the nitrogen atom is accommodated in an sp3 orbital of nitrogen as shown in the question. This sp3 orbital is coplanar with the two methyl groups.

Write the number of sig. fig. in four numbers given in the sentence below. An (one) octopus has 8 legs. 13 octopi have 104 legs.
Give four answers.
A. Infinity, Infinity, Infinity, Infinity
B. 1, 1, 2, 3
C. Infinity, Infinity, 2, 3
D. No answer text provided.​

Answers

Answer:

1, 1, 2, 3

Explanation:

The numbers 1 and 8 both have 1 sig. fig.

The number 13 has 2 sig. figs.

The number 104 has 3 sig. figs.

Calculate the Experimental Molar Volume in L/mol of the Hydrogen gas, H2, if the volume of H2 at STP is 52.8 mL and the mass of Magnesium metal, Mg, used in the experiment is 0.055 g.

Answers

Answer:

The Experimental Molar Volume in L/mol of the Hydrogen gas=23.36L/mol

Explanation:

We are given that

Volume of H2 at STP=52.8mL

Mass of magnesium metal ,M(Mg)=0.055g

We have to find the Experimental Molar Volume in L/mol of the Hydrogen gas.

Molar mass of Mg=24.305 g/mol

Number of moles=[tex]\frac{given\;mass}{molar\;mass}[/tex]

Using the formula

Number of moles of Mg=[tex]\frac{0.055}{24.305}[/tex]moles

Number of moles of Mg=0.00226moles

Number of moles of Mg=Number of moles of H2

Number of moles of H2=0.00226moles

Molar volume of Hydrogen gas (H2)=[tex]\frac{volume\;at\;STP}{No\;of\;moles\;H_2}[/tex]

Molar volume of Hydrogen gas (H2)=[tex]\frac{52.8}{0.00226}mL/mol[/tex]

Molar volume of Hydrogen gas (H2)=[tex]\frac{52.8}{0.00226}\times 10^{-3}L/mol[/tex]

[tex]1L=1000mL[/tex]

Molar volume of Hydrogen gas (H2)=23.36L/mol

Hence, the Experimental Molar Volume in L/mol of the Hydrogen gas=23.36L/mol

she goes away change to negative form​

Answers

She goes away.

Negative

She doesn't go away.

The equilibrium constant (K p) for the interconversion of PCl 5 and PCl 3 is 0.0121:
PCl5 (g) → PCl3 (g) + Cl2 (g)
A vessel is charged with PCl 5 giving an initial pressure of 0.123 atm and yields PCl 3 and Cl 2. At equilibrium, the partial pressure of PCl 3 is ________ atm.
A) 0.0782.
B) 0.0455.
C) 0.0908.
D) 0.0330.
E) 0.123.

Answers

Answer: At equilibrium, the partial pressure of [tex]PCl_{3}[/tex] is 0.0330 atm.

Explanation:

The partial pressure of [tex]PCl_{3}[/tex] is equal to the partial pressure of [tex]Cl_{2}[/tex]. Hence, let us assume that x quantity of [tex]PCl_{5}[/tex] is decomposed and gives x quantity of [tex]PCl_{3}[/tex] and x quantity of [tex]Cl_{2}[/tex].

Therefore, at equilibrium the species along with their partial pressures are as follows.

                         [tex]PCl_{5}(g) \rightarrow PCl_{3}(g) + Cl_{2}(g)\\[/tex]

At equilibrium:  0.123-x          x              x

Now, expression for [tex]K_{p}[/tex] of this reaction is as follows.

[tex]K_{p} = \frac{[PCl_{3}][Cl_{2}]}{[PCl_{5}]}\\0.0121 = \frac{x \times x}{(0.123 - x)}\\x = 0.0330[/tex]

Thus, we can conclude that at equilibrium, the partial pressure of [tex]PCl_{3}[/tex] is 0.0330 atm.

Where do reactions in a solid
generally take place?
A. All throughout the solid
B. At the center of the solid.
C. Only on opposite sides of the solid
due to repelling forces.
D. On the surface of the solid.

Answers

Answer:

A

Explanation:

because solid stick together like magnetic and can feel every vibration

Answer:D

Explanation: on the surface of a solid

Suppose you perform a titration of an unknown weak acid solution. You start with 4.00 mL of the weak acid and find that it takes 14.2 mL of 0.0500 M NaOH to reach the equivalence point. What is the concentration of the unknown weak acid solution

Answers

Answer:

0.1775 M

Explanation:

The reaction that takes place is:

HA + NaOH → NaA + H₂O

Where HA is the unknown weak acid.

At the equivalence point all HA moles are converted by NaOH. First we calculate how many NaOH moles reacted, using the given concentration and volume:

0.0500 M NaOH * 14.2 mL = 0.71 mmol NaOH

That means that in 4.00 mL of the weak acid solution, there were 0.71 weak acid mmoles. With that in mind we can now calculate the concentration:

0.71 mmol HA / 4.00 mL = 0.1775 M

What is the phase of water at 0.25 atm and 0°C?
Water
(liquid)
Pressure (atm)
0.5-
0.25
Ice
(solid)
Water vapor
(gas)
0
000
Temperature (°C)
O A. Gas
O B. Solid and gas
O C. Solid and liquid
D. Solid

Answers

It should be a because the temperature and the atm are to low

Water is in the solid phase at 0.25 atm and 0°C.

