a. Use the following data to calculate the enthalpy of hydration for calcium chloride and calcium iodide.
Lattice Energy* ΔHsoln
CaCl_2(s) -2247 kJ/mol -46 kJ/mol
CaI_2(s) -2059 kJ/mol -104 kJ/mol
*Lattice energy is defined as the energy change for the process M^+(g) + X^-(g) -------> MX(s).
b. Based on your answers to part a, which ion, Cl^- or I^-, is more strongly attracted to water?
O Chloride
O Iodide

Answers

Answer 1

Answer:

A. Enthalpy of hydration of CaCl2 = -2293 KJ/mol

Enthalpy of hydration of CaI2 = -2163 KJ/mol

B. Chloride ions

Explanation:

Enthalpy of hydration is the energy required to convert one mole of gaseous ions to aqueousions.

Enthalpy of hydration = Enthalpy of solution - lattice energy

For CaCl2;

Enthalpy of hydration = -46 - 2247 = -2293 KJ/mol

For CaI2;

Enthalpy of hydration = -104 - 2059 = -2163 KJ/mol

B. Since the enthalpy of hydration of CaCl2 is more negative than that of CaI2, it means that chloride ions are more easily attracted to water molecules. This we conclude because the difference in enthalpy values are due to the negative ions as the two compounds share a common positive calcium ion.

Answer 2

The enthalpy for hydration of calcium chloride is -2293 kJ/mol. The enthalpy for the hydration of calcium iodide is -2163 kJ/mol. The chloride ion Cl^- is more strongly attracted to water than iodide.

The enthalpy of hydration also the enthalpy of solvation is the quantity of energy released when 1 mole of gaseous ion is diluted.

It can be expressed by using the formula:

[tex]\mathbf{\Delta H_{hyd} = \Delta H_{solution} + \Delta H_{LE}}[/tex]

The enthalpy for hydration of calcium chloride can be expressed as:

[tex]\mathbf{\Delta H_{hyd(cacl_2)} = \Delta H_{solution(caci_2)} + \Delta H_{LE(caci_2)}}[/tex]

[tex]\mathbf{\Delta H_{hyd(cacl_2)} = -46 \ kJ/mol +-2247 \ kJ/mol}[/tex]

[tex]\mathbf{\Delta H_{hyd(cacl_2)} =-2293 \ kJ/mol}[/tex]

The enthalpy for the hydration of calcium iodide can be expressed as:

[tex]\mathbf{\Delta H_{hyd(cal_2)} = \Delta H_{solution(caI_2)} + \Delta H_{LE(caI_2)}}[/tex]

[tex]\mathbf{\Delta H_{hyd(cacl_2)} = -104 \ kJ/mol +-2059 \ kJ/mol}[/tex]

[tex]\mathbf{\Delta H_{hyd(cacl_2)} =-2163 \ kJ/mol}[/tex]

From the above calculation, we can see that the enthalpy of hydration of calcium chloride is greater than that of calcium iodide,

Therefore, we can conclude that the chloride ion Cl^- is more strongly attracted to water than iodide.

Learn more about enthalpy of hydration here:

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Related Questions

In the news recently, an individual poured an unknown liquid substance over a female victim and fled on
foot. The victim sustained chemical burns to her face, neck, shoulder, and back (source: NYPD). What
could the unknown substance have been?
water
a base, only
either an acid or a base
an acid, only

Answers

Answer:

either an acid or a base

Explanation:

Especially, concentrated acids and bases tend to do enormous amounts of chemical burns. People usually think its only acids but the strongest of bases can easily melt our skin.

With 21 g of Zinc, and 7 g of CuCl2, how much ZnCl2 is made in grams?

