The pure molecular substance with the lowest vapor pressure at 25°C is CH₃(CH₂)₃OH (1-pentanol).
The vapor pressure of a substance depends on the strength of its intermolecular forces. The stronger the intermolecular forces, the lower the vapor pressure. The intermolecular forces in a molecule depend on its size and shape, as well as the types of atoms and functional groups present.
Out of the given options, 1-pentanol (CH₃(CH₂)₃OH) has the largest molecular size and longest carbon chain, making it the most polar and having the strongest intermolecular forces of attraction.
Therefore, it has the lowest vapor pressure at 25°C compared to the other molecules. On the other hand, methanol (CH₃OH) has the smallest molecular size and the weakest intermolecular forces, making it the most volatile and having the highest vapor pressure at 25°C.
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7. Predict the structure of product obtained when cis-2-hexene is allowed to react with Zn/CHyl Draw Fischer projection formula(s) of the major product(s) of the reaction between Z-3methyl 3-hexene and cold, alkaline KMno4 I Briefly, but clearly, explain the following observation When 2-methylbutane reacts with Ch/hv, the monochlorinated products consist of four constitutional isomers in significant yields. However, when the same alkane is allowed to react with Br2/ hv, there is only one major monobromination product.
When cis-2-hexene reacts with Zn/CHyl, the product obtained is a trans-2-hexene. The reaction proceeds through a syn addition of hydrogen atoms from the Zn/CHyl reagent to the double bond of cis-2-hexene. The resulting intermediate is a trans-2-hexene, which is the major product of the reaction.
The Fischer projection formula of the trans-2-hexene is:
H H
| |
H--C--C--C--C--C--H
| |
H CH3
When Z-3-methyl-3-hexene reacts with cold, alkaline KMnO4, the major product obtained is 3-methyl-3-hexanone. The reaction proceeds via oxidative cleavage of the double bond, leading to the formation of two carbonyl groups. The resulting ketone is the major product of the reaction.
The Fischer projection formula of the 3-methyl-3-hexanone is:
O
||
H--C--C--C--C--C--O
| |
CH3 CH3
The observation that monochlorinated products of 2-methylbutane with Cl/hv consist of four constitutional isomers in significant yields, while the same alkane with Br2/hv results in only one major monobromination product, can be explained by the difference in the reactivity of Cl and Br radicals.
Cl radicals are less selective and more reactive than Br radicals. Therefore, when 2-methylbutane reacts with Cl/hv, multiple monochlorination products can be formed due to the random abstraction of H atoms by Cl radicals from different positions of the alkane. In contrast, Br radicals are more selective and less reactive.
Therefore, when 2-methylbutane reacts with Br2/hv, only one major monobromination product is formed due to the selective abstraction of H atoms from a specific position of the alkane, leading to the formation of a specific product.
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how many sigma and pi bonds are in 2-butyne (ch3c≡cch3)?
In 2-butyne (CH3C≡CCH3), there are a total of 3 sigma bonds and 2 pi bonds. Sigma bonds are formed by head-on overlap of atomic orbitals, while pi bonds are formed by side-by-side overlap of atomic orbitals.
The carbon-carbon triple bond in 2-butyne consists of one sigma bond and two pi bonds. This is because the triple bond consists of two parallel p orbitals that overlap sideways to form two pi bonds, and a sigma bond is formed between the carbon atoms by overlap of sp hybrid orbitals.
Each carbon atom in the triple bond is also bonded to two other atoms (hydrogen atoms in this case) through sigma bonds, which brings the total number of sigma bonds to 3.
In summary, 2-butyne has one sigma bond and two pi bonds in its carbon-carbon triple bond, and two sigma bonds in each carbon-hydrogen bond, giving a total of 3 sigma bonds and 2 pi bonds.
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In 2-butyne (CH3C≡CCH3), there are a total of 9 bonds. Among these, there are 3 sigma bonds and 2 pi bonds. The sigma bonds are between the carbon atoms and their respective hydrogen atoms, while the pi bonds are between the two carbon atoms in the triple bond.
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determine the nuclear binding energy in j/mol of an o-16 nucleus given the following data: mass of o-16 15.9905 amu mass of proton 1.00728 amu mass of neutron 1.008665 amu
The nuclear binding energy of an o-16 nucleus is approximately [tex]4.04 \times 10^{12[/tex] joules per mole.
