The chemical symbol of the noble gas is (S), and its formula is S²-.
The monatomic ion with a charge of -2 has gained 2 electrons, making the electronic configuration isoelectronic with that of a noble gas.
To determine which noble gas it is isoelectronic with, we count backwards from the last orbital filled. The last orbital filled is the 5p orbital, which contains 6 electrons. The noble gas with an electronic configuration that ends in 5p6 is Xenon (Xe).
The formula of the ion can be determined by removing the 2 valence electrons from the original configuration. This gives us
1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶, which is the electronic configuration of the ion. The ion is a negative anion, so it is likely to be a non-metal.
Looking at the electron configuration, we see that it has a completely filled 4s and 3d orbitals, as well as a completely filled 4p orbital.
This suggests that the ion is a member of the oxygen group (group 16) on the periodic table. The ion with this electron configuration is Sulfur (S), and its formula is S²-
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If a substance’s size, shape, or form changes then a _____ has occurred.
Answer:
If you're asking about what type of change then it would be a Physical change.
A physical change is defined as changes affecting the form of a chemical substance, but not its chemical composition.
How can a medical examiner tell the difference between a death by suffocation and a death by carbon monoxide poisoning
A medical examiner can differentiate between death by suffocation and death by carbon monoxide poisoning by conducting an autopsy and examining the body, as well as investigating the circumstances surrounding the death.
Autopsy: During an autopsy, the medical examiner will examine the body for physical signs of suffocation, such as bruises, petechiae (small red or purple spots on the skin caused by bleeding), or damage to the throat, lungs, and airways.
In cases of carbon monoxide poisoning, the medical examiner may look for signs such as cherry-red skin, mucous membranes, and organs, which can indicate high levels of carbon monoxide in the bloodstream.
Toxicology: The medical examiner may also conduct toxicology tests to detect the presence of carbon monoxide in the blood. High levels of carbon monoxide can indicate carbon monoxide poisoning.
Circumstances of death: The medical examiner will also investigate the circumstances surrounding the death, such as whether the victim was found in an enclosed space or near a source of carbon monoxide, such as a car or generator. In cases of suffocation, the circumstances may suggest that the victim was intentionally or accidentally smothered or strangled.
In summary, a combination of physical examination, toxicology tests, and investigation of the circumstances surrounding the death can help a medical examiner differentiate between death by suffocation and death by carbon monoxide poisoning.
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A certain protein was found to contain 0.560% zinc by mass. Determine the minimum molecular mass of the protein.
The minimum molecular mass of the protein is: 17857.14 g/mol
To determine the minimum molecular mass of the protein, we need to use the mass percent composition of zinc to calculate the mass of zinc in one mole of the protein.
Let's assume that we have 100 grams of the protein. Then, the mass of zinc in 100 g of the protein would be:
0.560 g Zn per 100 g protein
To convert this to moles of Zn per mole of protein, we need to divide by the molar mass of Zn:
0.560 g Zn / 65.38 g/mol Zn = 0.00856 mol Zn
Since the protein contains 0.560% zinc by mass, the mass of one mole of the protein must be:
100 g protein / 0.560 g Zn per 100 g protein = 17857.14 g protein per mole of Zn
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"strongbox = a small lockable box, typically made of metal, in which valuables may be kept." This is an example of what word formation process? Group of answer choices alternation suppletion compounding conversion clipping blending
The example "strongbox = a small lockable box, typically made of metal, in which valuables may be kept" is an example of compounding.
Compounding is a word formation process in which two or more words are combined to create a new word that has a meaning that is different from the meanings of the individual words. In this case, "strong" and "box" are combined to create a new word, "strongbox," which refers to a specific type of lockable container for valuables.
The word "strongbox" is an example of compounding, which is a word formation process that involves combining two or more separate words to create a new word. In this case, the two separate words are "strong" and "box." Compounding is a common process in English and can result in new words that have a specific meaning or usage.
What is compounding?
Compounding is a word formation process in which two or more separate words are combined to create a new word that typically has a specific meaning or usage.
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chlorine dioxide is used as a disinfectant in municipal water-treatment plants. It decomposes in a first-order reaction with a rate constant of 0.0714 s^-1 If the initial concentration were 0.12M what wold the concentation be after 14.0s has elapsed
The first-order rate law equation for the decomposition of chlorine dioxide is given as:
ln([ClO2]t/[ClO2]0) = -kt
where [ClO2]t is the concentration of chlorine dioxide at time t, [ClO2]0 is the initial concentration, k is the rate constant, and t is the elapsed time.
