Oxidation of a dithiol such as 2,5-hexanedithiol forms a six-membered ring containing a disulfide group as part of the ring. Draw the structure of this cyclic disulfide (Hint: Draw the starting compound in line structure format first).

Answers

Answer 1

Answer:

See picture below

Explanation:

In general terms, oxidation of thiol are rather different than oxidations with alcohols.

A dithiol is a molecule that has two thiols in an organic compound. In the case of the 2,5 hexanedithiol, we have the thiols in the carbon 2 and carbon 5.

When oxidation of thiols occurs, and depending of the number of thiols in the molecule, the final compound will have a sulfide group.

This is because the oxydation makes that the hydrogen atom of the sulfur is substracted. So, in the case of the dithiols, we have that both hydrogen atoms are substracted and then, they are available to join. Therefore, As the thiols are in the same molecule, it will occur a self condensation reaction.

The picture below will show the final product.

Hope this helps

Oxidation Of A Dithiol Such As 2,5-hexanedithiol Forms A Six-membered Ring Containing A Disulfide Group
Answer 2

Oxidation of a dithiol such as 2,5-hexanedithiol forms a six-membered ring containing a disulfide group as part of the ring. The structure of the cyclic disulfide that is 2,5-hexanedione is shown below.

Oxidation is a chemical reaction that involves the loss of electrons by a molecule, atom, or ion. This process results in an increase in the oxidation state of the species undergoing oxidation.

The oxidation of 2,5-hexanedithiol is a chemical reaction in which the thiol [tex]\rm (-SH)[/tex] groups of the molecule are converted into disulfide[tex]\rm (-S-S-)[/tex] bonds, resulting in the formation of 2,5-hexanedione. This reaction usually requires an oxidizing agent, such as hydrogen peroxide or nitric acid.

Therefore, the structure of cyclic disulfide(2,5-hexanedione) is shown below.

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Oxidation Of A Dithiol Such As 2,5-hexanedithiol Forms A Six-membered Ring Containing A Disulfide Group

Related Questions

The octane number of gasoline is a measure of octane activity. The octane activity is determined by comparing the engine performance using gasoline and known mixtures of isooctane and n-heptane.

a. True
b. False

Answers

Answer:

A. True

Explanation:

The octane number is determined by comparing the characteristics of gasoline to isooctane (2,2,4-trimethylpentane) and heptane. The correct option is option A.

Basically, the higher the octane  number, the  greater the resistance of the gasoline to knocking.

Why do clumps of particles have slower reaction rates than particles that are separated?

Answers

Explanation:

Cause the clumps are so compacted together that it is harder to brake apart but the one that are separated are easy cause they do not have all the pressure on them and when they go to add reaction it is faster

Choose the aqueous solution below with the highest freezing point. These are all solutions of nonvolatile solutes and you should assume ideal van't Hoff factors where applicable.
(i) 0.200 m HOCH2CH2OH
(ii) 0.200 m Ba(NO3)2
(iii) 0.200 m K3PO3
(iv) 0.200 m Ca(CIO4)2
(v) These all have the same freezing point.

Answers

Answer:

0.200 m K3PO3

Explanation:

Let us remember that the freezing point depression is obtained from the formula;

ΔTf = Kf m i

Where;

Kf = freezing point constant

m = molality

i = Van't Hoff factor

The  Van't Hoff factor has to do with the number of particles in solution. Let us consider the  Van't Hoff factor for each specie.

0.200 m HOCH2CH2OH - 1

0.200 m Ba(NO3)2 - 3

0.200 m K3PO3 - 4

0.200 m Ca(CIO4)2 - 3

Hence, 0.200 m K3PO3 has the greatest van't Hoff factor and consequently the greatest freezing point depression.

Scoring Scheme: 3-3-2-1 Part II. You considered the properties of two acid-base indicators, phenolphthalein and methyl orange. Many indicators are weak acids in water and establish the equilibrium: HIn(aq)(Color 1) H2O(l) H3O (aq) In-(aq)(Color 2). Indicators change color depending on whether they are in a protonated (HIn) or unprotonated (In-) form. What is the equilibrium expression for the phenolphthalein indicator in water and what colors are the protonated and unprotonated forms of the indicator

Answers

Answer:

Explanation:

Phenolphthalein is a protonated indicator and methyl orange is a basic indicator having hydroxyl ionisable part .