Answers

Answer: 7.07 grams

Explanation:

To calculate the moles :

[tex]\text{Moles of solute}=\frac{\text{given mass}}\times{\text{Molar Mass}}[/tex]    

[tex]\text{Moles of} zinc=\frac{21g}{65g/mol}=0.32moles[/tex]

[tex]\text{Moles of} CuCl_2=\frac{7g}{134g/mol}=0.052moles[/tex]

[tex]Zn+CuCl_2\rightarrow Cu+ZnCl_2[/tex]

According to stoichiometry :

1 mole of [tex]CuCl_2[/tex] require 1 mole of [tex]Zn[/tex]

Thus 0.052 moles of [tex]CuCl_2[/tex] will require=[tex]\frac{1}{1}\times 0.052=0.052moles[/tex]  of [tex]Zn[/tex]

Thus [tex]CuCl_2[/tex] is the limiting reagent as it limits the formation of product and [tex]Zn[/tex] is the excess reagent.

As 1 mole of [tex]CuCl_2[/tex] give = 1 mole of [tex]ZnCl_2[/tex]

Thus 0.052 moles of [tex]CuCl_2[/tex] give =[tex]\frac{1}{1}\times 0.052=0.052moles[/tex]  of [tex]ZnCl_2[/tex]

Mass of [tex]ZnCl_2=moles\times {\text {Molar mass}}=0.052moles\times 136g/mol=7.07g[/tex]

Thus 7.07 g of [tex]ZnCl_2[/tex] will be produced from the given masses of both reactants.

Which type of reaction is the Haber process: N2(g) + 3 H2(g) → 2 NH3(g) + heat? *

exothermic, with an increase in entropy
exothermic, with a decrease in entropy
endothermic, with an increase in entropy
endothermic, with a decrease in entropy

Answers

Answer:

exothermic, with a decrease in entropy

Explanation:

Whenever you produce heat as a product in a reaction, the reaction is exothermic. To determine entropy, we know we have 4 moles of gas on reactant (1 from N2 and 3 from H2) and in produce side we only have two moles (2 from NH3) thus since we are decreasing the number of gas molecules, there is going to be less disorder, hence decrease in entropy.

briefly describe how a potentiometric ph meter works. [Hint describe how the pH meter measures the amount of H+ or OH- ions in a sample]

Answers

Answer:

pH meter measures the degree of acidity or alkalinity in a substance. The H+ ions measures its acidity and the OH- measures the alkalinity.It usually has a voltmeter which is connected to a pH-responsive electrode and a standard electrode which has no degree of variation.

The potentiometric ph meter works functions by measuring the voltage between two electrodes and the result are usually displayed after conversion into the corresponding pH value takes place.

PLEASE HELP BEFORE 7 A.M. PACIFIC TIME
SEE ATTACHED.

Answers

For i: 33mL
For ii: 87-88mL
For iii:22.3mL

Answer:

(i) 32.9 mL; (ii)  37.5 mL; (iii) 21.73 mL

Explanation:

You should always try to read a measuring instrument to a tenth of the smallest scale division.

Here, you are measuring liquids, so you take the scale reading from the bottom of the meniscus.

(i) Graduated cylinder

There are 10 divisions between 30 mL and 40 mL, so each division represents 1 mL.

The level of the liquid appears to be between 32 mL and 33 mL. It is much closer to 33 mL (perhaps right on 33 mL).

You should report the volume to the nearest 0.1 mL. I would read the volume as 32.9 mL, but 32.8 and 33.0 are also acceptable.

Note: If you think the level is right on the 33 mark, you report the volume as 33.0 mL (NOT 33 mL).

(ii) Thermometer

The reading is about half-way between 87 ° and 88 °.

I would report the temperature as 87.5 °, but 87.4 ° and 87.6 ° would also be acceptable.

(iii) Buret

There are 10 divisions between 21 mL and 22 mL, so each division represents 0.1 mL.

You should estimate to the nearest 0.01 mL.

The liquid level is about a third of the way from 21.7 mL to 21.8 mL.

I would report the volume as 21.73 mL, but 21.72 mL and 21.74 mL are also acceptable.

 

An aqueous solution contains 0.30 M potassium fluoride.
One liter of this solution could be converted into a buffer by the addition of:_______.
(Assume that the volume remains constant as each substance is added.)
A. 0.15 mol NaOH
B. 0.30 mol HNO3
C. 0.29 mol HF
D. 0.29 mol KBr
E. 0.15 mol HNO3

Answers

Answer:

A. 0.15 M NaOH, and

E. 0.15 M HNO3

Explanation:

A buffer solution contains a conjugate acid-base pair with both the acid and the base in reasonable concentrations.