Rearranging this equation, we get:
[ClO2]t = [ClO2]0 x e^(-kt)
Substituting the given values, we get:
[ClO2]t = ₍0.12 M₎ x e^(-0.0714 s^-1 x 14.0 s) = 0.064 M
Therefore, the concentration of chlorine dioxide after 14.0 seconds would be 0.064 M.
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a solution is made containing 4.6 g of sodium chloride per 250 g of water what is the percent by mass
The percent by mass of the solution containing 4.6 g of sodium chloride per 250 g of water is 1.81%. This means that 1.81% of the total mass of the solution is made up of sodium chloride.
To calculate the percent by mass of a solution containing 4.6 g of sodium chloride per 250 g of water, we need to divide the mass of the solute (sodium chloride) by the mass of the solution and multiply by 100%. Mathematically, this can be expressed as:
Percent by mass = (mass of solute / mass of solution) x 100%
The mass of the solution is the sum of the mass of the solute (4.6 g) and the mass of the solvent (water, 250 g), which is:
Mass of solution = Mass of solute + Mass of solvent
Mass of solution = 4.6 g + 250 g
Mass of solution = 254.6 g
Substituting the values, we get:
Percent by mass = (4.6 g / 254.6 g) x 100%
Percent by mass = 1.81%
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what is the ph of a 0.300 m solution of aniline (c₆h₅nh₂, kb = 4.3 × 10⁻¹⁰)?
The pH of a 0.300 M solution of aniline is 9.39.
The pH of a 0.300 M solution of aniline can be calculated using the relationship between the dissociation constant (Kb) and the ionization constant (Ka) of the acid-conjugate base pair. Since aniline is a weak base, it will react with water to produce the anilinium ion ([tex]C_6H_5NH_3^+[/tex]) and hydroxide ion (OH-).
The Kb value for aniline can be used to calculate the Ka value, which is [tex]1.9 * 10^{-5}[/tex]. From this, the pKa can be calculated as 4.72. Using the equation pH = pKa + log([A-]/[HA]), where [A-] is the concentration of the conjugate base ([tex]C_6H_5NH_2^-[/tex]) and [HA] is the concentration of the acid ([tex]C_6H_5NH_3^+[/tex]), the pH of the solution can be calculated to be approximately 9.39.
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Calculate the pH for each of the cases in the titration of 35.0 mL of 0.180 M KOH(aq) with 0.180 M HI(aq). Note: Enter your answers with two decimal places.
The pH at the equivalence point is 7.00, before the equivalence point is 0.74 (basic), and after the equivalence point is 0.74 (acidic).
In this titration, we have a strong base (KOH) reacting with a strong acid (HI). At the equivalence point, all the KOH will have reacted with HI to form KI and H₂O. We can use the stoichiometry of this reaction to calculate the number of moles of HI needed to reach the equivalence point.
First, we need to determine the volume of HI needed to reach the equivalence point. Since we have 35.0 mL of 0.180 M KOH, we can use the equation M1V1 = M2V2 to find the number of moles of KOH present:
0.180 M x 0.0350 L = 0.00630 mol KOH
Since the reaction between KOH and HI is 1:1, we need 0.00630 moles of HI to reach the equivalence point. Using the same equation, we can find the volume of HI needed:
0.180 M x V(HI) = 0.00630 mol HI
V(HI) = 0.0350 L
At the equivalence point, the solution will contain only KI and water. The pH of this solution will be neutral, or 7.00.
Before the equivalence point, the KOH is in excess and the solution is basic. We can use the equation for the reaction of KOH and water to calculate the concentration of hydroxide ions:
KOH(aq) + H₂O(l) → K⁺(aq) + OH⁻(aq)
The initial concentration of KOH is 0.180 M, so the concentration of OH⁻ will also be 0.180 M. Using the equation for the ion product constant of water, we can calculate the pH:
pH = -log[OH⁻] = -log(0.180) = 0.74
After the equivalence point, the HI is in excess and the solution is acidic. We can use the equation for the reaction of HI and water to calculate the concentration of hydronium ions:
HI(aq) + H₂O(l) → H₃O⁺(aq) + I⁻(aq)
The initial concentration of HI is 0.180 M, so the concentration of H₃O⁺ will also be 0.180 M. Using the equation for pH, we can calculate the pH:
pH = -log[H₃O⁺] = -log(0.180) = 0.74
Therefore, the pH at the equivalence point is 7.00, before the equivalence point is 0.74 (basic), and after the equivalence point is 0.74 (acidic).
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What mass of platinum could be plated on a electrode from the electrolysis of Pt(NO3)2 solution with a current of o.500 A for 55.0 s
0.111 g of platinum could be plated on the electrode under the given conditions. when electrolysis of Pt(NO3)2 solution with a current of o.500 A for 55.0 s.
