Which statement about hemiacetals is false? a. a hemiacetal is a geminal hydroxy ether. b. they are formed by the nucleophilic attack of an alcohol on an aldehyde. c. they can be converted to a ketal. d. the formation reaction is a two step process, catalyzed by acids. e. the formation reaction is reversible.

Answers

Answer 1

The false statement about hemiacetals is option A) that they are geminal hydroxy ethers.

Hemiacetals are formed by the nucleophilic attack of an alcohol on an aldehyde, and they can be converted to a ketal. The formation reaction is a two-step process catalyzed by acids, and it is reversible. However, hemiacetals are not considered geminal hydroxy ethers because geminal hydroxy ethers have two hydroxy groups on the same carbon atom, whereas hemiacetals have a hydroxy group and an alkoxy group on adjacent carbon atoms.

Hemiacetals are functional groups that have an alkyl or aryl group, an alkoxy group (-OR), a hydroxyl group (-OH), and a carbon atom linked to each of these groups. They are created when an alcohol and a carbonyl group (C=O) combine in the presence of an acid catalyst. Aldehydes and ketones can both produce hemiacetals, however aldehydes are the more typical source of these compounds. Hemiacetals are comparatively unstable and easily dehydrate to produce acetals, which are more stable substances. Hemiacetals are crucial to organic chemistry, especially in the synthesis of the glycosidic linkages found in carbohydrates.

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Answer 2

Hemiacetals are formed by the reaction of an aldehyde with an alcohol and can be converted to ketals. The reaction requires an acid catalyst and is reversible, with the equilibrium position depending on the reaction conditions. The false statement is that hemiacetals are geminal hydroxy ethers.

- Option a is false because a hemiacetal is not a geminal hydroxy ether. A geminal diol is a compound with two hydroxyl groups on the same carbon atom, while a hemiacetal has a hydroxyl group (-OH) and an alkoxy group (-OR) on the same carbon atom.

- Option b is true. Hemiacetals are formed by the reaction between an aldehyde and an alcohol, where the alcohol acts as a nucleophile and attacks the carbonyl carbon of the aldehyde, forming a new C-O bond and breaking the C=O bond.

This reaction is reversible, and the equilibrium position depends on the identity of the aldehyde and alcohol and the reaction conditions.

- Option c is true. Hemiacetals can be converted to ketals by the addition of another alcohol molecule under acidic conditions.

In this reaction, the hemiacetal is protonated by the acid, making it a better leaving group, and the second alcohol molecule attacks the carbonyl carbon, forming a new C-O bond and expelling water. This reaction is also reversible and depends on the reaction conditions.

- Option d is true. The formation of a hemiacetal from an aldehyde and an alcohol requires the presence of an acid catalyst, which can either be a mineral acid (such as HCl or H2SO4) or an organic acid (such as p-toluenesulfonic acid).

The acid protonates the carbonyl oxygen of the aldehyde, making it more susceptible to nucleophilic attack by the alcohol. After the alcohol attacks, the acid catalyst deprotonates the hemiacetal, regenerating the catalyst and releasing a water molecule.

- Option e is true. As mentioned before, the formation of hemiacetals and ketals is reversible. The equilibrium position depends on the identity of the aldehyde and alcohol, the reaction conditions, and the presence of any acid or base catalysts.

If the equilibrium is shifted towards the hemiacetal/ketal side, then the reaction is more likely to be reversible. If the equilibrium is shifted towards the aldehyde/alcohol side, then the reaction is more likely to be irreversible.

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Related Questions

What is the smallest whole-number coefficient for h₂s when the equation h₂s mno₄⁻ → mn²⁺ so₄²⁻ is balanced in acidic solution?

Answers

The lowest smallest whole-number coefficient for H₂S is 5. Option C

What is the smallest whole-number coefficient for H₂S?

Now we know that a redox reaction is one in which there is a loss and gain of electrons One specie is oxidized (looses electrons) while another specie is reduced (gains electrons). The electrons must be transferred leading to an increase in oxidation number of one specie and a decrease in the oxidation number of another.

