A solution is prepared by dissolving 0.26 mol of hydrazoic acid and 0.26 mol of sodium azide in water sufficient to yield 1.00 L of solution. The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly. The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution. The Ka of hydrazoic acid is 2.5 x 10^-5.

Answers

Answer 1

Answer:

The pH does not decrease drastically because the HCl reacts with the sodium azide (NaN₃) present in the buffer solution.

Explanation:

The buffer solution is formed by 0.26 moles of the weak acid, hydrazoic acid (HN₃), and by 0.26 moles of sodium azide (NaN₃). The equilibrium reaction of this buffer solution is the following:

HN₃(aq) + H₂O(l)  ⇄ N₃⁻(aq) + H₃O⁺(aq)          

The pH of this solution is:

[tex] pH = pka + log(\frac{[N_{3}^{-}]}{[HN_{3}]}) = -log(2.5 \cdot 10^{-5}) + log(\frac{0.26 mol/1 L}{0.26 mol/1 L}) = 4.60 [/tex]

When 0.05 moles of HCl is added to the buffer solution, the following reaction takes place:

H₃O⁺(aq) + N₃⁻(aq)  ⇄  HN₃(aq) + H₂O(l)

The number of moles of NaN₃ after the reaction with HCl is:

[tex] \eta_{NaN_{3}} = \eta_{i} - \eta_{HCl} = 0.26 moles - 0.05 moles = 0.21 moles [/tex]

Now, the number of moles of HN₃ is:

[tex] \eta_{HN_{3}} = \eta_{i} + \eta_{HCl} = 0.26 moles + 0.05 moles = 0.31 moles [/tex]

Then, the pH of the buffer solution after the addition of HCl is:

[tex] pH = pka + log(\frac{[N_{3}^{-}]}{[HN_{3}]}) = -log(2.5 \cdot 10^{-5}) + log(\frac{0.21 mol/V_{T}}{0.31 mol/V_{T}}) = 4.43 [/tex]

The pH of the buffer solution does not decrease drastically, it is 4.60 before the addition of HCl and 4.43 after the addition of HCl.    

Therefore, the pH does not decrease drastically because the HCl reacts with the sodium azide (NaN₃) present in the buffer solution.

I hope it helps you!


Related Questions

how does an organic pH indicator works. (illustrate using chemical equations and
mathematical expressions

Answers

Answer:

A pH indicator is a halochromic chemical compound added in small amounts to a solution so the pH (acidity or basicity) of the solution can be determined visually. Hence, a pH indicator is a chemical detector for hydronium ions (H3O+) or hydrogen ions (H+) in the Arrhenius model.A pH of 7 indicates a neutral solution like water. A pH less than 7 indicates an acidic solution and a pH greater than 7 indicates a basic solution. Ultimately, the pH value indicates how much H+ has dissociated from molecules within a solution. The lower the pH value, the higher concentration of H+ ions in the solution and the stronger the acid. Likewise, the higher the pH value, the lower the concentration of H+ ions in the solution and the weaker the acid.

Explanation:

state the purpose of respiration.​

Answers

To provide for the exchange of oxygen and carbon dioxide between the atmosphere and the blood

Answer:

The purpose of respiration is to supply the body with oxygen and eliminate carbon dioxide. Oxygen is essential for cellular respiration as cells cannot exist in the absence of it. The human lungs are the organs responsible for respiration.

Explanation:

Respiration refers to a person’s breathing and the movement of air into and out of the lungs. The respiratory system provides oxygen to body tissues for cellular respiration, removes the waste product carbon dioxide, and helps maintain acid–base balance. Inspiration is the process that causes air to enter the lungs, and expiration is the process that causes air to leave the lungs . A respiratory cycle (or one breath while you are measuring respiratory rate) is one sequence of inspiration and expiration.

Nitric acid can be formed in two steps from the atmospheric gases nitrogen and oxygen, plus hydrogen prepared by reforming natural gas. In the first step, nitrogen and hydrogen react to form ammonia:

N2 (g)+ 3H2(g) → 2NH3(g)

In the second step, ammonia and oxygen react to form nitric acid and water:

NH3(g)+ 2O2(g) → HNO3(g) + H2O(g)

Calculate the net change in enthalpy for the formation of one mole of nitric acid from nitrogen, hydrogen and oxygen from these reactions. Round your answer to the nearest .

Answers

Answer:

-376 kJ.