To calculate the mass of platinum plated on the electrode, we will use the following terms: current (I), time (t), molar mass of platinum (M_Pt), Faraday's constant (F), and the stoichiometry of the reaction (n).
In this case, we have:
I = 0.500 A
t = 55.0 s
M_Pt = 195.08 g/mol (platinum)
F = 96485 C/mol (Faraday's constant)
n = 2 (from Pt(NO3)2, where 2 moles of electrons are required to reduce 1 mole of Pt)
First, find the total charge (Q) passed through the solution:
Q = I × t = 0.500 A × 55.0 s = 27.5 C
Now, use Faraday's law to find the moles of platinum plated:
Moles of Pt = (Q × n) / F = (27.5 C × 2) / 96485 C/mol = 0.000569 mol
Finally, find the mass of platinum plated:
Mass of Pt = Moles of Pt × M_Pt = 0.000569 mol × 195.08 g/mol = 0.111 g
Therefore, 0.111 g of platinum could be plated on the electrode under the given conditions.
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water with an alkalinity of 2.00 10-3 mol/l has a ph of 7.65. calculate [co2], [hco3-], [co32-], [h3o ] and [oh-].
The concentrations of CO2, HCO3-, CO32-, H3O+, and OH- in the water are:
[CO2] = 4.37 × 10^(-12) mol/L
[HCO3-] = 1.00 × 10^(-3) mol/L
[CO32-] = 2.39 × 10^(-6) mol/L
[H3O+] = 1.96 × 10^(-8) mol/L
[OH-] = 2.24 × 10^(-7) mol/L
To solve this problem, we need to use the equations that describe the equilibria between CO2, HCO3-, CO32-, H3O+, and OH- in water. These equilibria are:
CO2 + H2O ⇌ HCO3- + H3O+
HCO3- ⇌ CO32- + H3O+
H2O ⇌ H+ + OH-
We also need to use the definition of alkalinity, which is the ability of water to neutralize acids. Alkalinity is equal to the concentration of HCO3- + 2 × CO32- in the water.
We can start by using the pH to find the concentration of H3O+ and OH-:
pH + pOH = 14
pOH = 14 - pH = 14 - 7.65 = 6.35
[H3O+] = 10^(-pH) = 10^(-7.65) = 1.96 × 10^(-8) mol/L
[OH-] = 10^(-pOH) = 10^(-6.35) = 2.24 × 10^(-7) mol/L
Next, we can use the definition of alkalinity and the concentrations of HCO3- and CO32- to find the concentration of each species:
Alkalinity = [HCO3-] + 2 × [CO32-] = 2.00 × 10^(-3) mol/L
[HCO3-] + [CO32-] = Alkalinity / 2 = 1.00 × 10^(-3) mol/L
We can use the equilibrium constant expression for the first equilibrium to find the concentration of CO2:
K1 = [HCO3-][H3O+] / [CO2] = 4.45 × 10^(-7) (at 25°C)
[CO2] = [HCO3-][H3O+] / K1 = (1.00 × 10^(-3) mol/L)(1.96 × 10^(-8) mol/L) / 4.45 × 10^(-7) = 4.37 × 10^(-12) mol/L
We can use the equilibrium constant expression for the second equilibrium to find the concentration of CO32-:
K2 = [CO32-][H3O+] / [HCO3-] = 4.69 × 10^(-11) (at 25°C)
[CO32-] = K2[HCO3-] / [H3O+] = (4.69 × 10^(-11))(1.00 × 10^(-3) mol/L) / (1.96 × 10^(-8) mol/L) = 2.39 × 10^(-6) mol/L
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A solution contains equal moles of liquid components X and Z. The vapor pressure of pure X is 140 mm Hg, and that of pure Z is 190 mm Hg. The experimentally measured vapor pressure of the solution is 170 mm Hg. What are the relative strengths of the particle interactions in this solution
The relative strengths of the particle interactions in this solution are weaker than those in the pure components.
The relative strengths of particle interactions in a solution can be determined by comparing the observed vapor pressure of the solution to the vapor pressures of the pure components.
Raoult's law states that the vapor pressure of a solution is equal to the vapor pressure of the pure solvent multiplied by its mole fraction in the solution. Mathematically, this can be expressed as:
P = P°X * X + P°Z * Z
X, P°Z is the vapor pressure of pure component Z, X and Z are the mole fractions of the respective components in the solution.