Now the reduction half equation is;

MnO4^-(aq) + 8H^+(aq) + 5e^- ----> Mn^2+(aq) + 4H2O (l)

The oxidation  half equation is;

H2S(aq) ----> S^2-(aq) + 2H^+(aq) + 2e^-

Multiplying the reduction half equation by 2 and the  oxidation  half equation is 5

2MnO4^-(aq) + 16H^+(aq) + 10e^- ----> 2Mn^2+(aq) + 8H2O (l)

And;

5H2S(aq) ----> 5S^2-(aq) + 10H^+(aq) + 10e^-

The overall balanced reaction equation is;

2MnO4^-(aq) + 6H^+(aq) + 5H2S(aq) ----> 2Mn^2+(aq) + 8H2O (l) + 5S^2-(aq)

Thus the lowest smallest whole-number coefficient for H₂S is 5.

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What mass of oxygen reacts during the incomplete combustion of 18.0 g of propane?

Answers

Answer:

66 grams of carbon dioxide

C3H8+5O2=3CO2+4H2O

In a mining community, groups of dead fish appear in a local river every few weeks. These fish kills coincide with incidents of mining waste dumped into the river. Which of the following components is an abiotic factor causing these fish kills?

Human activities
Biodiversity in the river
Water pollution
Overfishing

Answers

In a mining community, water pollution kills the fish in local river.

How does mining affect the rivers?

Large amounts of water are frequently used in mining, which has the potential to contaminate local groundwater, rivers, streams, and other water sources. A community's ability to grow its own food may be hampered by mining since it consumes grazing or agricultural land and pollutes the soil and the environment.

Metals that leach from the rock also contaminate nearby water sources when they do so. chemical processing pollution: When minerals are extracted from their ores using cyanide or sulfuric acid and water, the runoff pollutes the rivers in the area.

Through erosion and sedimentation, dewatering of wetlands, diverting and channelizing streams, and poisoning surface water and aquifers with harmful chemicals, surface mining can have an impact on fish and aquatic resources.

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Answer:

a

Explanation:

A mole is a name for a specific number of things. What is the value of a mole? write the number using scientific notation. By what other name is it known? (2 points)

Answers

The value of a mole is 6.022 ×[tex]10^{23}[/tex]. The other name of mole is Avogadro's number.

The mole is define as  6.022 ×[tex]10^{23}[/tex] of the chemical unit like atoms , molecules, ions or others.It is very convenient unit because of huge numbers o f atoms, molecules or others. This is very important unit used by chemist.

One mole = atomic Mass of atoms / molecular mass of molecule

Example: one mole of sodium = 23 g = atomic mass

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What is the name of the amide bond between amino acids?
a. polyamide bond
b. polyamine bond
c. polyamino acids bond
d. protein bond
e. peptide bond

Answers

The name of the amide bond between amino acids will be peptide bond.

Peptide bonds are amide-type covalent bonds that form bonds that connect two adjacent alpha-amino acids throughout peptide or protein chains, starting at C1 of one as well as [tex]N_{2}[/tex] of another.

The substances are known as amino acids, or the "building blocks of proteins," and play a variety of vital functions in the human body. Humans require them for essential functions like producing hormones, neurotransmitters, even proteins. In meals high in protein like meat, fish, as well as soybeans, amino acids could be concentrated.

Therefore, the name of the amide bond between amino acids will be peptide bond.

Hence, the correct answer will be option (e)

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You have two buffered solutions. Buffered solution 1 consists of 5.0 M HOAc and 5.0 M NaOAc; buffered solution 2 is made of 0.050 M HOAc and 0.050 M NaOAc. How do the pHs of the buffered solutions compare

Answers

The pH of buffered solution is:

The two buffered solutions have 'equal' pH values.

Comparison between two buffer solutions:

To compare the pH of two different buffer solutions with different concentrations, Henderson-Hasselbalch equation is used.

pH = pKa + log [tex]\frac{Salt}{Acid}[/tex]

pKa of HOAc = 4.76

In solution 1:

Concentration of salt= 5 M

Concentration of acid= 5 M

Putting the values in the equation,

pH = 4.76 + log [tex]\frac{5}{5}[/tex]

pH = 4.76 + log1

pH = 4.76

In solution 2:

Concentration of salt= 0.050 M

Concentration of acid= 0.050 M

Putting the values in the equation,

pH = 4.76 + log[tex]\frac{0.050}{0.050}[/tex]

pH = 4.76 + log1

pH = 4.76

As the ratio  [tex]log\frac{salt}{acid}[/tex] is the same for the different solutions.