Explanation:

A proton is a hydrogen atom without its electron?
True
False

Answers

True, electrons are on their own.

Why are white Americans less affected by toxic waste and air pollution than people of color?

A.They tend to live in urban centers .

B. They tend to vote in smaller numbers compared to other groups.

C. They tend to have more of a say in where uncontrolled toxic waste sites are located.

D. All of the above are true.

Answers

Answer:

D. All the above

Explanation:

WHite people are "previlged"

The chart below describes the molecular motion in solids, liquids, gases, and plasma.
Solids Liquids Gases Plasma
slower than liquids, slower than solids but faster than solids faster than solids,
gases, and plasma faster than gases and but slower than liquids and gases
plasma plasma
The information in the chart about molecular motion is incorrect for:______
1. solids
2. liquids
3. gases
4. plasma

Answers

Answer:

Liquids

Note: the attachment below shows the properly arranged chart

Explanation:

The order of molecular motion of matter from fastest to slowest is;

Plasma>Gases>Liquids>Solids

Liquids move faster than solids not slower.

Answer:

liguids

Explanation:

A substance is followed by the symbol (1) in a chemical equation. What does the symbol represent?

Answers

Answer:

The symbol (l) stands for liquid phase.

Explanation:

If 100 ml of a 0.75 m hno3 is required to exactly neutralize 50 ml of naoh what is the concentration of the base?

Answers

Answer:

1.5M

Explanation:

M1V1=M2V2

(0.75M)(100ml)=(M2)(50 ml)

M2= 1.5 M

*Text me at 561-400-5105 for private tutoring if interested: I can do homework, labs, and other assignments :)

The decomposition of nitrogen dioxide is described by the following chemical equation:
2NO_2 (g) --------> 2NO (g) + O_2 (g)
Suppose a two-step mechanism is proposed for this reaction, beginning with this elementary reaction:
NO_2 (g) --------> NO_(g) + O_(g)
Suppose also that the second step of the mechanism should be bimolecular.
a) Suggest a reasonable second step. That is, write the balanced chemical equation of a bimolecular elementary reaction that would complete the proposed mechanism.

Answers

Answer:

The balanced chemical equation will be "[tex]NO_{2}+O\rightarrow NO+O_{2}[/tex]".

Explanation:

The given equation is:

[tex]2NO_{2}\rightarrow 2NO+O_{2}[/tex]

Step 1:

[tex]2NO_{2}\rightarrow NO+O[/tex]...(equation 1)

Step 2:

[tex]NO_{2}+O\rightarrow NO+O_{2}[/tex]...(equation 2)

On adding "equation 1" and "equation 2", we get

⇒  [tex]NO_{2}+NO_{2}+O\rightarrow NO+O+NO+O_{2}[/tex]

⇒  [tex]2NO_{2}\rightarrow 2NO+O_{2}[/tex]

The second step:

⇒  [tex]NO_{2}+O\rightarrow NO+O_{2}[/tex]

What do you need in order to do a stoichiometric calculation? (Choose
multiple)
Balanced Chemical Equation
Molar masses of compounds involved
The type of reaction taking place
Oxidation Numbers

Answers

I think it is Molar masses of compounds involved or Oxidation numbers, but you can choose one of them. Or you can think about the question carefully.

Imagine designing an experiment in which the presence of a gas is determined by simply listening to the gas with your ear. The human ear can detect pressures as low as 2 x 10^-5 N*m^-2. Assuming that the eardrum has an area of roughly 1 mm^2, what is the minimum collisional rate that can be detected by ear? Assume that the gas of interest is N2 at 298 K.

Answers

Answer:

Explanation:

Pressure = Force/Area

so,

Force =Pressure x Area

Force =(2x 10⁻⁵ )N/M² x (1 x (10⁻³)² M²

Force = 2 x 10⁻¹¹N

as we know,

Force= mass x acceleration ( F=m.a)

a = F/m

a =(2 x 10⁻¹¹N)/28

g since 1 N=1.kg.m.s⁻²

a=(2 x 10-11kg.m.s⁻² )/(28 x 10⁻³kg)  

a = 5.6 x 10-7 m.s⁻²

thus minimum collision rate that can be detected is 5.6 x 10-7 m.s⁻²

What is the amount of energy needed to heat 2.3 g of aluminum from 6.2oC to 46.9oC in Joules?