Phenolphthalein can be represented by the following formula

HPh  which ionizes in water as follows

       HPh        + H₂O      ⇄    H₃O⁺      +        Ph⁻

( colourless  )                    ( pink  )

In acidic solution it is in the form of protonated Hph form which is colourless

In basic medium , it ionises to give H₃O⁺ and unprotonated  Ph⁻ whose colour is pink .

Rank the effective nuclear charge Z* experienced by a valence electron in each of these atoms:

atom Z* experienced by a valence electron.
An atom of carbon.
An atom of fluorine.
An atom of beryllium.
An atom of boron.

Answers

Answer:

The atoms are ranked in decreasing order as follows:

Fluorine ---4

Carbon ----3

Boron ------2

Beryllium --1

Explanation:

Effective nuclear charge (Zeff) is defined as the difference between the actual nuclear charge (the atomic number, Z) and the shielding constant (S).

It is calculated by finding the atomic number and electronic configuration, attributing a shielding value to each electron, adding all the shielding values and using the formula:

                 Z eff = Z - S

Effective nuclear charges:

An atom of carbon: 3.25

An atom of fluorine: 5.20

An atom of beryllium: 1.95

An atom of boron: 2.60

What happens during ice wedging

Answers

Frost wedging happens when water gets in crack, freezes, and expands. This process breaks rocks apart. When this process is repeated, cracks in rocks get bigger and bigger and may fracture, or break, the rock.

Hope this helps :)

Answer:water expands as it goes from liquid to solid.

Explanation:

The temperature is warm , water works it’s way to to cracks in rock

A diver planning to dive to a depth of 100 ft can choose to breathe air that is a mixture of oxygen, nitrogen, and helium. If the total pressure of the air in the tank is 3040 mm Hg , and the partial pressures of O2 and He are 304 mm Hg and 1520 mm Hg , respectively, what is the partial pressure of N2

Answers

Answer:

1216 mmHg = Partial pressure N₂

Explanation:

In a mixture of n gases, the partial pressure of each compound follows the equation:

Total pressure = Partial pressure n₁ + Partial pressure n₂ + Partial pressure n₃ + Partial pressure n₄ + Partial pressure n₅ + ... + Partial pressure nₙ

In a mixture of O₂, He and N₂, the total pressure = 3040mmHg is defined as:

3040 mmHg = Partial pressure O₂ + Partial pressure He + Partial pressure N₂

Replacing:

3040 mmHg = 304 mmHg + 1520 mmHg + Partial pressure N₂

3040 mmHg = 1824 mmHg + Partial pressure N₂

1216 mmHg = Partial pressure N₂


b) All atoms contain
charged electrons.

Answers

Answer:

b) All atoms contain

charged electrons.

Explanation:

A catalyst will

a) Increase the reaction rate

b) Move the equilibrium to the right

c) Be consumed by the reaction

d) Increase the activation energy

Answers

Answer:

increase the chemical rate

Which components of the apparatus affect in motion? If you answer this and it has non to do with the question imma report u!!!!

Answers

Answer:

Explanation:

An internal force acts between elements of the system. Only external forces affect the motion of a system, according to Newton's first law. Newton's second law states that a net force on an object is responsible for its ... Prior to manned space flights, rocket sleds were used to test aircraft, missile equipment, and physiological

When you remove energy from air or land it makes the temperature

Answers

Understanding how heat is transferred from the outdoors into your home and from your home to your body is important for understanding the challenge of keeping your house cool. Understanding the processes that help keep your body cool is important in understanding cooling strategies for your home.

Principles of Heat Transfer

Heat is transferred to and from objects -- such as you and your home -- via three processes: conduction, radiation, and convection.

Conduction is heat traveling through a solid material. On hot days, heat is conducted into your home through the roof, walls, and windows. Heat-reflecting roofs, insulation, and energy efficient windows will help to reduce that heat conduction.

Radiation is heat traveling in the form of visible and non-visible light. Sunlight is an obvious source of heat for homes. In addition, low-wavelength, non-visible infrared radiation can carry heat directly from warm objects to cooler objects. Infrared radiation is why you can feel the heat of a hot burner element on a stovetop, even from across the room. Older windows will allow infrared radiation coming from warm objects outside to radiate into your home; shades can help to block this radiation. Newer windows have low-e coatings that block infrared radiation. Infrared radiation will also carry the heat of your walls and ceiling directly to your body.