The nuclear binding energy (BE) of a nucleus is the amount of energy required to break apart the nucleus into its constituent protons and neutrons. The BE can be calculated using the mass defect, which is the difference between the mass of the nucleus and the sum of the masses of its constituent particles.
The mass of an o-16 nucleus is given as 15.9905 atomic mass units (amu). The nucleus consists of eight protons and eight neutrons, with each proton having a mass of 1.00728 amu and each neutron having a mass of 1.008665 amu. Therefore, the total mass of the protons and neutrons in the o-16 nucleus is:
8 protons x 1.00728 amu/proton + 8 neutrons x 1.008665 amu/neutron = 15.99503 amu
The mass defect of the o-16 nucleus is:
15.99503 amu - 15.9905 amu = 0.00453 amu
The mass defect is related to the BE by Einstein's famous equation [tex]E = mc^2[/tex], where E is the energy, m is the mass defect, and c is the speed of light. To convert the mass defect from amu to kg, we use the conversion factor [tex]1.66054 \times 10^{-27[/tex] kg/amu. Thus, the mass defect of the o-16 nucleus is:
[tex]$0.00453 \text{ amu} \times 1.66054\times 10^{-27}\text{ kg/amu}=7.52\times 10^{-29}\text{ kg}$[/tex]
The energy equivalent of the mass defect is given by:
[tex]$E = (7.52 \times 10^{-29}\text{ kg}) \times (299792458\text{ m/s})^2 = 6.72\times 10^{-12}\text{ J}$[/tex]
To convert this energy into joules per mole, we need to multiply it by Avogadro's number ([tex]6.022 \times 10^{23[/tex]). Thus, the nuclear binding energy of the o-16 nucleus is:
[tex]$6.72\times 10^{-12}\text{ J} \times 6.022 \times 10^{23}=4.05\times 10^{12}\text{ J/mol}$[/tex]
= [tex]4.04 \times 10^{12[/tex] J/mol
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Standards Standard retention time of dichloromethane solvent: 2.31 min Standard retention time of toluene: 12.17 min Standard retention time of cyclohexene: 5.74 min. (0.25pts) Standard retention time of dichloromethane solvent (min) (0.25pts) Standard etention time of toluene (min) (0.25pts) Standard retention time of cyclohexane (min) .
The given information provides standard retention times for three compounds: dichloromethane solvent, toluene, and cyclohexene, which are used for identifying these compounds in gas chromatography analysis. The retention time is the time taken for a compound to travel through the chromatography column and reach the detector.
The standard retention time for dichloromethane solvent is 2.31 min, while the standard retention time for toluene is 12.17 min. The standard retention time for cyclohexene is 5.74 min.
These standard retention times can be used to identify these compounds in a gas chromatography (GC) analysis. In GC, the retention time is the time taken for a particular compound to travel through the chromatography column and reach the detector.
By comparing the retention times of unknown compounds with the standard retention times of known compounds, we can identify the unknown compounds. Therefore, the given standard retention times are important for the identification of these compounds in GC analysis.
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Refer to the reactions represented below; which are involved in a demonstration commonly known as 'underwater fireworks_ Reaction 1: CaCz(s) + 2 HzO() _ CzHzlg) + Ca(OH)z(s) Reaction 2: NaOCllaq) + 2 HCI(aq) ~ Clzlg) NaCl(aq) HzO() Reaction 3: CzHz(g) Clz(g) CzHzClz(g) When Reaction 3 occurs, does the hybridization of the carbon atoms change? Yes; it changes from sp to sp2 Yes; it changes from sp to sp3 No; it does not change: Yes; it changes from sp2 to sp
Yes; it changes from sp3 to sp2".The reactions represented above are not involved in a demonstration commonly known as 'underwater fireworks'.
Instead, they are related to the formation of different chemical compounds. In the first reaction, calcium carbide and water react to form acetylene gas and calcium hydroxide.
The second reaction involves the reaction between sodium hypochlorite and hydrochloric acid to produce chlorine gas, sodium chloride, and water.