Answers

Answer:

Heat required = 84.25 Joule

Explanation:

Heat required = mass × specific heat capacity × temperature change

Specific heat capacity of aluminium = 0.90 J/g/K

Heat required = 2.3 × 0.9 × (46.9 -6.2)

= 84.25 Joules

what is the sex-ratio in rajasthan according to 2011 census?​

Answers

Answer:

Sex ratio of India according 2011 census is 940 females per 1000 males. Sex ratio of Rajasthan is 928 which means there are 928 female present per 1000 males

Explanation:

pls check my answer brain list

Use one of your experimentally determined values of k, the activation energy you determined, and the Arrhenius equation to calculate the value of the rate constant at 25 °C. Alternatively, you can simply extrapolate the straight-line plot of ln(k) vs. 1/T in your notebook to 1/298, read off the value of ln(k), and determine the value of k. Please put your answer in scientific notation. slope=-12070, Ea=100kJ/mol, k= 0.000717 (45 °C), 0.00284 (55 °C), 0.00492 (65 °C), 0.0165 (75 °C), 0.0396 (85 °C).

Answers

Answer:

Explanation:

Use one of your experimentally determined values of k, the activation energy you determined, and the Arrhenius equation to calculate the value of the rate constant at 25 °C. Alternatively, you can simply extrapolate the straight line plot of ln(k) vs. 1/T in your notebook to 1/298 , read off the value of ln(k), and determine the value of k. Please put your answer in scientific notation. slope=-12070, Ea=100kJ/mol, k= 0.000717(45C), 0.00284(55C), 0.00492(65C), 0.0165(75C), 0.0396(85C)

Explanation;

According to Arrhenius equation:

i.e. ln(k2/k1) = -Ea/R (1/T2 - 1/T1)

Where, k1 = 0.000717, T1 = 45 oC = (45+273) K = 318 K

T2 = 25 oC = (25 + 273) K = 298 K

i.e. ln(k2/0.000717) = -12070 (1/298 - 1/318)

i.e. ln(k2/0.000717) = -2.54738

i.e. k2/0.000717 = [tex]e^{-2.54738}[/tex]

= 0.078286

Therefore, the required constant (k2) = 0.078286 * 0.000717 = [tex]5.61*10^-^5[/tex]

the _ is responsible for absorbing the most uv radiation

Answers

Hey
Here’s your answer:-

The Stratosphere is responsible for absorbing the most uv radiation.

a chemical reaction can be represented by ​

Answers

Answer:

A chemical reaction is a rearrangement of atoms which turn one or more compounds into new compounds. Equations and models may describe all of the chemical reactions. ... If atoms detach from each other and recombine into various types of atoms, we conclude that there has been a chemical reaction.

Answer:

equations and models.

Explanation:

All chemical reactions can be represented by equations and models.

If it's a summer day and you want to take a picnic are you concerned with weather
or climate? Why?

Answers

Answer:

Not really, the chances you will get hurt are insignificant

Explanation:

If you want to produce 11 moles of NH3, how much H2 do you need?

Answers

Answer:

33 g of H2

Explanation:

N2 + 3 H2 -> 2 NH3

3 mol H2 -> 2 mol NH3

             x -> 11 mol NH3

x= (11 mol NH3 * 3 mol H2)/ 2 mol NH3

x= 16.5 mol H2

1 mol H2    -> 2 g

16.5 mol H2 ->x

x= (16.5 mol H2 * 2 g)/ 1 mol H2

x= 33 g

Three examples of chemical reactions ????? PLEASE HELP

Answers

Answer:

Photosynthesis, Respiration, Combustion, Anaerobic Respiration

Explanation:

Im not 100% sure if this is what you are looking for but it should be correct. Hope this helps! :)

Ultraviolet photoelectron spectroscopy (UPS) is an important analytical tool used to characterize the composition of materials in academic, industrial and national laboratories. The technique relies on the photoelectric effect where-in electrons are emitted from a material when it absorbs ultraviolet photons. Make a plot of the kinetic energy of the photo-emitted electrons versus the frequency of the incident light as the frequency is varied across the transition where photon energy exceeds the ionization energy (IE) of a material being examined by UPS. Label you axes.