NaOH and HNO3 is an acid base pair with relatively equal concentrations. So, they would most likely make a buffer solution.

Watch the video to determine which of the following relationships are correct according to Boyle’s law.
1. PV∝P
2. P∝V
3. PV∝V
4. P∝1V
5. V∝1P
6. V∝P
Part B. Standard temperature and pressure (STP) are considered to be 273 K and 1.0 atm. Predict which of the following changes will cause the volume of the balloon to increase or decrease assuming that the temperature and the gas filling the balloon remain unchanged. Drag the appropriate items to their respective bins.
A. Volume increases
B. Volume decreases
C. Volume is unchanged
Part C. If a certain gas occupies a volume of 20 L when the applied pressure is 10 atm, find the pressure when the gas occupies a volume of 5.0 L. Express your answer to two significant figures, and include the appropriate units.
ki, kf =
Part D. If a certain gas occupies a volume of 18 L when the applied pressure is 9.0 atm , find the pressure when the gas occupies a volume of 4.5 L .Express your answer to two significant figures and include the appropriate units.

Answers

Answer:

Part A

Boyle's Law is given mathematically as

P ∝(1/V) or V ∝(1/P)

Options 4 and 5, if they are properly written.

Part B

At constant temperature, and according to the Boyle's law for an ideal gas,

A. What can cause a Volume increase is a corresponding decrease in pressure.

B. What can cause a Volume decrease is a corresponding increase in pressure.

C. The Volume is unchanged if the pressure of the gas is unchanged too.

Part C

The pressure when the gas occupies a volume of 5.0 L = 40 atm

Part D

The pressure when the gas occupies a volume of 4.5 L = 36 atm

Explanation:

Part A

Boyle's Law states that at constant temperature, the pressure of an ideal gas is inversely proportional to the volume occupied by the gas.

So, mathematically, Boyle's Law is given as

P ∝(1/V) or V ∝(1/P)

Part B

Inverse relationship between two quantities means that the higher the value of one of the quantities go, the lower the value of the other quantity goes and vice versa.

So, at constant temperature, and according to the Boyle's law for an ideal gas.

A. What can cause a Volume increase is a corresponding decrease in pressure.

B. What can cause a Volume decrease is a corresponding increase in pressure.

C. The Volume is unchanged if the pressure of the gas is unchanged too.

Part C

A certain gas occupies a volume of 20 L when the applied pressure is 10 atm, find the pressure when the gas occupies a volume of 5.0 L.

According to Boyle's Law for an ideal gas,

P ∝(1/V)

P = (k/V)

where k is the constant of proportionality

PV = k

Therefore,

P₁V₁ = P₂V₂ = k

P₁ = 10 atm

V₁ = 20 L

P₂ = ?

V₂ = 5.0 L

10 × 20 = P₂ × 5

P₂ = 40 atm

Part D

If a certain gas occupies a volume of 18 L when the applied pressure is 9.0 atm , find the pressure when the gas occupies a volume of 4.5 L

P₁V₁ = P₂V₂ = k

P₁ = 9.0 atm

V₁ = 18 L

P₂ = ?

V₂ = 4.5 L

9 × 18 = P₂ × 4.5

P₂ = 36 atm

Hope this Helps!!!

Tellurium is a period 5 chalcogen. Selenium is a period 4 chalcogen. If the only factor affecting ionization energies was the nuclear charge, then electrons would be easier to remove (ionize) from Se than Te. Experimentally the opposite is true. It takes 941.0 kJ/mol of energy to ionize the outermost electron from Se while it only takes 869.3 kJ/mol to ionize from Te. A good model should account for this. Quantum mechanical calculations do predict this but require access to sophisticated software, large amounts of computing power and technical expertise. Slater suggested that some simple empirical rules that take into account electron electron repulsion (or shielding) could give a good estimate of the effective nuclear charge (Zeff). The Zeff for the outermost electron in Te is . The Zeff for the outermost electrons in Se is . According to Slater's calculation of effective nuclear charge (does or does not) predict the correct ordering of ionization energies for Se and Te. A better means of rationalizing ionization energies is to include the atomic as follows: [Z subscript e f f end subscript over r squared] . For Te, r = 136 pm and for Se r = 117 pm. This new model (does or does not) predict the correct ordering of first ionization energies for Se and Te.