In this case, we are given that the mole fractions of X and Z in the solution are equal, i.e., X = Z = 0.5. We are also given the vapor pressures of pure X and pure Z, which are 140 mm Hg and 190 mm Hg, respectively. The experimentally measured vapor pressure of the solution is 170 mm Hg.
Raoult's law, we get:
170 mm Hg = (140 mm Hg * 0.5) + (190 mm Hg * 0.5)
170 mm Hg = 115 mm Hg + 95 mm Hg
170 mm Hg = 210 mm Hg
The calculated vapor pressure is higher than the experimentally measured value, which indicates that the interactions between the particles in the solution are weaker than the interactions between the particles in the pure components.
Since the vapor pressure is a measure of the escaping tendency of the particles in the liquid, weaker interactions mean that the particles are less tightly held in the liquid phase and more readily escape into the gas phase. This could be due to weaker intermolecular forces or a difference in the size or shape of the particles in the solution compared to those in the pure components.
Therefore, the relative strengths of the particle interactions in this solution are weaker than those in the pure components.
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In the proton-proton chain, the net reaction is that four hydrogen nuclei are converted to one helium nucleus and ________ are released. Group of answer choices
In the proton-proton chain, the net reaction is that four hydrogen nuclei are converted to one helium nucleus and two positrons are released.
During the proton-proton chain, four hydrogen nuclei fuse to form one helium nucleus. The neutrinos are neutral, low-mass particles that are released during the fusion process. In this process, four hydrogen nuclei (protons) undergo a series of reactions, ultimately forming one helium nucleus (two protons and two neutrons) and releasing two positrons, along with other particles and energy in the form of photons.
The proton-proton chain plays a crucial role in the energy production of stars, and its net reaction involves the conversion of four hydrogen nuclei into one helium nucleus, with the release of two positrons.
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A hydrogen atom is in the third excited state. To what state (give the quantum number n) should it jump to (a) emit light with the longest possible wavelength, (b) emit light with the shortest possible wavelength, and (c) absorb light with the longest possible wavelength?
To answer your question, we need to consider the energy level diagram of a hydrogen atom. The energy levels are given by the equation E = -13.6/n^2, where n is the principal quantum number.
(a) To emit light with the longest possible wavelength, the hydrogen atom should jump from the third excited state (n=4) to the second excited state (n=3). This transition corresponds to the emission of a photon with the lowest energy and longest wavelength, which corresponds to the red end of the visible spectrum.
(b) To emit light with the shortest possible wavelength, the hydrogen atom should jump from the third excited state (n=4) to the ground state (n=1). This transition corresponds to the emission of a photon with the highest energy and shortest wavelength, which corresponds to the violet end of the visible spectrum.
(c) To absorb light with the longest possible wavelength, the hydrogen atom should jump from the ground state (n=1) to the second excited state (n=3). This transition corresponds to the absorption of a photon with the lowest energy and longest wavelength, which again corresponds to the red end of the visible spectrum.
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How many grams of radium may be formed by the passage of 1.71 amps for 2.21 hours through an electrolytic cell that contains a molten radium salt.
The mass of radium formed by the passage of 1.71 A current for 2.21 hours through an electrolytic cell containing molten radium salt is 5.45 g.
The amount of substance (in moles) formed during electrolysis can be calculated using Faraday's law, which states that the amount of substance (in moles) formed is directly proportional to the charge passed through the electrolyte. The equation for Faraday's law is:
n = (Q) / (zF)
Where:
n = amount of substance formed (in moles)
Q = charge passed through the electrolyte (in coulombs)
z = charge number or valency of the ion being reduced or oxidized
F = Faraday's constant (96,485 C/mol)
Given:
Current (I) = 1.71 A
Time (t) = 2.21 hours = 2.21 x 3600 seconds (converted to seconds)
Charge (Q) = I x t (current multiplied by time)
Charge number of radium ion (z) = 2 (since radium has a charge of +2)
Faraday's constant (F) = 96,485 C/mol
Molar mass of radium (Ra) = 226 g/mol
Plugging in the values and solving for n:
Q = 1.71 A x 2.21 x 3600 s = 13,268 C
n = (13,268 C) / (2 x 96,485 C/mol) = 0.0687 mol
The mass of radium formed can be calculated using the molar mass of radium:
Mass = n x molar mass of radium = 0.0687 mol x 226 g/mol = 5.45 g
So, the mass of radium formed by the passage of 1.71 A current for 2.21 hours through the electrolytic cell containing molten radium salt is 5.45 g.