Therefore, the pH of the solution remains the same in both the buffer solutions even if the two solutions have different concentrations.

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Please show all work:
If 40.0 grams of magnesium is reacted with an excess of nitric acid, HNO 3 , how many
grams of hydrogen gas will be produced?

Answers

3.3 g of hydrogen gas will be produced.

What is Stoichiometry ?

Stoichiometry helps to measure quantitative relationships between the amounts of products and reactants that are given in a reaction.

What is Balanced Chemical Equation ?

The balanced chemical equation is the equation in which the number of atoms on the reactant side is equal to the number of atoms on the product side in an equation.

Now we have to write the balanced equation

Mg + 2HNO₃  → Mg(NO₃)₂ + H₂

According to Stoichiometry

[tex]40.9\ \text{g Mg} \times \frac{1\ \text{mol Mg}}{24.31\ \text{g Mg}} \times \frac{1\ \text{mol}\ H_2}{1\ \text{mol Mg}} \times \frac{2.02\ g\ H_2}{1\ \text{mol}\ H_2}[/tex]

= 3.3 g H₂

Thus from the above conclusion we can say that 3.3 g of hydrogen gas will be produced.

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Consider the following intermediate chemical equations.
CH₂(g) → C(s) + 2H₂(g)
ΔΗ, = 74.6KJ
CCl4(g) →C(s) + 2Cl₂(g)
AH₂ = 95.7 kJ
H₂(g) + Cl₂(g) → 2HCl(g)
AH₂=-92.3 KJ
What is the enthalpy of the overall chemical reaction CH4(g)+4Cl₂(g) → CCl4(g) + 4HCI(g)?
O-205.7 kJ
O-113.4 kJ
O-14.3 kJ
O 78.0 kJ

Answers

Based on the calculations, the enthalpy of the overall chemical reaction is equal to: C. -14.3 kJ.

What is a chemical reaction?

A chemical reaction can be defined as a chemical process that involves the continuous transformation (rearrangement) of the ionic, atomic or molecular structure of a chemical element by breaking down and forming chemical bonds, in order to produce a new chemical compound while new bonds are formed.

What is a chemical equation?

A chemical equation can be defined as a group of chemical symbols that is typically used in chemistry to represent the chemical reaction between two (2) or more chemical elements.

Mathematically, an expression for enthalpy of the overall chemical reaction is given by:

ΔHrxn = (n × ΔH₃) + (-n × ΔH₁) + (n × ΔH₂)

Where:

n represents the number of moles.

Substituting the given points into the formula, we have;

ΔHrxn = (2 × ΔH₃) + (-1 × ΔH₁) + (1 × ΔH₂)

ΔHrxn = (2 × (-92.3)) + (-1 × (-74.6)) + (1 × (-95.7))

ΔHrxn = -184.6 + 74.6 + 95.7

ΔHrxn = -14.3 kJ.

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In the redox reaction below, which is the reducing agent?

MnO2(s) + 4H+(aq) + 2Cl–(aq) Right arrow. Mn2+(aq) + 2H2O(l) + Cl2(g)
CI–
CI2
Mn2+
MnO2

Answers

In the following redox reaction, the reducing agent is MnO2 (option D). Details about reducing agent can be found below.

What is a reducing agent?

A reducing agent in a redox reaction is any substance that reduces, or donates electrons to another, hence, it becomes oxidized.

According to this question, a redox reaction is given as follows: MnO2(s) + 4H+(aq) + 2Cl–(aq) = Mn2+(aq) + 2H2O(l) + Cl2(g)

As shown in the equation, MnO2 is oxidized into Mn2+, therefore, it is the reducing agent.

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What are the correct half reactions for the following reaction:
Zn + 2 HCI -> H₂ +zncl2

Answers

Answer:

Zn(s) + 2H+(aq) => Zn²+(aq) + H2 (g)

Explanation:

The equation Zn + 2 HCI -> H₂ +zncl2 on reduction and oxidation, it results as below;

2H+ + 2e- => H2 ; reductionZn => Zn²+ + 2e- ; oxidation

The equations above are half cell.