Answers

Answer:

yes

Explanation: took quiz

What is the molarity of a solution when 3.58 moles of NaCl are dissolved in 2.12 L of solution?

Answers

Answer:

  1.69 M

Explanation:

Molarity is the ratio of moles to liters:

  (3.58 moles)/(2.12 liters) = 1.6887 moles/liter ≈ 1.69 M

How does a mixture of benzoic acid and benzaldehyde can be isolated separately by extractions? ​

Answers

Answer:

Dissolve benxioc acid and benzaldehyde in organic solvent. The two compounds are not miscible.with water. Put the two in separating funnel. Then use aqueous sodium bicarbonate to extract. Benzioc acid will be in aqueous layer as benzioate ion. Benzaldehyde remain insoluble and can be isolated.

Explanation:

Extractions are techniques use to separate desired compounds when mixed together. The mixture is brought in contact with solvent in which the sites substance is soluble and other is insoluble. Extractions use imissicible stages to separate substance from another.

The original fluid mosaic model stated that membrane proteins move freely in the plane of the lipid bilayer via lateral diffusion "like protein icebergs in a sea of lipids." Since its initial description in 1927, the fluid mosaic model has been refined.
Complete the statements that describe some of the refinements of the fluid mosaic model as it relates to protein mobility.
Choose the answer that best completes each sentence:
Membrane (lipid) rafts, Vesicles, Cytoskeletal elements, Protein-protein interactions, Bilayer leaflets.
1) ______ may form a locally rigid, non-lipid matrix surrounded by the fluid lipid matrix.
2) ______, membrane domains rich in sphingolipids and cholesterol, are regions with reduced lipid and protein mobility.
3) ______ can be attached to proteins or can "fence in" proteins, reducing protein mobility.

Answers

Answer:

1. Protein-protein interactions

2. Lipid rafts

3. Cytoskeletal elements

Explanation:

The fluid mosaic model was proposed by the Singer and Nicolson in 1972 which stated that the membrane is a mosaic of the lipids, carbohydrates and the proteins.

The fluid mosaic model has been revised many times which are:

1. Protein-protein interactions: the proteins present in the lipid bilayer can easily float in the lipid layer, can be found integrated into the layer and exist on the outside of the layer. These proteins can form a bond with each other which are rigid and are non-lipid matrix.

2. Lipid rafts: the structure formed in the bilayer which is rich in cholesterol and the sphingolipids. These regions have a reduced amount of lipids and reduced protein mobility.

3. Cytoskeletal elements: are attached to the proteins and act as a fence in proteins which reduces the mobility of the proteins.

Convection refers to the movement of heat through a fluid, such as water. Which best describes one way that convection
influences the circulation of ocean water?
Cold water at the surface flows toward the poles and sinks as it cools.
Deep, warm water flows toward the equator and rises as it cools.
Warm water at the surface flows toward the poles and sinks as it cools.
Deep, cold water flows toward the equator and rises as it cools,

help me please

Answers

Answer:

the second answer where it says deep warm water flows, etc.

Explanation:

i hope that helps you

Answer:

C) Warm water at the surface flows toward the poles and sinks as it cools.

Explanation:

have a nice day.

A seed crystal of diameter D (mm) is placed in a solution of dissolved salt, and new crystals are observed to nucleate (form) at a constant rate r (crystals/min). Experiments with seed crystals of different sizes show that the rate of nucleation varies with the seed crystal diameter as r(crystals/min)=200D−10D2(D in mm)

a. What are the units of the constants 200 and 10? (Assume the given equation is valid and therefore dimensionally homogeneous.)
b. Calculate the crystal nucleation rate in crystals/s corresponding to a crystal diameter of 0.050 inch.
c. Derive a formula for r(crystals/s) in terms of D(inches). (See Example 2.6-1.) Check the formula using the result of Part b.