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A sample of gas occupies a volume of 71.3 mL . As it expands, it does 123.7 J of work on its surroundings at a constant pressure of 783 Torr . What is the final volume of the gas
The final volume of the gas is 0.0000671 m3
To solve this problem, we can use the formula for work done by a gas at constant pressure:
W = -PΔV
where W is the work done, P is the pressure, and ΔV is the change in volume.
We can rearrange this formula to solve for ΔV:
ΔV = -W/P
Substituting the given values, we get:
ΔV = -(123.7 J) / (783 Torr)
Note that we need to convert Torr to SI units of pressure (Pascal) before using it in the formula:
1 Torr = 133.322 Pa
So, 783 Torr = 104373.2 Pa
Substituting this value, we get:
ΔV = -(123.7 J) / (104373.2 Pa)
Simplifying, we get:
ΔV = -0.001184 m³
Since the initial volume was 71.3 mL, we need to convert it to cubic meters before adding the change in volume:
71.3 mL = 0.0000713 m³
Adding the change in volume, we get:
Final volume = initial volume + ΔV
Final volume = 0.0000713 m³ - 0.001184 m³
Final volume = 0.0000671 m³
Therefore, the final volume of the gas is 0.0000671 m³
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Answer:
The final volume of the gas is 0.06025 L.
Explanation:
We can use the formula for work done by a gas at constant pressure:
W = -PΔV
where W is the work done by the gas, P is the pressure, and ΔV is the change in volume. Since the pressure is constant, we can rearrange the formula to solve for the change in volume:
ΔV = -W/P
Plugging in the given values, we get:
ΔV = -(123.7 J)/(783 Torr)
Note that we need to convert the pressure from Torr to SI units (Pascals) before we can use it in the formula. 1 Torr is equal to 133.32 Pa, so:
ΔV = -(123.7 J)/(783 Torr * 133.32 Pa/Torr) = -0.01105 m³
Finally, we can find the final volume of the gas by adding the change in volume to the initial volume:
Vf = Vi + ΔV = 71.3 mL + (-0.01105 m³) = 0.0713 L - 0.01105 L = 0.06025 L
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Which of the following reagents, when treated with phenylmagnesium bromide followed by acid workup, will yield benzoic acid? a) carbon dioxide b) formaldehyde c) acetaldehyde d) carbon monoxide
The correct answer is: a) Carbon dioxide from amongst the reagents which are treated with phenylmagnesium bromide followed by acid. It gives benzoic acid.
When phenylmagnesium bromide (a Grignard reagent) is treated with carbon dioxide followed by an acid workup, benzoic acid is formed. Here's the step-by-step explanation:
1. Phenylmagnesium bromide reacts with carbon dioxide to form a magnesium salt of benzoic acid.
2. After completing the reaction, an acid workup (usually aqueous acidic solution) is added.
3. The magnesium salt is protonated by the acid, leading to the formation of benzoic acid.
Benzoic acid is a colorless crystalline solid and a common organic acid. Its chemical formula is C7H6O2, and it is also known as carboxybenzene or phenylformic acid. It is a weak acid that is often used as a food preservative, as it inhibits the growth of bacteria and fungi.
Benzoic acid can be found naturally in many fruits and berries, including cranberries, plums, and apples.
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In which of these substances are the atoms held together by metallic bonding?A. CrB. SiC. S8D. CO2E. Br2
Electrostatic attraction between metal cations and delocalized electrons produces metallic bonds. Many of the physical characteristics of metals, including conductivity and malleability, are explained by the type of metallic bonding that exists.
The substance in which the atoms are held together by metallic bonding is A. Cr (Chromium). Metallic bonding occurs between metal atoms, where the valence electrons are shared by all the atoms in a lattice structure, creating a strong bond. Cr is a transition metal and its atoms have a partially filled d orbital, which allows them to share their valence electrons and form metallic bonds.
B. Si (Silicon) is a non-metal and forms covalent bonds, where atoms share electrons with each other to form a stable molecule.
C. S8 (Sulfur) is a molecular substance where eight sulfur atoms are covalently bonded together in a ring structure, with weak van der Waals forces holding the molecules together.
D. CO2 (Carbon dioxide) is a molecular substance where one carbon atom is covalently bonded to two oxygen atoms, with the bonds formed by sharing electrons between atoms.
E. Br2 (Bromine) is a molecular substance where two bromine atoms are covalently bonded together, with the bonds formed by sharing electrons between atoms. Br2150 is not a known substance.
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Write the balanced equation for the reaction of aqueous Pb(ClO3)2Pb(ClO3)2 with aqueous NaI.NaI. Include phases
The Cr2O72- ion absorbs light of wavelength close to 500 nm. Based on this information, what can you conclude
Based on the information provided, we can conclude that the Cr2O72- ion has a visible absorption spectrum with a peak around 500 nm.