Answers

Answer:

The equation for the Kinetic Energy, [tex]KE_e[/tex], of the photo-emitted electrons is given as follows;

[tex]KE_e = h\cdot f- BE[/tex]

Please find attached the required plot of the kinetic energy versus the frequency

Explanation:

The equation for the Kinetic Energy, [tex]KE_e[/tex], of the photo-emitted electrons is given as follows;

[tex]KE_e = h\cdot f- BE[/tex]

Where:

h = Planck's constant = 6.63×10⁻³⁴ J·s

f = Frequency

BE = Binding Energy = 2.71 eV  for Calcium metal

f₀ = Threshold frequency for the material

The ionization energy is the energy required to free an electron from an isolated atom

Which of the following is an example of acceleration? 88m/s, 15km/hr,14m/s East, 9.8 m/s^2 south

Answers

Answer: The answer is 9.8 m/s^2 south

Explanation:

Predict the products of the following reactions (assume complete reaction). In your submission include the overall balanced equation, and balanced net ionic equation if applicable:
a. Adding zinc metal to a solution of copper(II) sulfate
b. Dripping silver perchlorate into a solution of sodium carbonate
c. A lump of aluminum metal is dropped into concentrated hydroiodic acid
d. Sucrose is fermented in water by yeast to make ethanol and carbon dioxide (note: water is a reactant)
e. Solid calcium oxide is added to water (careful)
f. A lump of potassium metal is dropped into water (careful)

Answers

Answer:

Zn(s) + CuSO4(aq) -----> ZnSO4(aq) + Cu(s)

Na2CO3 (aq)+ 2AgClO4(aq) → 2NaClO4(aq) + Ag2CO3(s)

2Al(s) + 6HI(aq) ------> 2AlI3(aq) + 3H2(g)

C12H22O11(s)+H2O(l)→4C2H5OH(aq)+4CO2(g)

2K(s) + 2H2O(l) ------->2KOH(aq) + H2(g)

Explanation:

In the first reaction, zinc displaces copper from an aqueous copper II salt since zinc is higher than copper in the electrochemical series.

Reaction two leads to the precipitation of silver carbonate. Remember that carbonates are mostly insoluble in water.

Acids are known to displace hydrogen gas from dilute acids. Hence in the third reaction, aluminum displaced hydrogen from aqueous hydroiodic acid.

In the fourth reaction, the action of yeast leads to the fermentation of sucrose yielding ethanol and carbon dioxide in the process.

Metals are known to form aqueous alkaline solutions liberating hydrogen gas when they react with water. Hence potassium metal reacts with water to liberate hydrogen gas and form alkaline potassium hydroxide.

1. What is the answer to the following expression in the correct number of significant figures?
(0.1245) x (0.00003) x (298,000)/(2.0 - 1.5)

Answers

Answer:

2 with 1 SF

Explanation:

Which multimedia does this ad from the Centers for Disease Control’s advertising campaign for the flu vaccine include? (more than one)


A.) animation

B.) image

C.) text

D.) graph

E.) chart

Answers

Is imagine and text I just answer this question hope this helps and if you get it right can you put it as brainless answer

Answer:

Image and text

Explanation:

on edge

which of the following is larger then the atomic radius of phosphorus
Options
a: the ionic radius of phosphorus
b: the atomic radius of argon
c: the atomic radius of nitrogen
d: the ionic radius of chlorine

Answers

Answer:

a)the ionic radius of phosphorus

Explanation:

phosphorus=2.8.6

for phosphorus to become stable(2.8.8) it gains two electrons thus the ionic radious increases bcz of the gained electrons

which of the following can cause acid precipitation
the use of solar panels
the use of hydroelectricity
the use of coal
all of the above

Answers

Answer:

C. The use of coal

Explanation:

Answer:

C. The use of coal

Explanation:

Edge 2021

Plants need sunlight, water, and minerals from the soil in order to grow and thrive. These factors
A.
are always abundant, allowing unlimited growth.
B.
limit the number of plant populations that can grow in an ecosystem.
C.
require human intervention to be replenished.
D.
prevent new plant populations from entering the ecosystem.

Answers

Answer:

B. limit the number of plant populations that can grow an ecosystem

Answer:

B. limit the number of plant populations that can grow in an ecosystem.

Explanation:

what is 2H2O state of matter

Answers

Answer:

2 MOLECULES OF WATER

Explanation:

SO, LIQUID

I really need to pass chem, someone please help me! <3

Answers

1. Is that you need to pay more attention in class

5. Which of the following is NOT a physical change?
nailing together boards of wood
breaking an egg
dying your hair
adding food coloring to water​

Answers

adding food coloring to water it’s a chemical change
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