In what phase is water at 25?

A pressure of 50 kPa and a temperature of 50 °C correspond to the “water” region—here, water exists only as a liquid. At 25 kPa and 200 °C, water exists only in the gaseous state.

What phase is water in at 0 C?

Under standard atmospheric conditions, water exists as a liquid. But if we lower the temperature below 0 degrees Celsius, or 32 degrees Fahrenheit, water changes its phase into a solid called ice.

Learn more about the solid phase here https://brainly.com/question/13396621

#SPJ2

Please help me, I don't bite. 3.

Answers

Answer:

jjjjjjjjj

Explanation:

hhhhhhhhhhh

A buffer is prepared containing 0.75 M NH3 and 0.20 M NH4 . Calculate the pH of the buffer using the Kb for NH3. g

Answers

Answer:

pH=8.676

Explanation:

Given:

0.75 M [tex]NH_{3}[/tex]

0.20 M [tex]NH_{4}[/tex]

The objective is to calculate the pH of the buffer using the kb for [tex]NH_3[/tex]

Formula used:

[tex]pOH=pka+log\frac{[salt]}{[base]}\\[/tex]

pH=14-pOH

Solution:

On substituting salt=0.75 and base=0.20 in the formula

[tex]pOH=-log(1.77*10^{-5})+log\frac{0.75}{0.20}\\ =4.75+0.5740\\ =5.324[/tex]

pH=14-pOH

On substituting the pOH value in the above expression,

pH=14-5.324

Therefore,

pH=8.676

Name the following aldehyde PLEASE PLEASE HELP

Answers

Answer:

Explanation:

Answer is D 2,5-dimethylheptanal

You should accern the lowest possible number close to the parent name

A gas mixture is made by combining 8.7 g each of Ar, Ne, and an unknown diatomic gas. At STP, the mixture occupies a volume of 17.28 L. What is the molar mass of the unknown gas

Answers

Answer: Molar mass of the unknown gas is 73.153 g/mol.

Explanation:

Given: Mass of each gas = 8.7 g

Volume = 17.28 L

Let us assume that the molar mass of gas is m g/mol.

Molar mass of Ar is 40 g/mol and Ne is 20 g/mol.

Hence, total moles of each gas are as follows.

[tex](\frac{8.7}{40} + \frac{8.7}{20} + \frac{8.7}{m}) mol[/tex]

At STP, the total volume of these gases is as follows.

[tex](\frac{8.7}{40} + \frac{8.7}{20} + \frac{8.7}{m}) mol \times 22.4 L = 17.28 L\\(\frac{8.7}{40} + \frac{8.7}{20})22.4 L + \frac{8.7}{m} \times 22.4 L = 17.28 L\\14.616 + \frac{8.7}{m} \times 22.4 L = 17.28 L\\\frac{8.7}{m} \times 22.4 L = (17.28 L - 14.616)\\\frac{8.7}{m} \times 22.4 L = 2.664 \\m = 73.153 g/mol[/tex]

Thus, we can conclude that molar mass of the unknown gas is 73.153 g/mol.

Nickel + oxygen = nickel oxide. What is the balanced redox reaction?

Answers

Answer:

This is an oxidation-reduction (redox) reaction:

2 Ni0 - 4 e- → 2 NiII

(oxidation)

2 O0 + 4 e- → 2 O-II

(reduction)

Ni is a reducing agent, O2 is an oxidizing agent.

Please help me ASAP I’ll mark Brainly

Answers

Answer:

cell

chloroplast and cell wall

nucleus

life processes

cell membrane

shape and size

vacuole

Hope it helps


Essentially all of the mass of an atom is due to the?
nucleons
electrons.
protons
Neutrons

Answers

Answer:

nucleons

Explanation:

The answer to the question is nucleons. Because there are both protons and neutrons in the nucleon, it will be heavier. Also, protons and neutrons are much heavier than the weight of an electron, because electrons float around the atom so it is not the answer. So, our final answer is actually option A.

When we react a weak acid with a strong base of equal amounts and concentration, the component of the reaction that will have the greatest effect on the pH of the solution is: Select the correct answer below:_________
a. the reactant acid
b. the reactant base
c. the conjugate acid of the strong base
d. the conjugate base of the weak acid

Answers

Answer:

d. the conjugate base of the weak acid

Explanation:

The strong base (BOH) is completely dissociated in water:

BOH → B⁺ + OH⁻

The resulting conjugate acid (OH⁻) is a weak acid, so it remains in solution as OH⁻ ions.

By other hand, the weak acid (HA) is only slightly dissociated in water:

HA ⇄ H⁺ + A⁻

The resulting conjugate base (A⁻) is a weak base. Thus, it reacts with H⁺ ions from water to form HA, increasing the concentration of OH⁻ ions in the solution.

Therefore, the resulting solution will have a pH > 7 (basic).

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