The third reaction shows the formation of chloroform from methane and chlorine gas. When this reaction occurs, the hybridization of the carbon atoms changes from sp3 to sp2. "Yes; it changes from sp3 to sp2".
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What is an additional safety feature that could have helped to reduce the force felt by the drivers of both cars even more?
An additional safety feature that could have further reduced the force felt by drivers in both cars is the implementation of advanced crash mitigation systems utilizing predictive algorithms and automated braking technology.
One potential safety feature that could have provided further reduction in the force felt by drivers in both cars is the implementation of advanced crash mitigation systems. These systems employ predictive algorithms and automated braking technology to detect potential collisions and initiate braking or other corrective actions before impact.
By analyzing factors such as relative speed, distance, and trajectory, these systems can intervene rapidly to minimize the force of the collision. With such advanced technology in place, the safety systems can act autonomously, enabling quicker response times than human drivers, potentially reducing the severity of the impact and the resultant forces experienced by the occupants of the vehicles involved in the crash.
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how many unpaired electrons are there in the high-spin state of cr2 in an tetrahedral field?
In the high-spin state of Cr²⁺ in a tetrahedral field, there are 4 unpaired electrons.
Step-by-step explanation:
1. Determine the electron configuration of Cr²⁺: Chromium (Cr) has an atomic number of 24, so its ground-state electron configuration is [Ar] 3d⁵ 4s¹. When it loses 2 electrons to form Cr²⁺, the electron configuration becomes [Ar] 3d⁴.
2. Consider the tetrahedral field: In a tetrahedral field, the d-orbitals split into two energy levels: e (double-degenerate) and t2 (triple-degenerate). The e orbitals are lower in energy than the t2 orbitals.
3. Distribute the electrons in the high-spin state: In a high-spin state, electrons will fill the available orbitals with parallel spins before pairing up. In the case of Cr²⁺ with 4 d-electrons, two electrons will occupy the e orbitals, and the other two will occupy the t2 orbitals.
4. Count the unpaired electrons: Since all the electrons have parallel spins and occupy different orbitals in the high-spin state, there are 4 unpaired electrons in the Cr²⁺ ion within a tetrahedral field.
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the weak acid hz has a ka of 2.55 × 10−4. calculate the ph of 0.095 m hz.
pH of the solution = 1.82
pH is a measure of the acidity or basicity (alkalinity) of a solution. It is defined as the negative logarithm (base 10) of the concentration of hydrogen ions (H+) in a solution. The pH scale ranges from 0 to 14, with a pH of 7 being neutral. A pH less than 7 is acidic, while a pH greater than 7 is basic (alkaline).
To calculate the pH of 0.095 M HZ, we need to use the equation for the dissociation of a weak acid:
HZ ⇌ H+ + Z-
The equilibrium constant for this reaction is Ka = [H+][Z-]/[HZ], which can be simplified as:
Ka = [H+]^2 / [HZ]
Rearranging this equation, we get:
[H+] = sqrt(Ka * [HZ])
Substituting the values given in the question, we get:
[H+] = sqrt(2.55 × 10−4 * 0.095) = 0.015 M
Now, we can use the equation for pH:
pH = -log[H+]
Substituting the value of [H+], we get:
pH = -log(0.015) = 1.82
Therefore, the pH of 0.095 M HZ is 1.82.
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how many moles of benzoic acid, a monoprotic acid with ka = 6.4 × 10–5, must be dissolved in 500. ml of h2o to produce a solution with ph = 2.50?
Since 0.020 does not equal 1, this is not a valid solution. There may be an error in the given information or calculations. Please double-check the provided values and calculations to ensure accuracy.
How many moles of benzoic acid must be dissolved in 500 ml of H2O to produce a solution with a pH of 2.50?To determine the number of moles of benzoic acid required to produce a solution with a pH of 2.50, we can use the Henderson-Hasselbalch equation, which relates the pH of a solution to the pKa of the acid and the ratio of the concentrations of the acid and its conjugate base.
The Henderson-Hasselbalch equation is given by:
[tex]pH = pKa + log([A-]/[HA])[/tex]
In this case, benzoic acid (HA) is a monoprotic acid, so it will only form one conjugate base (A-). The pKa value given is [tex]6.4 × 10^–5[/tex].