On combination of the above half cell reaction equations gives;

Zn(s) + 2H+(aq) => Zn²+(aq) + H2 (g).

Therefore, the half reaction equation for Zn + 2 HCI -> H₂ +zncl2 is given by;

Zn(s) + 2H+(aq) => Zn²+(aq) + H2 (g).

Zinc Sulfide reacts with oxygen according to the reaction:

2ZnS (s) + 3 O2(g) 2 ZnO (s) +2 SO2 (g)

A reaction mixture contains 4.2 moles of zinc sulfide and 6.8 moles of oxygen. Once the reaction occurred as a completely as possible, what amount in moles is left of the excess reactant?

Answers

The amount in moles of the excess reactant left is 0.5 mole

Balanced equation

2ZnS (s) + 3O₂(g) --> 2ZnO (s) + 2SO₂(g)

From the balanced equation,

2 moles of ZnS reacted with 3 moles of O₂

How to determine the excess reactant

From the balanced equation,

2 moles of ZnS reacted with 3 moles of O₂

Therefore,

4.2 moles of ZnS will react with =(4.2 × 3) / 2 = 6.3 moles of O₂

From the calculations made above, we can see that only 6.3 moles of O₂ out of 6.8 moles given, is required to react completely with 4.2 moles of ZnS.

Thus, ZnS is the limiting reactant and O₂ is the excess reactant.

How to determine the mole of the excess reactant remaining

The excess reactant is O₂. Thus the mole remaining after the reaction can be obtained as illustrated below:

Mole of O₂ given = 6.8 molesMole of O₂ that reacted = 6.3 molesMole of O₂ remaining =?

Mole of O₂ remaining = (Mole of O₂ given) - (Mole of O₂ that reacted)

Mole of O₂ remaining = 6.8 - 6.3

Mole of O₂ remaining = 0.5 mole

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Which molecules are types of lipids?

Answers

Answer: The answer is fatty acids and triglycerides

Explanation:

If 10.0 moles of sulfur dioxide react with excess chlorine gas, what is the theoretical yield (in grams) of CI2O produced?

Answers

Answer:

869 g Cl₂O

Explanation:

To find the theoretical yield of Cl₂O, you need to (1) convert moles SO₂ to moles Cl₂O (via mole-to-mole ratio from reaction coefficients) and then (2) convert moles Cl₂O to grams Cl₂O (via molar mass). It is important to arrange the conversions/ratios in a way that allows for the cancellation of units (the desired unit should be in the numerator). The final answer should have 3 sig figs to reflect the sig figs of the given amount (10.0 moles).

1 SO₂ (g) + 2 Cl₂ (g) ----> 1 SOCl₂ (g) + 1 Cl₂O (g)

Molar Mass (Cl₂O): 2(35.453 g/mol) + 15.998 g/mol

Molar Mass (Cl₂O): 86.904 g/mol

10.0 moles SO₂         1 mole Cl₂O            86.904 g
------------------------  x  ----------------------  x  ------------------  = 869 g Cl₂O
                                    1 mole SO₂              1 mole

How many moles of MgCl₂ are present in 60.0 mL of 0.100 M MgCl₂ solution?

Answers

There is 0.0600moles of MgCl2 in 60.0ml of 0.100M MgCl2 solution.

Explanation:

First we need to determine the number of moles of MgCl2 in 60.0L of solution.

After determining the number of moles,now multiply moles of MgCl2 by its Molar mass i.e (95.205g/mol)

We know Molarity= mol of solute/L solution

∴ 0.10 M MgCl2 = 0.10mol MgCl2/L

Step1:

First convert 60.0ml to litres.

1L=1000mL

60.0mL×1L/1000mL=0.0600L

Step2:

To determine moles of MgCl2, multiply 0.0600 L by the molarity of the solution

0.0600L×0.10mL/1L=0.0600mol MgCl2

∴ 0.0600moles of MgCl2 are present in 60.0mL of 0.100M MgCl2 solution.

what is molar mass?