This means that when light with a wavelength close to 500 nm passes through a solution containing the Cr2O72- ion, the ion will absorb some of the light, resulting in a decrease in the intensity of the light passing through the solution at that wavelength.
This property can be used to identify the presence of the Cr2O72- ion in a solution and to determine its concentration using spectrophotometry.
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Answer:
The absorption of light by the Cr2O72- ion at a wavelength of 500 nm indicates that the ion has a visible absorption spectrum.
Explanation:
The absorption spectrum of a molecule or ion can provide information about its electronic structure and chemical properties, which can be useful in many areas of chemistry and physics.
This absorption corresponds to a transition between energy levels in the ion, which may involve the promotion of an electron to a higher energy level..
In addition, the absorption of light by the Cr2O72- ion at this wavelength may be used in analytical techniques such as spectrophotometry to quantitatively determine the concentration of the ion in a sample.
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How many moles of carbon dioxide are produced when 18.6 g of HF are reacted with an excess amount of sodium carbonate
0.4645 moles of carbon dioxide are produced when 18.6 g of HF are reacted with an excess amount of sodium carbonate.
To answer this question, we first need to write out the balanced chemical equation for the reaction between HF and sodium carbonate:
2HF + Na₂CO₃ -> 2NaF + CO₂ + H₂O
From this equation, we can see that for every 2 moles of HF that react, 1 mole of CO₂ is produced.
To determine the number of moles of HF in 18.6 g, we need to use the molar mass of HF, which is 20.01 g/mol:
moles of HF = mass / molar mass = 18.6 g / 20.01 g/mol = 0.929 moles
Since there is an excess amount of sodium carbonate, all of the HF will be consumed in the pressure reaction, so we can use the ratio of 2 moles HF to 1 mole CO₂ to calculate the number of moles of carbon dioxide produced:
moles of CO₂ = 0.929 moles HF x (1 mole CO₂ / 2 moles HF) = 0.4645 moles
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What is the volume percentage of butanol if a solution contains 37 L of butanol in 100. L of solution
The volume percentage of butanol in the given solution is 37%.
Butanolis a four-carbon alcohol with the formula C4H9OH that may be found in five isomeric configurations (four structural isomers), ranging from straight-chain primary alcohol to branched-chain tertiary alcohol.
The volume percentage of butanol in the given solution can be calculated using the formula:
Volume Percentage = (Volume of Butanol ÷ Total Volume of Solution) × 100
Substituting the given values in the formula, we get:
Volume Percentage = (37 L ÷ 100 L) × 100
Volume Percentage = 37%
Therefore, the volume percentage of butanol in the given solution is 37%.
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Which gas has the same density at 316 °C and 1.50 atm that O2 gas has at 0°C and 1.00 atm? a. SO2 b. N2 c. NO2 d. CO2 e. CI2
The correct answer to the given question is option b. N2
The answer can be found by using the ideal gas law, which states:
PV = nRT
Where:
P = pressure
V = volume
n = number of moles
R = gas constant
T = temperature
Assuming that the volume and the number of moles are constant, the equation can be simplified to:
(P/T)1 = (P/T)2
Where subscripts 1 and 2 represent the initial and final conditions, respectively.
We can use this equation to find the temperature at which the density of the given gas is the same as that of O2 gas at 0°C and 1.00 atm. The molar mass of O2 is 32.00 g/mol.
Let's first convert the initial and final temperatures to Kelvin:
316 °C = 589 K
0°C = 273 K
Now, let's solve for the pressure of the given gas:
(P/T)1 = (P/T)2
(P/589) = (1.50/273) (using the values given in the question)
P = (1.50/273) * 589
P = 3.23 atm
Next, we can use the density equation:
density = (molar mass * pressure) / (gas constant * temperature)
For O2 at 0°C and 1.00 atm, the density is:
density = (32.00 g/mol * 1.00 atm) / (0.08206 Latm/molK * 273 K)
density = 1.43 g/L
Now we can solve for the temperature at which the density of the given gas is also 1.43 g/L:
1.43 = (molar mass * 3.23) / (0.08206 * T)
T = (molar mass * 3.23) / (0.08206 * 1.43)
T = 258 K = -15°C
Therefore, the gas that has the same density at 316°C and 1.50 atm that O2 gas has at 0°C and 1.00 atm is nitrogen gas (N2).
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Urea, (NH2)2CO, is a product of metabolism of proteins. An aqueous solution is 31% urea by mass and has a density of 1.038 g/ml. Calculate the molarity of urea in this solution. Enter to 2 decimal places.