First, let's determine the ratio of the concentration of the conjugate base to the concentration of the acid. Since the pH is 2.50, we can convert it to the hydrogen ion concentration ([H+]) by taking the antilog:
[H+] = [tex]10^(-pH)[/tex] = [tex]10^(-2.50)[/tex] = 0.00316 M
Next, we need to find the concentration of the acid ([HA]). We can assume that all of the benzoic acid dissociates into its conjugate base, so the concentration of the acid will be equal to the concentration of the conjugate base. Therefore, [HA] = [A-] = 0.00316 M.
Now we can substitute these values into the Henderson-Hasselbalch equation:
2.50 = -log[tex](6.4 × 10^(-5))[/tex] + log(0.00316/0.00316)Simplifying the equation gives:
2.50 = 4.20 + log(1)Taking the antilog of both sides:
[tex]10^(2.50 - 4.20)[/tex] = 1[tex]10^(-1.70)[/tex] = 10.020 = 1Learn more about ensure accuracy
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According to advertisements, "a diamond is forever."
(a) Calculate , and at 298k for the phase change Diamond graphite.
(b) Given the conditions under which diamond jewelry is normally kept, argue for and against the statement in the ad.
(c) Given the answers in part (a), what would need to be done to make synthetic diamonds from graphite?
(d) Assuming role="math" localid="1663313565397" and role="math" localid="1663313547943" do not change with temperature, can graphite be converted to diamond spontaneously at 1 atm?
However, the transformation rate is extremely slow, and it would take billions of years for a diamond to completely transform to graphite.
(a) The standard enthalpy change for the conversion of diamond to graphite can be calculated using the standard enthalpy of formation values for diamond and graphite:
ΔH° = H°(graphite) - H°(diamond)
ΔH° = 0 - 1.90 kJ/mol
ΔH° = -1.90 kJ/mol
The standard entropy change can be calculated using the molar entropies of diamond and graphite:
ΔS° = S°(graphite) - S°(diamond)
ΔS° = 5.74 J/(mol·K) - 2.40 J/(mol·K)
ΔS° = 3.34 J/(mol·K)
The standard Gibbs free energy change can be calculated using the equation:
ΔG° = ΔH° - TΔS°
At 298 K:
ΔG° = -1.90 kJ/mol - (298 K)(3.34 J/(mol·K))
ΔG° = -2.90 kJ/mol
(b) For diamond to be "forever" it would need to be chemically stable and not undergo any transformation under normal conditions. Diamond is a metastable form of carbon and can be converted to graphite over very long periods of time under normal conditions, especially with exposure to high temperatures and pressures.
(c) To make synthetic diamonds from graphite, high pressure and high temperature conditions are required to induce the conversion of graphite to diamond. The process is often carried out using a high-pressure apparatus that mimics the conditions found deep in the Earth's mantle, where diamonds are formed naturally.
(d) Graphite cannot be converted to diamond spontaneously at 1 atm and room temperature because the standard Gibbs free energy change for the conversion is negative (-2.90 kJ/mol), indicating a non-spontaneous process. High pressure and high temperature conditions are required to overcome the activation energy barrier for the transformation.
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predict the major product formed by 1,4-addition of hcl to 1,3-cycloheptadiene.
1,4-addition of HCl to 1,3-cycloheptadiene yields 1-chloro-2,3-dimethylcyclohexene as the major product.
1,3-cycloheptadiene is a conjugated diene that can undergo addition reactions with electrophilic reagents.
When 1,3-cycloheptadiene is treated with HCl, 1,4-addition occurs, meaning that the HCl adds to the 1 and 4 positions of the diene. The major product formed is 1-chloro-2,3-dimethylcyclohexene.
The mechanism of the reaction involves the formation of a cyclic carbocation intermediate, followed by attack of the chloride ion on the more substituted carbon, as it is more stabilized by the adjacent methyl groups. This leads to the formation of the major product, as shown below:
1,4-Addition of HCl to 1,3-Cycloheptadiene
The product is a substituted cyclohexene, with a chlorine atom at the 1 position and two methyl groups at the 2 and 3 positions. This reaction is an example of electrophilic addition to a conjugated diene, which is an important class of reactions in organic chemistry.
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The carbon nucleus has atomic number A =13. calculate the radius, mass and volume of the nucleus?