Relative molar mass is defined as the smallest mass unit of a compound with one twelfth of the mass of one carbon – 12 atom.

In a substance, the amount of entities present for e.g. atoms, molecules, ions, is defined as a mole. A mole of any substance is 6.022×1023 molecules. Just as we take a standard value to calculate different things e.g. 1 dozen =12 items similarly we use the mole to calculate the size of the smallest entities quantitatively.

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what is molarity?

Molarity of a solution is defined as the number of moles of the solute dissolved per litre of the solution. I is represented as \textbf{`M`}. Thus a solution, which contains one gram mole of the the solution dissolved per litre* of the solution is regarded as molarity.

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Given the incomplete equation for the combustion of ethane (C2H6): 2 C2H6 7 O2 --> 4 CO2 6 ___ Group of answer choices

Answers

The correct option is D. H2O.

For the combustion of ethane (C2H6); the chemical equation is;

2 C2H6 + 7 O2 --> 4 CO2 + 6 H2O.

All hydrocarbons go through combustion processes, and the only byproducts are water (H2O) & carbon dioxide (CO2).

What is hydrocarbons?

Any of a group of organic molecules with only the atoms carbon (C) & hydrogen are known as hydrocarbons (H). The hydrogen atoms bind to the carbon atoms in a variety of ways to create the compound's structural framework. chemical mixture.

The classification of hydrocarbons are done by-

It is not necessary for a substance to be classified into a single class; rather, this categorization of hydrocarbons is meant to help in the association of structural traits with properties. In fact, it is typical for molecules to contain structural elements that are unique to two or even more hydrocarbon families. For instance, a molecule with a benzene ring and a carbon-carbon triple bond would have certain features that are typical of alkynes and some that are typical of arenes.Alkenes, alkynes, and aromatics are referred to as unsaturated hydrocarbons, whilst alkanes are regarded as saturated hydrocarbons.

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The complete question is -

Given the incomplete equation for the combustion of ethane (C2H6): 2 C2H6 + 7 O2 --> 4 CO2 + 6 ___

Group of answer choices:

A. H2O2

B. HCOOH

C. CH3OH

D. H2O

A generic element, Q, has two isotopes, 195Q and 190Q, and an average atomic mass of 191.86 amu. The natural abundances of the two isotopes are 38% 195Q and 62% 190Q. The isotopic mass of 195Q is 194.96 amu. What is the isotopic mass of 190Q

Answers

A generic element, Q, has two isotopes, 195Q and 190Q, and an average atomic mass of 191.86 amu. The natural abundances of the two isotopes are 38% 195Q and 62% 190Q. The isotopic mass of 195Q is 194.96 amu.  the isotopic mass of 190Q is 186.80.

What do you mean by Isotopes?

Isotopes are two or more atom types that share the same atomic number (number of protons in their nuclei), location in the periodic table, and chemical element but have distinct nucleon numbers (mass numbers) as a result of having a different number of neutrons in their nuclei. Although the chemical properties of each isotope of a given element are nearly identical, they differ in their atomic weights and physical characteristics.

191.86 =(62% x 194.96 + 38% x  X )

where, X is the mass of other Isotope.

X     = (191.86  - 120.8752)/0 .38

       = 186.80

Parent and Daughter Isotopes

The initial radioisotope and the isotope that results from radioactive decay may not be the same. The atoms created by the reaction are known as daughter isotopes, whereas the original isotope is known as the parent isotope. It's possible to get different kinds of daughter isotopes.

As an illustration, the uranium atom is the parent isotope and the thorium atom is the daughter isotope when U-238 decays into Th-234.

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You can use mass percent composition as a conversion factor between grams of a constituent element and grams of the compound. Write the conversion factor (including units) inherent in each mass percent composition. (a) Water is 11.19% hydrogen by mass. (b) Fructose, also known as fruit sugar, is

Answers

You can use mass percent composition as a conversion factor between grams of a constituent element and grams of the compound. The conversion factor in each mass percent composition are (a) 11.19 g H‚ 100 g H₂O (b) 53.29 g O‚100 g fructose (c) 84.12 g C‚100 g octane (d) 52.14 g C‚100 g ethanol

What is the Mass Percent ?

