Compounds of copper(II) are generally colored, but compounds of copper(I) are usually colorless. Use crystal field theory to explain why this is true.

Answers

Answer 1

Answer:

See explanation

Explanation:

The crystal field theory assumes the interaction between the central metal ion and ligands to be purely electrostatic.

The five d orbitals remain degenerate until they are surrounded by ligands which split the degeneracy of the d orbitals depending on the crystal fields formed to give either square planar, octahedral, tetrahedral or other kinds of crystal fields.

The electronic configuration of Cu II ion is 1s2 2s2 2p6 3s2 3p6 3d9. Its colour arises from an incomplete d orbital which makes d - d electron transition possible.

On the other hand, the electron configuration of copper I is  1s2 2s2 2p6 3s2 3p6 3d10. We can see that the d orbital is completely filled. Hence copper I ion has no color due to its completely filled d- orbitals


Related Questions

The half-life of the radioactive isotope Carbon-14 is about 5730 years.

a. What percentage of the original amount of Carbon-14 is left after 20,000 years?
b. If an old wooden tool is found in a cave and the amount of Carbon-14 present in it is estimated to be only 42% of the original amount, approximately how old is the tool?
c. Radiocarbon dating is not as easy as these exercises might lead you to believe. With the help of your classmates, research radiocarbon dating and discuss why our model is somewhat over-simplified.

Answers

Answer:

See explanation for details

Explanation:

a) Now from the data given, recall that;

N/No = (1/2)t/t1/2

Where,

N= amount of radioactive material remaining at time t

No= Amount of radioactive material originally present

t= time taken for N amount of radioactive material to remain

t1/2= half life of radioactive material

So,

N/No = (1/2)^20,000/5730

N/No = (1/2)^3.49

N/No = 0.089

Since the fraction N/No is the fraction remaining after t years, then;

Percentage of Carbon-14 left after 20,000 years = 0.089 * 100 = 8.9%

b) From;

0.693/t1/2 = 2.303/t log No/N

Given that N = 0.42 No

Hence;

0.693/5730 = 2.303/t log (No/0.42No)

1.21 * 10^-4 = 0.87/t

t= 0.87/1.21 * 10^-4

t = 7190 years

c) Radiocarbon dating is a method of obtaining the age of an object derived from plants or animals by comparing the Carbon-14 activity of living things with that of the sample under study. Due to contamination, the age of artifacts obtained by Carbon-14 dating may yield outlying figures.

Find the Molarity of 6.25 grams of barium nitrate dissolved in 250 mL solution.

Answers

Answer:

0.0956 M

Explanation:

Step 1: Calculate the moles corresponding to 6.25 g of barium nitrate (solute)

The molar mass of barium nitrate is 261.34 g/mol.

6.25 g × 1 mol/261.34 g = 0.0239 mol

Step 2: Convert the volume of solution to liters

We will use the conversion factor 1 L = 1000 mL.

250 mL × 1 L/1000 mL = 0.250 L

Step 3: Calculate the molarity of the solution

The molarity is equal to the moles of solute divided by the liters of solution.

M = 0.0239 mol / 0.250 L = 0.0956 M

Determine the total number of electrons in the d orbitals of an atom of tin, Sn (Z = 50).

Answers

Answer:

Explanation:

Sn (Z = 50 )

Electronic configuration = [Kr] 4d¹⁰5s²5p²

= 1s²2s²p⁶3s²3p⁶3d¹⁰4s²4p⁶4d¹⁰5s²5p²

So , total number of electrons in d orbital = 10 + 10 = 20 .

Is mass conserved when neutralisation takes place? That is, is the total mass of the acid and alkali equal to the total mass of
the products, salt and water?​

Answers

Answer:

Yes

Explanation:

yes, this is in every chemical reaction (except nuclear reaction) and Is known as "law of conservation of mass"

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A 1.9450 g sample containing only Na2CO3 (F.M. 105.99) and NaHCO3 (F.M. 84.01) is titrated with 35.31 mL of 0.8724 M HCl. Calculate the percentage sodium carbonate and sodium bicarbonate.