The molarity of urea in the given aqueous solution is 5.31 M.
First, we need to determine the mass of urea present in 100 g of the solution:
Mass of urea in 100 g of solution = 31 g
Next, we can use the density of the solution to determine the volume of 100 g of the solution:
Volume of 100 g of solution = 100 g / 1.038 g/mL = 96.3 mL
We can then convert the mass of urea to moles of urea using its molar mass:
Molar mass of urea = 60.06 g/mol
Moles of urea = 31 g / 60.06 g/mol = 0.516 mol
Finally, we can calculate the molarity of the urea solution:
Molarity of urea = moles of urea / volume of solution in liters
= 0.516 mol / 0.0963 L
= 5.31 M (to 2 decimal places)
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Benzyl bromide (C6H5CH2Br) reacts rapidly with CH3OH to afford benzyl methyl ether (C6H5CH2OCH3).Draw a stepwise mechanism for the reaction, and explain why this 1∘ alkyl halide reacts rapidly with a weak nucleophile under conditions that favor an SN1 mechanism.Would you expect the para-substituted benzylic halides CH3OC6H4CH2Br and O2NC6H4CH2Br to each be more or less reactive than benzyl bromide in this reaction? Explain your reasoning.
[tex]CH_3OC_6H_4CH_2Br[/tex], which has an electron-donating substituent, would be more reactive than benzyl bromide, while [tex]O_2NC_6H_4CH_2Br[/tex], which has an electron-withdrawing substituent, would be less reactive.
The stepwise mechanism for the reaction of benzyl bromide ([tex]C_6H_5CH_2Br[/tex]) with [tex]CH_3OH[/tex] to afford benzyl methyl ether ([tex]C_6H_5CH_2OCH_3[/tex]) involves the following steps:
1. Formation of carbocation: The alkyl halide, benzyl bromide, undergoes heterolytic cleavage of the C-Br bond to form a carbocation intermediate ([tex]C_6H_5CH_2^+[/tex]).
2. Nucleophilic attack: The nucleophile, [tex]CH_3OH[/tex], attacks the carbocation intermediate to form the desired product, benzyl methyl ether, and HBr.
The reaction occurs rapidly because benzyl bromide is a 1st-degree alkyl halide, which means that the carbocation intermediate is relatively stable due to the presence of the aryl group. This stability allows for the formation of the carbocation intermediate even under conditions that favor an SN1 mechanism. Additionally, [tex]CH_3OH[/tex] is a weak nucleophile, which means that it is not hindered by steric effects and can easily attack the carbocation intermediate.
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A current of 4.82 A is passed through a Sn(NO3)2 solution. How long, in hours, would this current have to be applied to plate out 6.70 g of tin
Therefore, the current would have to be applied for 9.96 hours to plate out 6.70 g of tin.
The amount of tin deposited on the electrode is directly proportional to the quantity of electricity that passed through the circuit. The formula that relates the amount of substance deposited with the electric current and time is:
mass = (current x time x atomic mass) / (valence electrons x Faraday's constant)
We can rearrange this formula to solve for time:
time = (mass x valence electrons x Faraday's constant) / (current x atomic mass)
Substituting the given values, we have:
time = (6.70 g x 2 x 96485 C/mol) / (4.82 A x 118.71 g/mol) = 9.96 hours
So, the current would have to be applied for 9.96 hours to plate out 6.70 g of tin.
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in part 1 predict the product of the following three-step sequence, and then in parts 2 -4 classify each step as either a functional group transformation or a carbon–carbon bond-forming reaction.
Step 1 is a functional group transformation, while steps 2 and 3 are carbon-nitrogen bond forming and carbon-carbon bond forming reactions respectively.
In order to predict the product of the three-step sequence, we need to first identify the reactants and the reagents involved in each step. The three steps are:
Step 1: Benzene reacts with bromine in the presence of FeBr3 as a catalyst to form bromobenzene.
C6H6 + Br2 + FeBr3 → C6H5Br + HBr + FeBr2
Step 2: Bromobenzene reacts with sodium amide (NaNH2) in liquid ammonia (NH3) to form phenylsodium (C6H5Na).
C6H5Br + NaNH2 → C6H5Na + NaBr + H2
Step 3: Phenylsodium reacts with methyl iodide (CH3I) to form toluene.
C6H5Na + CH3I → C6H5CH3 + NaI
In step 1, we see a substitution reaction where a hydrogen on the benzene ring is replaced by a bromine atom, resulting in a functional group transformation. In step 2, we see a carbon-nitrogen bond forming reaction where the bromine atom is replaced by a sodium atom to form a phenylsodium intermediate. This is also a functional group transformation as we are replacing a halogen atom with a metal atom. In step 3, we see a carbon-carbon bond forming reaction where the phenylsodium intermediate reacts with methyl iodide to form toluene. This is a carbon-carbon bond forming reaction.