Convection is another means for the heat from your walls and ceiling to reach you. Hot air naturally rises, carrying heat away from your walls and causing it to circulate throughout your home. As the hot air circulates past your skin (and you breathe it in), it warms you.

Cooling Your Body

Your body can cool down through three processes: convection, radiation, and perspiration. Ventilation enhances all these processes. You can also cool your body via conduction -- some car seats now feature cooling elements, for instance -- but this is not generally practical for use in your home.

Convection occurs when heat is carried away from your body via moving air. If the surrounding air is cooler than your skin, the air will absorb your heat and rise. As the warmed air rises around you, cooler air moves in to take its place and absorb more of your warmth. The faster this convecting air moves, the cooler you feel.

Radiation occurs when heat radiates across the space between you and the objects in your home. If objects are warmer than you are, heat will travel toward you. Removing heat through ventilation reduces the temperature of the ceiling, walls, and furnishings. The cooler your surroundings, the more you will radiate heat to the objects, rather than the other way around.

Perspiration can be uncomfortable, and many people would prefer to stay cool without it. However, during hot weather and physical exercise, perspiration is the body's powerful cooling mechanism. As moisture leaves your skin pores, it carries a lot of heat with it, cooling your body. If a breeze (ventilation) passes over your skin, that moisture will evaporate more quickly, and you'll be even cooler.

Hope this helps

Indicate whether each statement is true or false.

a. When a solution is made, the enthalpy of mixing is always a positive number.
b. An increase in entropy favors mixing.
c. A solute will dissolve in a solvent if solute-solute interactions are stronger than solute-solvent interactions.

Answers

Answer: a. False.

b. True

c. False

Explanation:

a. When a solution is made, the enthalpy of mixing is always a positive number.

This is false. It should be noted that the nature of reaction determine the enthalpy which can either be positive or can be negative.

b. An increase in entropy favors mixing.

This is true because when molecules get randomly distributed, they mix with one another. Therefore, an increase in entropy favors mixing.

c. A solute will dissolve in a solvent if solute-solute interactions are stronger than solute-solvent interactions.

This is false. This is because the solute-solute interactions have to be weaker and not stronger.

a. When a solution is made, the enthalpy of mixing is always a positive number. FALSE

b. An increase in entropy favors mixing. TRUE

c. A solute will dissolve in a solvent if solute-solute interactions are stronger than solute-solvent interactions. FALSE

Entropy

Entropy is the measure of a system's thermal energy per unit temperature that is unavailable for doing useful work

Entalphy

Enthalpy is the sum of the system's internal energy and the product of its pressure and volume.

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C3H8 (g)+ 502 (g)  3CO2 (g) + 4 H2O (g) + 531 kcal

Answers

Answer:

Exotérmica.

Explanation:

¡Hola!

En este caso, dado que la mayoría de reacciones de combustión son exotérmicas, al generar calor en los productos, es posible inferir que esta reacción, referida a la combustion de metano es exotérmica debido a lo anteriormente mencionado, ya que el término de energía de reacción, 531 kcal, está al lado de los productos, lo que quiere decir que es energía generada.

¡Saludos!

PLEASE PLEASE HELP!!!

Click an item in the list or group of pictures at the bottom of the problem and, holding the button down, drag it into the
correct position in the answer box. Release your mouse button when the item is place. If you change your mind, drag
the item to the trashcan. Click the trashcan to clear all your answers.
Make a Punnett Square for two smooth seed hybrid pea plants (Ss)
Click once to select an item at the bottom of the problem.
Click again to drop the item in its correct place.
S
SS SS SS S

Answers

the top middle box is S, to the right of it is s, middle row left box is S, middle row middle box is SS, middle row right box is Ss, bottom row left box is s, bottom row middle box is Ss, and bottom row right box is ss

What describes how a liquid flows and diffuses?

A: Fluidity

B: Viscosity

C: Surface tension

D: Condensation

Answers

The answer is option is a fluidity

Answer:

A. According to the kinetic-molecular theory of liquids, the particles are not bound together in fixed positions; instead they move about constantly giving them their fluidity

If 50 ml of 0.235 M NaCl solution is diluted to 200.0 ml what is the concentration of the diluted solution

Answers

This is a straightforward dilution calculation that can be done using the equation

[tex]M_1V_1=M_2V_2[/tex]

where M₁ and M₂ are the initial and final (or undiluted and diluted) molar concentrations of the solution, respectively, and V₁ and V₂ are the initial and final (or undiluted and diluted) volumes of the solution, respectively.