Answers

Answer:

1.0979g of Na2CO3

0.8471g of NaHCO3

Explanation:

NaHCO3 and Na2CO3 reacts with HCl as follows:

NaHCO3 + HCl → NaCl + H2O + CO2

Na2CO3 + 2HCl → 2NaCl + H2O + CO2

Moles of HCl required were:

0.03531L * (0.8724mol / L) = 0.03080 moles of HCl

With this information we can write 2 equations:

1.9450g = X + Y (1)

X is the mass of NaHCO3 and Y is mass of Na2CO3

Also we can write:

0.03080 moles = X/84 + 2Y/106 (2)

Where 84 is molar mass of NaHCO3 and 106 is molar mass of Na2CO3, 2 is due the reaction (2 moles of HCl react per mole of Na2CO3)

Replacing (1) in (2):

0.03080 moles = (1.9450-Y)/84 + 2Y/106

0.03080 = 0.023155 - Y/84 + Y/53

0.007645 = 0.00696316Y

Y = 1.0979g of Na2CO3

And mass of NaHCO3 =

1.9450g - 1.0979g =

0.8471g of NaHCO3

What is the cathode in an electrochemical cell?​

Answers

Answer: The cathode is the electrode where reduction (gain of electrons) takes place (metal-B electrode)

Answer: The electrode where reduction occurs.

Before a chemical reaction, the total mass of two reactants is measured to be 40 grams.
After the reaction, what should be the total mass of the products?
A. 0 grams
B. 20 grams
C. 40 grams
D. 80 grams

Answers

C.40g ...................

The total mass of the products is 40 grams (Option C).

In 1789, Antoine Lavoisier discovered that mass is neither created nor destroyed in chemical reactions. This is now known as Lavoisier's law of conservation of mass. In other terms, the sum of the masses of the reactants is equal to the sum of the masses of the products. So, in this case, the total mass of the products must be 40 grams as well.

The total mass of the products is 40 grams.

You can learn more about Lavoisier's law here: https://brainly.com/question/11429078

How do you know about a substance if you know its temperature


A. How heavy the substance is

B. How large or small the particles of the substance are

C. How hot or cold the substance is

D. How many particles are in the substance

Answers

Answer:

How hot or cold the substance is

Explanation:

You can do a lot with just the temperature of a substance. Chemists can use this to identify the substance because of the temperature at which it melts. They can then find out how long it took to melt, which can also help.

Answer:c how hot or cold

Explanation:

3. A calibration curve plotting E vs. pNi is used to measure the concentration of Ni2+ in solution at 25 °C using a solid Ni electrode. What is the slope of the calibration curve?

Answers

Answer: the slope of the calibration curve is - 0.0295

Explanation:

as things are not under standard conditions that is;  1M of each reactants at T = 25°C and P = 1 atm; therefore we will use the Nernst Equation.

E = a × pNi + b

a is the slope

pNi = -log [Ni²⁺] = log 1/[Ni²⁺]

therefore the Half reaction;

Ni²⁺ (aq) + 2e⁻ = Ni (s)

here; E = E₀ + RT/zF ln[Ni²⁺]

we know that;

gas constant R = (8.31 J/mol-K)

absolute temperature T =25°C =  298 K

number of moles of electrons transferred by the cell's reaction z  = 2

F is Faraday constant, = 9.64853399(24)×10⁴ C mol−1

E₀ = b

RT/zF ln[Ni²⁺] = alog 1/[Ni²⁺]

Logx = Ln x / Ln 10 = Ln (x/2.3)

so

a = (RT/zF ln[Ni²⁺])/log 1/[Ni²⁺]

= (RT/zF ln[Ni²⁺]) / ((ln 1/[Ni²⁺]) / 2.3)  

= (2.3RT/zF ln[Ni²⁺]) / (ln 1/[Ni²⁺])

= (2.3RT/zF ln[Ni²⁺]) / (-ln [Ni²⁺])

= -2.3RT/zF

so we substitute

= (-2.3 × 8.31 ×298 ) / (2 × 9.64853399(24) × 10⁴)

= - 0.0295

therefore the slope of the calibration curve is - 0.0295

What is the primary cause of diffusion? some substances can dissolve in solvents heat added to a substance random internal motion of atoms and molecules attraction of opposite atomic charges

Answers

Answer:

random internal motion of atoms and molecule

Explanation:

The primary cause of diffusion is the random internal motion of atoms and molecules.

Randomness of atoms and molecules results in diffusion.

Diffusion is the movement of particles from a region of high concentration to that of lower concentration. Substances often tend to spread out over the concentration gradient. Therefore, they have this propensity to be randomized.

Answer:

random internal of motion of atoms and molecules

Explanation:

took assignment on odyssey ware

What must be true about two objects for conduction to take place?
The objects must be different temperatures and they must be in contact.
The objects must be the same temperature and they must be in contact
The objects must be different temperatures and they must be insulators.
O The objects must be the same temperature and they must be insulators.

Answers

Answer:

The objects must be different temperatures and they must be in contact.

Explanation:

For conduction to take place between two objects, they must be in contact with one another and at different temperatures.

Generally, heat transfer takes place over a gradient i.e. from a region of higher temperature to one with a low temperature. If two places or bodies have the same temperature, heat transfer will not take place. In conduction, the two bodies must be in contact with one another. The collision of molecules of one body transfers this kinetic energy to the other one in contact with it.