Answers

Answer:

Explanation:

a)   the units of the constants 200 and 10 are as follows:

unit of 200 = unit of r / unit of D

= crystals/min× mm

= crystals / (min×mm)

unit of 10 = unit of r / unit of D^2

= crystals/min × mm²

= crystals / (min×mm²)

b) The objective here is to determine the crystal nucleation rate in crystals/s corresponding to a crystal diameter of 0.050 inch; T o do that ; let's first convert the inch to  mm

We all know that

1 inch = 25.4 mm

0.050 inch = 0.050 ×25.4 mm

= 1.27 mm

nucleation rate = 200×D - 10×D²

= 200×1.27 - 10×(1.27)²

=237.9 Crystals/min

=237.9/60 crystals/sec

= 3.96 crystals/sec

c) Derive a formula for r(crystals/s) in terms of D(inches). (See Example 2.6-1.) Check the formula using the result of Part b.

r(crystals/sec)=A D−B D² (D in inch)

unit of 200= crystals / (min×mm)

unit of 10=crystals / (min×mm² )  

 

A = 200 crystals / (min×mm) × 1/60 min/sec ×25.4 mm/inch

= 84.7 crystals/(sec-inch)

B = 10 crystals / (min×mm² ) × 1/60 min/sec ×25.4 mm/inch×25.4 mm/inch

=107.5 crystals/(sec-inch)

Types of radioactive decay

Answers

Alpha decay
Beta negative decay
Gamma decay
Positron emission
Electron

For the equation 3Cu + 8HNO3 → 3Cu(NO3)2 + 2NO + 4H2O, how many units of NO3 are represented on the products side?
A 2
B 3
C 6
D 8

Answers

Answer:

C

Explanation:

Following are the calculation to units of [tex]\bold{NO_{3}}[/tex]:

Given equation:

[tex]\bold{3Cu + 8HNO_3 \longrightarrow 3Cu(NO_3)2 + 2NO + 4H_2O}[/tex]

To find:

units of [tex]\bold{NO_{3}}[/tex]=?

Solution:

[tex]\bold{3Cu + 8HNO_3 \longrightarrow 3Cu(NO_3)2 + 2NO + 4H_2O}[/tex]

The above-given equation when the 3 mol copper reacts with Nitric acid so, it will give 3 mol Cupric nitrate, 2 mol nitric oxide, and 4 mol of water.In the above-given equation[tex]\bold{3Cu(NO_3)_2= 3Cu +3(NO_3)_2 =3Cu +6(NO_3) }[/tex] there are 6 mols of[tex]\bold{NO_3}[/tex].

Therefore, the final answer is "Option C".

Learn more:

brainly.com/question/18492732

Can you please help me ?

Answers

Answer:

6.82 moles of Fe2O3

Explanation:

Step 1:

Determination of the number of mole of in 450g of CO2.

This is illustrated below:

Molar Mass of CO2 = 12 + (2x16) = 44g/mol

Mass of CO2 = 450g

Number of mole of CO2 =.?

Number of mole = Mass/Molar Mass

Number of mole of CO2 = 450/44 = 10.23 moles

Step 2:

Determination of the number of mole of Fe2O3 needed for the reaction. This is illustrated below:

2Fe2O3 + 3C—> 4Fe + 3CO2

From the balanced equation above,

2 moles of Fe2O3 reacted to produce 3 moles of CO2.

Therefore, Xmol of Fe2O3 will react to produce 10.23 moles of CO2 i.e

Xmol of Fe2O3 = (2x10.23)/3

Xmol of Fe2O3 = 6.82 moles

Therefore, 6.82 moles of Fe2O3 is required.

I need help solving this problem:

How many moles is 1.5x10^23 atoms of Carbon

Answers

To find out how many moles is 1.5x10^23 atoms of Carbon, we will use Avogadro's number, which is represented by 6.022x10^23 atoms or molecules per mol.