Here, we have the initial concentration (M₁) and the initial (V₁) and final (V₂) volumes, and we want to find the final concentration (M₂), or the concentration of the solution after dilution. So, we can rearrange our equation to solve for M₂:

[tex]M_2=\frac{M_1V_1}{V_2}.[/tex]

Substituting in our values, we get

[tex]\[M_2=\frac{\left ( 50 \text{ mL} \right )\left ( 0.235 \text{ M} \right )}{\left ( 200.0 \text{ mL} \right )}= 0.05875 \text{ M}\].[/tex]

So the concentration of the diluted solution is 0.05875 M. You can round that value if necessary according to the appropriate number of sig figs. Note that we don't have to convert our volumes from mL to L since their conversion factors would cancel out anyway; what's important is the ratio of the volumes, which would be the same whether they're presented in milliliters or liters.

HELPPPP PLZ



Using an applied force to move an object in the direction of the force is...


potential energy

the scientific definition of work

none of these

the scientific definition of power

Answers

I believe it is the scientific definition of work, as work = force x distance

Answer:

the scientific definition of work

Explanation:

In physics, work is defined as the use of force to move an object. For work to be done, the force must be applied in the same direction that the object moves.

I hope it helps! ^^

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explain why vapour pressure increases with increasing temperature.​

Answers

As the temperature of a liquid increases, the kinetic energy of its molecules also increases. And as the kinetic energy of the molecules increases, the number of molecules transitioning into a vapor also increases, thereby increasing the vapor pressure.

Compute the value of the molar heat capacity at constant volume, CVCV, for CO2CO2 on the assumption that there is no vibrational energy. (Note: CO2CO2 is linear; SO2SO2 and H2SH2S are not. Recall that a linear polyatomic molecule has two rotational degrees of freedom, and a nonlinear molecule has three.)

Answers

Answer:

Explanation:

Molar heat capacity at constant volume Cv  of a gas = n x .5 R where n is degree of freedom of the gas molecules

CO₂ is a linear molecule , so number of degree of freedom =  3 + 2 = 5

3 is translational and 2 is rotational degree of freedom . There is no vibrational degree of freedom given .

So Cv = 5 / 2 R

= 2.5 R .

How long will it take for the concentration of A to decrease from 0.850 M to 0.205 for the reaction A → Products? (k = 0.0882 M⁻¹s⁻¹)

Answers

Answer:

16.1 s

Explanation:

The reaction,  A → Products, follows first order kinetics.

So,

ln[A] = ln[A]o - kt

Where;

[A] = concentration at time= t

[A]o = initial concentration

k= rate constant

t = time taken

ln(0.205) = ln(0.850) - 0.0882t

ln(0.205) -  ln(0.850) = - 0.0882t

-1.5847 - (-0.1625) = - 0.0882t

-1.5847 + 0.1625 = - 0.0882t

-1.4222 = - 0.0882t

t = -1.4222/- 0.0882

t = 16.1 s

Based on first order kinetics, the time taken for the concentration of A to decrease from 0.850 M to 0.205 M is 16.1 seconds.

What is order of a reaction?

The order of a reaction refers to the relationship between the rate of a reaction and the the concentration of each reactant.

For a first-order reaction, the rate is dependent on the concentration of a single species.

The reaction,  A → Products is a first order reaction.

Therefore, using the first order kinetics equation

ln[A] = ln[A]° - kt

Where;

[A] = concentration at time= t[A]° = initial concentrationk= rate constantt = time taken

Substituting the values:

ln(0.205) = ln(0.850) - 0.0882t

ln(0.205) -  ln(0.850) = - 0.0882t

-1.5847 - (-0.1625) = - 0.0882t

-1.5847 + 0.1625 = - 0.0882t

-1.4222 = - 0.0882t

t = -1.4222/- 0.0882

t = 16.1 s

Therefore, the time taken for the concentration of A to decrease from 0.850 M to 0.205 M is 16.1 seconds.

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Density of water is affected by (select all that apply)

A) Animals that life in the area
B) Salinity (salt concentration)
C) Temperature of water
D) Amount of plants in an area
E) How close the water is to land

Answers

Density of water is affected by, Temperature of water, and I also think How close the water is to land.
Hope this helped!