Answer:

The objects must be different temperatures and they must be in contact.

Explanation:

Got a 100% on edge 2020

HOPE THIS HELPS!!!

two atoms bonded together will remain some distance apart minimizing the A. Number of valence electrons in the bond. B. Potential energy of the bond. C.partial charge of the bond D.bond distance​

Answers

Answer:

Answer is the number of the c

How does heat energy help change shape of metals?

Metals releases heat energy to be able to be shaped.
Heat energy provides more pressure that allows metals to bend.
Heat energy allows metal to become more malleable.
Metals require a lot of heat energy to be destroyed.

Answers

Answer: 3

Explanation:

It speed up the molecules to get them to bent and move instead of staying solid

Answer:

c

Explanation:

When enough heat energy is transferred to a metal, the molecules vibrate quickly enough so that the solid metal starts to change shape.

How many milliliters of an aqueous solution of 0.227 M sodium carbonate is needed to obtain 3.55 grams of the salt?

Answers

Answer:

147.6 mL .

Explanation:

sodium carbonate , Na₂CO₃

Molecular weight = 106

3.55 gm of sodium carbonate = 3.55 / 106

= .0335 moles

Let the volume of litre required = V

V litre of .227 M solution will contain

V x .227 moles of sodium carbonate . So

V x .227 = .0335

V = .1476 L

= 147.6 mL .

Heptane (C7H16) is a hydrocarbon fuel used for gas barbecues. Balance the chemical equation (given below) for the reaction that occurs when heptane burns in air. What are the coefficients in the balanced equation

Answers

Answer:

a = 1, b = 11, c = 7, d = 8

Explanation:

aC7H16 + bO2 ------> cCO2 + dH2O

1 C7H16 + 11 O2 ------> 7 CO2 + 8H2O

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From which type of clouds do hail pellets form?

Answers

Answer:

Hail pallets forms inside of cumulonimbus clouds

Explanation:

Answer: cumulonimbus hope it helps pls stay safe

2. How many orbitals are in the following sublevels?
a. ls
b. 5s
c. 4d
d. 4f
e. 7s
f. 3p

Answers

This answer would be a

A flask of ammonia is connected to a flask of an unknown acid HX by a 1.68 m glass tube (where "X" represents a halogen). As the two gases diffuse down the tube, a white ring of NH4X forms 115 cm from the ammonia flask. Identify element X (Name or symbol).

Answers

Answer:

Explanation:

white ring of NH₄X is formed . Here X is Cl and

NH₄X is NH₄Cl ( ammonium chloride )

The reaction is as follows

NH₃ + HCl = NH₄Cl ( white fume )

The acid that reacts with ammonia has been Hydrochloric acid (HCl), and the element X in the acid has been Chlorine (Cl).

The ammonia has been the gas with the pungent smell. It has been the compound with the dihybrid element used for the production of various nitrogen compounds.

The reaction of Ammonia with acid results in the formation of ammonium ions. The ions on reacting with the basic part of the acid, form the salt and give the product.

The white ring with the reaction of ammonia has been formed of the ammonium chloride. Thus the acid that reacts with ammonia has been Hydrochloric acid (HCl), and the element X in the acid has been Chlorine (Cl).

For more information about ammonia, refer to the link:

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Select the correct answer.
Which letter represents the wavelength of the wave?
c
ОА а
OB. b
ОС, с
OD d

Answers

Answer:

it is the letter D

Explanation:

Considering the definition of wavelength, the correct answer is option D. You can see that "d" represents the distance between two consecutive highs, and then the wave repeats. In this way the definition of wavelength is fulfilled.

Definition of wavelength

In a periodic wave, that is, for the type of wave that repeats with exactly the same shape every given time interval, the wavelength is the physical distance between two points from which the wave repeats.

That is, the wavelength is its spatial period, that is, the distance at which the waveform repeats itself. Normally, two consecutive points that have the same phase are considered: two maximums, two minimums, two zero crossings (in the same direction).

In summary, the wavelength is the actual distance that a disturbance can travel in a given time interval, the quas between two consecutive maxima with respect to the physical property of the wave.

Letter that represent the wavelength of the wave

Considering the definition of wavelength, the correct answer is option D. You can see that "d" represents the distance between two consecutive highs, and then the wave repeats. In this way the definition of wavelength is fulfilled.