To convert from atoms to moles, divide the atoms by Avogadro's number.

So, now we can convert the numbers into proper form:

1.5x10^23 ---> 1.5E23

6.022x10^23 ---> 6.022E23

Then, we divide them.

1.5E23/6.022E23 = 0.24908

Round to nearest hundredth.

0.24908 --> 0.25

Therefore, there are 0.25 moles of carbon in 1.5E23 atoms of carbon.

3. A thin lead apron is used to protect patients from harmful X rays. If the sheet measures 75.0 cm by 55.0 cm by 0.10 cm, and the density of lead is 11.3 g/cm3, what is the mass of the apron in grams?

Answers

Answer:

4.67 kg

Explanation:

Given data

Dimensions of the lead sheet: 75.0 cm by 55.0 cm by 0.10 cmDensity of lead: 11.3 g/cm³

Step 1: Calculate the volume of the sheet

The volume of the sheet is equal to the product of its dimensions.

[tex]V = 75.0 cm \times 55.0 cm \times 0.10 cm = 413 cm^{3}[/tex]

Step 2: Calculate the mass of the sheet

The density (ρ) is equal to the mass divided by the volume.

[tex]\rho = \frac{m}{V} \\m = \rho \times V = \frac{11.3g}{cm^{3} } \times 413cm^{3} = 4.67 \times 10^{3} g = 4.67 kg[/tex]

Answers only please 100pts and brainliest. you will be reported for wrong answers.​

Answers

Answer:

1. 42.75 grams KOH

2. Add 150ml of water to the 250ml containing 9.8 grams 42.75 grams KOH

Explanation

1. moles KOH in 500ml in 1.5M solution = 0.500L x 1.5 mole/Liter = 0.75 mol KOH

grams KOH in 0.75 mole = 0.75 mole x 57 grams/mole = 42.75 grams KOH

2. formula weight H₃PO₄ = 98 grams/mole

9.8 grams H₃PO₄ in 250ml H₂O => 9.8g/98g·mole⁻¹/0.250Liters = 0.40M in H₃PO₄

Final volume of 0.25M H₃PO₄ solution = (0.40M)(250ml)/(0.25M) = 400ml

∴ Add 400ml - 250ml = 150ml of water to the 250ml of 0.40M H₃PO₄ solution => 400ml of 0.25M H₃PO₄ solution.

Answer:

1. 42.75 grams koh

2. add 150 ml of water to the 250 ml containing 9.8 grams 42.75 grams koh

Explanation:

A chemical engineer must calculate the maximum safe operating temperature of a high-pressure gas reaction vessel. The vessel is a stainless-steel cylinder that measures wide and high. The maximum safe pressure inside the vessel has been measured to be .
For a certain reaction the vessel may contain up to of carbon monoxide gas. Calculate the maximum safe operating temperature the engineer should recommend for this reaction. Write your answer in degrees Celsius. Be sure your answer has the correct number of significant digits.

Answers

Answer:

T = 643K = 643-273.15 = 369.85°C = 370°C = maximum safe operating temperature

Explanation:

The actual question has following data which the question given has missing

The vessel is a stainless-steel cylinder that measures wide 25.0 cm and 30.0 cm high.

The maximum safe pressure inside the vessel is 6.60 MPa.

The vessel may contain up to 0.800 kg of carbon monoxide gas.

Volume of cylinder = pi x r^2 x h  = 3.14 x (25/2)cm^2 x 30cm = 14725.78 cm^3 or 0.01472578 m^3

Now, using ideal gas law, PV = nRT

P = 6.60×10^6 Pa

V = 0.01472578 m^3

n= no. of moles = mas staken/ molar mass of CO2 = 800g/44g/mol = 18.18

moles

R =  8.314 J/mol.K

So, (6.60x10^6 ) x 0.01472578  = 18.18×8.314×T

T = 643 K = 643-273.15 = 369.85°C = 370°C = maximum safe operating temperature

Which step is this ?prophase I, Anaphase I, prophase II, Anaphase II

Answers

Answer:

Prophase 1

Explanation:

Answer:

The correct answer will be prophase I

Explanation:

During this stage, the genetic code is together and hasn't split yet therefore, the answer is prophase I hopefully this helps!