The percent by mass of each element present in a compound is called Mass Percent.

(a) Water is 11.19% hydrogen by mass.

Here it is given mass of hydrogen is 11.19 %. That means 11.19 % of solute should be added in 100 g H₂O.

(b) Fructose, also known as fruit sugar, is 53.29% oxygen by mass.

Here it is given mass of oxygen is 53.29 %. That means in 53.29% of solute should be added in 100 g fructose.

(c) Octane, a component of gasoline, is 84.12% carbon by mass.

Here it is given mass of carbon is 84.12 %. That means in 84.29% of solute should be added in 100 g Octane.

(d) Ethanol, the alcohol in alcoholic beverages, is 52.14% carbon by mass.

Here it is given mass of carbon is 52.14 %. That means in 52.14% of solute should be added in 100 g Ethanol.

Thus from the above conclusion we can say that You can use mass percent composition as a conversion factor between grams of a constituent element and grams of the compound. The conversion factor in each mass percent composition are (a) 11.19 g H‚100 g H2O (b) 53.29 g O‚100 g fructose (c) 84.12 g C‚100 g octane (d) 52.14 g C‚100 g ethanol

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Disclaimer: The question was given incomplete on the portal. Here is the complete question.

Question: You can use mass percent composition as a conversion factor between grams of a constituent element and grams of the compound. Write the conversion factor (including units) inherent in each mass percent composition.

(a) Water is 11.19% hydrogen by mass.

(b) Fructose, also known as fruit sugar, is 53.29% oxygen by mass.

(c) Octane, a component of gasoline, is 84.12% carbon by mass.

(d) Ethanol, the alcohol in alcoholic beverages, is 52.14% carbon by mass.

Conclusion: why do you think it is important to record your data with all the decimals provided by the instruments even if they are zero? How does this help with data analysis?

Answers

It increases the degree of accuracy for your results.

Which state of matter is being described below?
It cannot be squashed easily, spreads out slowly, is of medium density & flows to
fill up space
A. Plasma
B. Liquid
C. Gas
D. Solid

Answers

Answer:

C. Gas

Explanation:

I think this is the right answer because it fits the description

The procedure calls for 2.0 ml of concentrated nitric acid. how many moles is this?

Answers

Answer:

ρHNO₃= 1.51 g/cm3

ρ = m/V

m = ρ x V

m = (1.51 g/cm3)(2 cm3)= 3.02 g de HNO₃

n = m/PM = 3.02 g/63.01 g/mol = 0.0479 mol de HNO₃

Explanation:

2 mL of concentrated nitric acid equals 0.0479 mol

H. If you had 64 amu of ch4, how many molecules would this be? i. If you had 64 g of ch4, how many moles would this be?

Answers

The number of molecules and number of moles of [tex]CH_{4}[/tex] is 4 moles and 24.088×[tex]10^{23}[/tex] molecules.

Calculation,

Atomic mass of carbon is 12 u and H is 1 u

So, molar mass of [tex]CH_{4}[/tex] = 12 + 1×4 = 16 u = 16 g/mole

Number of moles = given mass / molar mass = 64 g/ 16 g/mol = 4 moles

1 moles of substance contains 6 .022 ×[tex]10^{23}[/tex] molecules.

So, number of molecules in 3 moles of methane = 4×6.022 ×[tex]10^{23}[/tex]  

number of molecules in 3 moles of methane  = 24.088×[tex]10^{23}[/tex] molecules.

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Liquids A and B form an ideal solution. The vapor pressure of pure A is 0.700 atm at the normal boiling point of a solution prepared from 0.250 mole of B and 0.650 mole of A. What is the vapor pressure of pure B at this temperature

Answers

The vapor pressure of pure B is 1.77atm

Given:-

Vapor pressure of Pure A = 0.700atm

Mole of A = 0.650mole

Mole of B = 0.250mole

Dalton's law of partial pressures states that the total pressure exerted by a gas mixture is equal to the sum of the partial pressures of all of the constituent gases.

So, Ptotal =  [tex]P_A + P_B[/tex]

According to Raoult's law, a solvent's partial vapor pressure in a solution (or mixture) is equal to or the same as the pure solvent's vapor pressure times the mole fraction present in the solution.