What is the overall reaction order for a reaction with the following rate law?
Rate =
k[BrO 3 ][Br][ht]2

Answers

Answer:

4

Explanation:

In a rate law, The reaction order is basically the superscript (power) of the concentration of the reaction. It defines the extent to which the rate of the reaction depends on the concentration of the reaction.

In this rate law, the order of the reactants are;

[BrO3] = 1

[Br] = 1

[ht] = 2

The overall reaction order is the sum total of the individual orders. We have;

1 +1 + 2 = 4

Which term is used to describe the variety
of inheritable traits in a species?

Ecosystem diversity

Genetic diversity

Natural selection

Species diversity

Answers

Genetic diversity.

Genetic diversity refers to genetic variability within species. Each individual species possesses genes which are the source of its own unique features: In human beings, for example, the huge variety of people's faces reflects each person's genetic individuality.

So, Ecosystem Diversity is a term that describes how different habitats of organisms are. For example, the fact that our planet has deserts, tundras but also estuaries is a sign of the diversity of its ecosystems. Species diversity refers to the number of different species that inhabit a specific ecosystem or the whole biosphere; the more, the better for species diversity. Genetic diversity is the term we are looking for; it means the variation in genes (usually in one species) that leads to different inheritable traits (in members of the same species). For example eye color is an inheritable trait that showcases genetic diversity since there are many genes that determine a different color such as brown, blue, green etc. (even though the environment plays a role too). Finally, natural selection is a theory about the survival of the fittest due to competition. It relates to inheritable traits and their diversity but it does not describe them.

Nuclear energy could come from
A
kicking a soccer ball.

B
heat inside the Earth.

C
splitting atoms apart.

D
solar panels.

Answers

Answer:

C Splitting atoms apart

The answer would be C.splitting atoms apart

Hope this helps

Have a great day/night

The act of changing something but not being able to change it back

Answers

I would assume it would be impossible or unlikely


What is the cathode ray? How was the Nature of cathode rays determined?​​

Answers

Answer:

Cathode rays are streams of electrons observed in discharge tubes. In 1897, British physicist J. J. Thomson showed that cathode rays were composed of a previously unknown negatively charged particle, which was later named the electron. Cathode-ray tubes (CRTs) use a focused beam of electrons deflected by electric or magnetic fields to render an image on a screen.

What is the Chemical formula for Hexacarbon octaphosphide?

Answers

Answer:C6P8

Explanation:

Forensic scientists encounter few drug investigations in their work.
True
False

Answers

Answer:

false

Explanation:

What is the M, of C3H,COONa? A: Na = 23; C = 12, 0 = 16:
110
87
98
103​

Answers

Answer: Molecular mass of [tex]CH_3COONa[/tex] is 82 g

Explanation:

Molecular mass (M) is defined as the mass in grams of 1 mole of a substance.

S.I Unit of Molar mass is gram per mole and it is represented as g/mol.

Atomic Mass of Carbon (C) = 12 g

Atomic Mass of hydrogen (H) = 1 g

Atomic Mass of oxygen (O) = 16 g

Atomic Mass of sodium (Na) = 23 g

Molecular mass of [tex]CH_3COONa[/tex] = 12(1)+1(3)+12(1)+16(2)+23(1) = 82 g

One mole of a metallic oxide reacts with one mole of hydrogen to produce two moles of the pure metal
and one mole of water. 5.00 g of the metallic oxide produces 2.32 g of the metal. What is the metallic
oxide? (Use molar masses)

Answers

Answer:

Lithium oxide, Li₂O.  

Explanation:

Hello!  

In this case, according to the given amounts, it is possible to write down the chemical reaction as shown below:

[tex]M_2O+H_2\rightarrow 2M+H_2O[/tex]  

Which means that the metallic oxide has the following formula: M₂O. Next, we can set up the following proportional factors according to the chemical reaction:

 

Thus, we perform the operations in order to obtain:

[tex]\frac{10X}{(2X+16)}=2.32[/tex]  

So we solve for x as shown below:

[tex]10X=2.32(2X+16)\\\\10X=4.64X+37.12\\\\X=\frac{37.12}{10-4.64}\\\\X= 6.93g/mol[/tex]  

Whose molar mass corresponds to lithium, and therefore, the metallic oxide is lithium oxide, Li₂O.  

Best regards!

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