A Na2CO3 standard solution is prepared by transferring 2.4817 g of primary
standard-grade sodium carbonate (fw = 106 g/mol) to a 250-ml volumetric flask.
Dissolving the sample in - 100 mL distilled water and diluted to the mark. A 25.0
mL aliquot is taken and titrated with 42.65 mL of HCl, calculate the
concentration of the HCl solution?​

Answers

Answer:

0.1098 M

Explanation:

A chemistry graduate student is studying the rate of this reaction:
NH4OH(aq)→NH3(aq)+H2O(aq)
She fills a reaction vessel with and measures its concentration as the reaction
proceeds: time (seconds).
1. Write the rate law for this reaction.
2. Calculate the value of the rate constant.

Answers

Answer:

See explaination

Explanation:

Please kindly check attachment for the step by step solution of the given problem

A solution is prepared by dissolving 0.26 mol of hydrazoic acid and 0.26 mol of sodium azide in water sufficient to yield 1.00 L of solution. The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly. The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution. The Ka of hydrazoic acid is 2.5 x 10^-5.

Answers

Answer:

The pH does not decrease drastically because the HCl reacts with the sodium azide (NaN₃) present in the buffer solution.

Explanation:

The buffer solution is formed by 0.26 moles of the weak acid, hydrazoic acid (HN₃), and by 0.26 moles of sodium azide (NaN₃). The equilibrium reaction of this buffer solution is the following:

HN₃(aq) + H₂O(l)  ⇄ N₃⁻(aq) + H₃O⁺(aq)          

The pH of this solution is:

[tex] pH = pka + log(\frac{[N_{3}^{-}]}{[HN_{3}]}) = -log(2.5 \cdot 10^{-5}) + log(\frac{0.26 mol/1 L}{0.26 mol/1 L}) = 4.60 [/tex]

When 0.05 moles of HCl is added to the buffer solution, the following reaction takes place:

H₃O⁺(aq) + N₃⁻(aq)  ⇄  HN₃(aq) + H₂O(l)

The number of moles of NaN₃ after the reaction with HCl is:

[tex] \eta_{NaN_{3}} = \eta_{i} - \eta_{HCl} = 0.26 moles - 0.05 moles = 0.21 moles [/tex]

Now, the number of moles of HN₃ is:

[tex] \eta_{HN_{3}} = \eta_{i} + \eta_{HCl} = 0.26 moles + 0.05 moles = 0.31 moles [/tex]

Then, the pH of the buffer solution after the addition of HCl is:

[tex] pH = pka + log(\frac{[N_{3}^{-}]}{[HN_{3}]}) = -log(2.5 \cdot 10^{-5}) + log(\frac{0.21 mol/V_{T}}{0.31 mol/V_{T}}) = 4.43 [/tex]

The pH of the buffer solution does not decrease drastically, it is 4.60 before the addition of HCl and 4.43 after the addition of HCl.    

Therefore, the pH does not decrease drastically because the HCl reacts with the sodium azide (NaN₃) present in the buffer solution.

I hope it helps you!

When wave-particle duality was applied to the electron, it explained why the energy of the electron is quantized because:

a. The electron is a standing wave that can only have an integer number of wavelengths
b. An electron can only exhibit specific velocities
c. The electron must have a specific mass
d. An electron will emit and absorb light quanta

Answers

Answer:

a. The electron is a standing wave that can only have an integer number of wavelengths.

Explanation:

As per quantum physics, the theory of wave-particle duality refers to the notion that matter and light show the characteristics of both waves and particles, based on the case of the experiment. Much like light, the matter appeared to possess both wave and particle properties.  Large objects display very low wavelengths, but for small particles, the wavelength may be detected and important, as shown by a double-slit experiment with electrons.