Learn more about wavelength:

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https://brainly.com/question/10728818?source=aidnull

Which graph shows the pressure-temperature relationship for a gas at a fixed volume?
A. Graph D
B. Graph B
C. Graph A
D. Graph C​

Answers

Answer:

The answer is

C. Graph A

Answer:

Graph A

Explanation:

:)

Calculate the mass percent of 0.389 g of silicon (Si) that reacts with oxygen to form 0.832 g silicon dioxide (SiO 2 )

Answers

Answer:

Mass percent of silicon = 46.75% (Approx)

Explanation:

Given:

Mass of silicon = 0.389 g

Mass of silicon dioxide = 0.832 g

Find:

Mass percent of silicon

Computation:

Mass percent of silicon = Mass of silicon / Mass of silicon dioxide

Mass percent of silicon = [0.389 g / 0.832 g]100

Mass percent of silicon = 46.75% (Approx)

what the type of solid materials are typically hard, have high melting pionts and poor electrical conductivities​

Answers

Answer:

Ionic solids

Explanation: Ionic solids—Made up of positive and negative ions and held together by electrostatic attractions. They're characterized by very high melting points and brittleness and are poor conductors in the solid state. An example of an ionic solid is table salt, NaCl.

Answer:

Ionic solids

Explanation:

If 30.0 g of H2SO4 reacts with sodium hydroxide, what mass of water is produced?

Answers

11.02g

Explanation:

mole ratio between H2SO4 and water is 1:2

mole of H2SO4 is 0.306

then the mole of water is 0.612

finally the mole of water is multiplied by 18, the molar mass to get 11.02 g of water

How to atoms share more than one pair of electrons?

Answers

Answer:

A covalent bond is a chemical bond that involves the sharing of electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs, and the stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding.

Explanation:

More than one pair of electrons can be shared between atoms to form double or triple covalent bonds. Unlike ionic bonds, covalent bonds are often formed between atoms where one of the atoms cannot easily attain a noble gas electron shell configuration through the loss or gain of one or two electrons.

Which term describes boron?
A. Metal
B. Metalloid
C. Noble Gas
D. Nonmetal

Answers

Answer:

Boron is Nonmetal

Explanation:

hope it's helped

A solution was prepared by mixing 20.00 mL of 0.100 M and 120.00 mL of 0.200 M. Calculate the molarity of the final solution of nitric acid.

Answers

Answer:

0.186M

Explanation:

First, we need to obtain the moles of nitric acid that are given for each solution. Then, we need to divide these moles in total volume (120mL + 20mL = 140mL = 0.140L) to obtain molarity:

Moles Nitric acid:

0.0200L * (0.100mol / L) = 0.00200 moles

0.120L * (0.200mol / L)= 0.02400 moles

Total moles: 0.02400moles + 0.00200moles = 0.026 moles of nitric acid

Molarity: 0.026 moles / 0.140L

0.186M

When an atom of oxygen forms an ion, what is the most likely charge for that ion?
a. -2
b. -8
C. +2
d. -6

Answers

Answer:

b option is the answer.

Answer:

-2

__________________________________________________________

How many electrons does Oxygen need:

We know that oxygen has an electric configuration of:

2 , 6     [8 electrons]

From the octet rule, we know that all elements try to get to the electronic configuration of the nearest noble gas

In the case of Oxygen, the nearest noble gas is Neon with the electronic configuration:

2 , 8     [10 electrons]

From the above, we can see that oxygen needs 2 more electrons in order to attain the nearest noble gas configuration

What will be the Charge on the ion?:

We know that electrons are negatively charged

Once oxygen gains 2 electrons to attain noble gas configuration, it will have 2 more electrons than it should have

So, the charge on the ion will be -2 since there are 2 extra electrons and both of the electrons contribute a negative charge

Hence, the charge is -2

An element has the mass number 12 and atomic number 6. The number of neutron in it is?
A)6
B)10
C)4
D)8

Answers

Answer:

12-6=6

the answer is A)6

Winds move in the same direction in both southern and northern hemispheres.

Select one:
True
False

Answers

False this is the answer

Answer:

your answer would be false.

Explanation:

prevailing winds blow east-west rather than north-south.

1.1
A sample of oxygen occupies 47.2 L under a pressure of 1240 torr at 25 °C. What
volume would it occupy at 25 °C if the pressure were decreased to 730 torr?​

Answers

Answer:

80.2L

Explanation:

Given parameters:

Initial volume of oxygen = 47.2L

Initial pressure of oxygen = 1240torr

Final pressure  = 730torr

Unknown:

Final volume  = ?

Solution:

To solve this problem, we apply the Boyle's law proposed by Robert Boyle. It states that "the volume of a fixed mass of a gas varies inversely as the pressure changes if the temperature is constant".

Mathematically;

             P₁V₁ = P₂V₂

P and V are pressure and volume

1 and 2 are initial and final states

              1240 x 47.2  = 730 x V₂  

                  V₂  = 80.2L

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