So, Ptotal =  [tex]X_AP_A + X_BP_B[/tex]

Ptotal = 1atm

1atm = (0.650/0.650+0.250 X 0.700atm) + 0.250/0.650+0.250 X [tex]P_B[/tex]

1atm = 0.722 X 0.700atm + 0.278 X [tex]P_B[/tex]

1atm = 0.506atm + 0.278 X [tex]P_B[/tex]

1atm - 0.506atm =  0.278 X [tex]P_B[/tex]

0.494atm = 0.278 X [tex]P_B[/tex]

[tex]P_B[/tex] =  0.494atm / 0.278

[tex]P_B[/tex] = 1.77atm

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1. You have learned that alkyl iodides may be prepared by SN2 replacement of other leaving groups, or by treatment of alcohols or ethers with co centrated hydriodic acid (HI). A milder method for preparation of alkyl iodides from alcohols is shown below:

Answers

Imidazole's cyclic structure is aromatic and the lone pair present at the N₁ atom available for donation. hence, according to question N₁ is the most basic atom in the structure.

What is resonating structure?Two π bonds (between C₂-C₃ and N₁-C₅), as well as one lone pair on N₄, can interact with one another to generate a delocalized π system in the cyclic structure.This delocalization is intriguing since it has the same number of delocalized electrons as benzene—six.As a result, imidazole, like benzene, has a closed, delocalized ring with six π electrons. So, like benzene, it is regarded as an aromatic chemical with resonance stability.N₄ is neutral since it cannot be donated because it needs to use its lone pair to be aromatic.On the other hand, N₁ already forms a π connection, which helps the system become delocalized.N₁ is sp² hybridized and has a trigonal planar basic form. Its lone pair cannot communicate with the delocalized π system since it is pointed away from the cyclic structure.

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5.18 L of nitrogen gas at 76.0°C are cooled to 6.0°C at constant pressure. Calculate the new volume of
the gas.
(write your answer in this space with sig digs and units - submit your work in the work space provided)

Answers

Answer:

0.409 L

Explanation:

Because you are dealing with volume and temperature, you need to use the Charles' Law equation:

V₁ / T₁ = V₂ / T₂

In this equation, "V₁" and "T₁" represent the initial volume and temperature. "V₂" and "T₂" represent the final volume and temperature.

V₁ = 5.18 L                            V₂ = ? L

T₁ = 76.0 °C                          T₂ = 6.0 °C

V₁ / T₁ = V₂ / T₂                                           <----- Charles' Law equation

5.18 L / 76.0 °C = V₂ / 6.0 °C                     <----- Insert values

0.06815789 = V₂ / 6.0 °C                          <----- Simplify left side

0.409 L = V₂                                              <----- Multiply both sides by 6.0

What mass of oxygen reacts during the incomplete combustion of 18.0 g of propane?

Answers

Based on the mole ratio, the mass of oxygen reacting is 45.8 g.

What mass of oxygen reacts during the reaction?

The incomplete combustion of propane with oxygen produces carbon (ii) oxide and water.

The mole ratio of propane to oxygen according to the equation of the reaction is 2 : 7.

Molar mass of propane = 44 g/mol

Molar mass of oxygen = 32 g/mol

moles in 18.0 g = 18/44 mole

Mass of oxygen reacting = 18/44 * 7/2 * 32 = 45.8

In conclusion, incomplete combustion of propane produces carbon (ii) oxide.

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Name the following ether: OCH2CH3
A. ethyl benzyl ether
B. methyl phenyl ether
C. ethyl phenyl ether
D. ethyl propyl ether

Answers

The name of the given ether is ethyl benzyl ether .

What are ethers?

Ethers are organic compounds formed when nan oxygen atom is bonded to two alkyl or aryl groups.

Ethers usually have relatively high boiling points as a result of the central oxygen atom. An example of an ether, is ethyl propyl ether

The name of the given ether is ethyl benzyl ether as it has a benzyl and ethyl group attached to the oxygen atom.

In conclusion, ethers are characterized by an oxygen atom bonded to two alkyl or aryl groups.