In summary, step 1 is a functional group transformation, while steps 2 and 3 are carbon-nitrogen bond forming and carbon-carbon bond forming reactions respectively.
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Chrysoberyl is ___. Group of answer choices A light green-yellow form of Beryl very common throughout the world only formed in beryllium-poor environments
Chrysoberyl is Faceted to produce "cyclic twins" which is the correct option E.
Chrysoberyl is a beryllium aluminate mineral or gemstone with the chemical formula BeAl₂O₄. Chrysoberyl and beryl are two very distinct gemstones, despite the fact that their names are similar and they both contain beryllium. On the Mohs scale of mineral hardness, chrysoberyl, which ranks between corundum and topaz at 8.5, is the third-hardest naturally occurring gemstone that is often found.
Pegmatitic mechanisms result in the formation of chrysoberyl. Relatively low-density molten lava is created during melting in the Earth's crust and has the ability to ascend higher and reach the surface. Because water could not be integrated into the crystallisation of solid minerals, it grew increasingly concentrated in the molten rock as the primary magma body cooled.
As a result, the remaining magma is more abundant in water and uncommon elements that also do not fit into the crystal structures of the main minerals that form rocks. By lowering the temperature range before the magma solidifies fully, water allows the concentration of rare elements to advance to the point where they can create their own unique minerals.
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Complete question:
Chrysoberyl is
A light green-yellow form of Beryl
very common throughout the world
only formed in beryllium-poor environments
the 3rd hardest natural gemstone
Faceted to produce "cyclic twins"
A process increases the entropy of the system by 119 J/mol K and absorbs 38 kJ/mol of heat from the surroundings. Does this process favor products at high temperature or low temperature
This process favor products at high temperature because ∆G is positive (∆G > 0), it indicates that the reaction is non-spontaneous and favors the formation of products at high temperature.
In the context of a non-spontaneous reaction, the process would favor products at a high temperature. Non-spontaneous reactions require an input of energy to proceed, and increasing the temperature can provide the necessary energy to drive the reaction in the forward direction.
By supplying heat and raising the temperature, the system can overcome the energy barrier and favor the formation of products.
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. A flask containing 155 cm3 of hydrogen was collected under a pressure of 22.5 kPa. What pressure would have been required for the volume of the gas to have been 90.0 cm3, assuming the same temperature
A pressure of 38.8 kPa would have been required for the volume of hydrogen gas to have been 90.0 cm3, assuming the same temperature.
Boyle's Law states that the pressure of a gas is inversely proportional to its volume, when the temperature and the amount of gas are constant. This can be represented mathematically as:
P1V1 = P2V2
where P1 and V1 are the initial pressure and volume, and P2 and V2 are the final pressure and volume.
We can rearrange the equation to solve for P2:
P2 = (P1V1)/V2
Substituting the given values:
P2 = (22.5 kPa x 155 cm³) / 90.0 cm³ P2 = 38.8 kPa
Boyle's Law is a fundamental gas law that describes the relationship between the pressure and volume of a gas, assuming that the temperature and the number of gas particles are constant. It was first formulated by the Irish scientist Robert Boyle in the 17th century.
The law states that as the pressure of a gas increases, its volume decreases proportionally, and vice versa. This can be expressed mathematically as P₁V₁ = P₂V₂, where P₁ and V₁ are the initial pressure and volume of the gas, and P₂ and V₂ are the final pressure and volume. This law is often used in practical applications, such as in scuba diving, where changes in pressure and volume affect the amount of air needed for breathing. Boyle's Law is also important in understanding the behavior of gases in many industrial and scientific processes.
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Oxygen and copper are produced during the electrolysis of a CuO solution. Which reaction occurs at the positive electrode
The reaction that occurs at the positive electrode during the electrolysis of a CuO solution is:
2O²⁻→ O₂ + 4e⁻
During the electrolysis of a CuO solution, oxygen gas is produced at the positive electrode (also known as the anode). This is because the positive electrode attracts negatively charged ions, which are oxide ions (O²⁻), and causes them to lose electrons and form oxygen gas. The copper ions (Cu²⁺) from the CuO solution will be attracted to the negative electrode (also known as the cathode) and gain electrons, which will cause them to form solid copper metal.
So overall, the reaction at the positive electrode is 2O²⁻→ O₂ + 4e⁻.
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