There are certain trends with which you should become very familar (recognizing these trends will save you time!) This part of the question is dedicated to that task.

a) Whenever you see 9 or a multiple of 9 in the integration ratio, which group should you first consider for being responsible for that signal.
b) Whenever you see a quartet and triplet on a spectrum, which group should you first consider for being responsible for those signals?
c) Whenever you see septet and a doublet on a spectrum, which group should you first consider for being responsible for those signals?
d) Whenever you see 6 or a multiple of 6 in the integration ratio, which group should you first consider for being responsible for that signal
e) Whenever you see 3 as the actual number of protons for a given signal, which group should you first consider for being responsible for that signal

Answers

Answer:

Explanation:

The objective of this  question is all about identifying the phenomena that holds true for the statement being said in each instance. Let; walk through them.

a) Whenever you see 9 or a multiple of 9 in the integration ratio, which group should you first consider for being responsible for that signal.

( C₄H₉ )Tert. Butyl group

b) Whenever you see a quartet and triplet on a spectrum, which group should you first consider for being responsible for those signals?

(CH₃CH₂)  ethyl group

c) Whenever you see septet and a doublet on a spectrum, which group should you first consider for being responsible for those signals?

(CH(CH₃)₂)  isoproply group

d) Whenever you see 6 or a multiple of 6 in the integration ratio, which group should you first consider for being responsible for that signal

(CH(CH₃)₂)  isoproply group

e)  Whenever you see 3 as the actual number of protons for a given signal, which group should you first consider for being responsible for that signal.

CH₃- methyl group

A perfect description showing  the explanation of each answers chosen is explained with an aid of diagram below.

Which of the following acts as a bronsted Lowry acid, but not as a bronsted Lowry base

Answers

Answer:

D. (HCIO4(AQ)

Explanation:

Each iron atom has a mass of about 9 x 1023 grams. Even a small grain of iron has an incredible number of atoms in. it--about 1 x 1018 atoms in one grain. Which of these is most similar to the number of atoms in a grain of iron?

Answers

Answer:

A) The number of atoms in a grain of iron is most similar to the number of meters between Earth and Vega.

The options attached to the question are missing, but out of the numbers presented in the options, 10¹⁷ is closest to 10¹⁸.

B) The mass of a grain of iron is approximately (9 × 10⁻⁵) g

Explanation:

The options attached to the question are missing, after searching online, the image of the question was obtained, but it won't be attached to this solution in order not to violate the community guidelines and lead to deletion of answer.

But, out of the numbers presented in the options, 10¹⁷ is closest to 10¹⁸, hence, the number of atoms in a grain of iron is most similar to the number of meters between Earth and Vega.

The second part of the question asks for the approximate mass of a grain of iron.

1 atom of iron has a mass of (9 × 10⁻²³) g

1 grain of iron has about (1 × 10¹⁸) atoms of iron.

So, the mass of a grain of iron = (9 × 10⁻²³) × (1 × 10¹⁸) = (9 × 10⁻⁵) g

Hope this Helps!!!

Which is not a physical property?
A) Hardness
B) Boiling point
C)ability to conduct electricity
D) ability to combine with hydrogen​

Answers

Answer:

D

Explanation:

Combing with hydrogen is a chemical property.

Answer:

D. ability to combine with hydrogen

explanation: It is a chemical property.

An empty container weighs 80.21 g. it is filled with 20.14 mL of an unknown liquid, and the total weight of the container and liquid is 105.22 g. What is the density of the liquid?

Answers

Answer:

1.242 g/mL

Explanation:

Step 1: Given data

Mass of the empty container (m₁): 80.21 g

Mass of the filled container (m₂): 105.22 g

Volume of the unknown liquid (V): 20.14 mL

Step 2: Calculate the mass of the liquid

The mass of the liquid is equal to the difference between the mass of the filled container and the mass of the empty container.

[tex]m = m_2 - m_1 = 105.22g - 80.21 g = 25.01 g[/tex]

Step 3: Calculate the density of the unknown liquid

The density of the liquid is equal to its mass divided by its volume.

[tex]\rho = \frac{m}{V} = \frac{25.01g}{20.14mL} = 1.242 g/mL[/tex]

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