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6) What is the pH of a solution with [H3O+] = 1 × 10-9 M?
A) 1.0 × 10-5
B) -9.0
C) 5.0
D) -5.0
E) 9.0

Answers

Answer:

E) 9.0

Explanation:

pH = -log [1×10^-9] = 9

The answer is E (9.0)

when gas evolution becomes very slow, heat the solution gently in the hood, then allow it to cool. What gas is formed in this reaction

Answers

Nitrogen gas is formed in this reaction.

Nitrogen gas

Atomic number 7 and the letter N designate nitrogen as the chemical element. Group 15 of the periodic table, often known as the pnictogens, contains nitrogen as the lightest nonmetal element. It ranks eighth in overall abundance in the Milky Way and the Solar System, making it a common element in the cosmos. Two of the element's atoms combine to create the colorless and odorless diatomic gas N2 at standard temperature and pressure. The most common element that isn't mixed, N2 makes up around 78 percent of the Earth's atmosphere. All living things contain nitrogen, which is mostly found in amino acids (and thus proteins), nucleic acids (DNA and RNA), and the energy-transfer molecule adenosine triphosphate.

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For what mechanistic reason does g1 of lactase first act as a brønsted acid during catalysis?.

Answers

Glucose becomes a better leaving group.

In a manner similar to how protonation of an alcohol makes it easier to substitute a -OH group, glucose becomes a better leaving group when the oxygen atom is protonated.

What is Bronsted acid-base theory?

A substance that releases or donates hydrogen ions during a chemical reaction is referred to as a Bronsted-Lowry acid. A Bronsted-Lowry base, on the other hand, takes hydrogen ions. Another way to look at it is that a base accepts protons whereas a Bronsted-Lowry acid donates them. Amphoteric species are those that, depending on the circumstance, can either give or take protons.

Every Bronsted-Lowry acid gives a species that is its conjugate base a proton in exchange for the species' support. Each base in the Bronsted-Lowry system similarly accepts a proton from its conjugate acid.

I understand the question you are looking for is this:

For what mechanistic reason does G1 of lactase first act as a Bronsted acid during catalysis?

A) G1 becomes a better nucleophile

B) G2 becomes a better nucleophile

C) Glucose becomes a better leaving group.

D) Galactose becomes a better leaving group.

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Describe the scale used to measure the basicity of a substance. Demonstrate how you could differentiate a weak base from a strong one. (10
points)

Answers

Answer:

The pH scale is used to measure the acidity or basicity of a substance.

Explanation:

pH stands for potential hydrogen. It ranges from 0 to 14, 7 being neutral. The pH of water is 7 i.e. it is neither acidic nor basic. 0 to 7 shows acidic behavior while 7 to 14 shows basic behavior.

Experiment:

Dip the pH paper in the liquid and wait for ten seconds. The pH strip starts to discolor.

For a strong acid the strip will turn red.

For a weak acid the strip will become pale red.

To find the correct pH value we can compare it with the indicator scale present on the pH scale box.

The scale used to measure the basicity of a substance is called the pH scale.

What is the pH scale?

The pH scale is a logarithmic scale that ranges from 0 to 14 and is used to determine the acidity or basicity of a solution. A pH value of 7 is considered neutral, values below 7 are acidic, and values above 7 are basic.

To differentiate a weak base from a strong one, you can perform the following experiments:

pH Measurement: Measure the pH of the solution containing the base using a pH meter or pH indicator paper. A strong base will have a higher pH value, typically around 12-14, indicating a highly basic solution. A weak base will have a lower pH value, closer to 7, indicating a less basic or slightly basic solution.

Conductivity Test: Dissolve a small amount of the base in water and measure its electrical conductivity using a conductivity meter. Strong bases are good electrolytes and will conduct electricity well, resulting in a high conductivity. Weak bases, on the other hand, are poor electrolytes and will exhibit lower conductivity.

Reaction with Acids: Add a few drops of a strong acid, such as hydrochloric acid (HCl), to a solution containing the base. Strong bases will rapidly and completely neutralize the acid, resulting in a significant increase in pH. Weak bases, however, will only partially neutralize the acid, leading to a smaller increase in pH.

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