The radius, mass and volume of the nucleus are Radius ≈ 2.72 fm Mass ≈ 2.17 x 10^(-26) kg Volume ≈ 108.4 cubic femtometers (fm^3)
The atomic number (A) represents the number of protons in the nucleus of an atom. However, carbon usually has an atomic number of 6, not 13. Nonetheless, I'll provide calculations based on the given A = 13.
To calculate the radius of the nucleus, we can use the empirical formula:
Radius = r0 * A^(1/3)
Where r0 is a constant equal to approximately 1.2 femtometers (1.2 fm).
Radius = 1.2 fm * 13^(1/3)
Radius ≈ 2.72 fm
To calculate the mass of the nucleus, we need to consider the mass of individual protons and neutrons. The atomic number (A) represents the total number of protons and neutrons in the nucleus.
Mass = A * mass of one nucleon
The mass of one nucleon (proton or neutron) is approximately 1.67 x 10^(-27) kilograms.
Mass = 13 * (1.67 x 10^(-27) kg)
Mass ≈ 2.17 x 10^(-26) kg
To calculate the volume of the nucleus, we can use the formula for the volume of a sphere:
Volume = (4/3) * π * Radius^3
Volume = (4/3) * π * (2.72 fm)^3
Volume ≈ 108.4 cubic femtometers (fm^3)
Please note that the given value for the atomic number (A = 13) is unusual for carbon. Normally, carbon has an atomic number of 6.
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The chemical reaction that causes aluminum to corrode in air is given by: 4Al+3O2?2Al2O3, in which at 298 K deltaHrxn = -3352 kJ and deltaSrxn = -625.1 J/K.
1) What is the standard Gibbs free energy for this reaction? Assume the commonly used standard reference temperature of 298 K.
Express your answer as an integer and include the appropriate units.
2) What is the Gibbs free energy for this reaction at 5975 K ? Assume that ?H and ?S do not change with temperature.
Express your answer to two decimal places and include the appropriate units.
3) At what temperature Teq do the forward and reverse corrosion reactions occur in equilibrium?
Express your answer as an integer and include the appropriate units.
1. The standard Gibbs free energy change for the reaction is -3309 kJ/mol.
2. The Gibbs free energy change for the reaction at 5975 K is approximately -2621.24 kJ/mol.
3. There is no temperature at which the forward and reverse corrosion reactions occur in equilibrium.
1. The standard Gibbs free energy change for a reaction is given by the formula:
ΔG° = ΔH° - TΔS°
where ΔH° and ΔS° are the standard enthalpy and entropy changes, respectively, and T is the temperature in Kelvin.
Plugging in the given values, we get:
ΔG° = -3352 kJ/mol - (298 K)(-625.1 J/(mol·K))(1 kJ/1000 J) = -3309 kJ/mol
Therefore, the standard Gibbs free energy change for the reaction is -3309 kJ/mol.
2. To find the Gibbs free energy change at a higher temperature, we can use the formula:
ΔG = ΔH - TΔS
where ΔH and ΔS are the enthalpy and entropy changes, respectively, and T is the temperature in Kelvin.
We can assume that ΔH and ΔS do not change with temperature.
First, we need to convert the temperature to Kelvin:
5975°C + 273.15 = 6248.15 K
Plugging in the given values, we get:
ΔG = -3352 kJ/mol - (6248.15 K)(-625.1 J/(mol·K))(1 kJ/1000 J) ≈ -2621.24 kJ/mol
Therefore, the Gibbs free energy change for the reaction at 5975 K is approximately -2621.24 kJ/mol.
3. At equilibrium, the Gibbs free energy change is zero:
ΔG = 0 = ΔH - T_eqΔS
Solving for T_eq, we get:
T_eq = ΔH/ΔS
Plugging in the given values, we get:
T_eq = (-3352 kJ/mol)/(625.1 J/(mol·K)) ≈ -5361.98 K
This result is negative, which does not make physical sense. The negative sign indicates that the forward reaction is thermodynamically unfavorable and the reverse reaction is favorable at any temperature. Therefore, there is no temperature at which the forward and reverse corrosion reactions occur in equilibrium.
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how many σσ bonds can the two sets of 2p2p orbitals make with each other?
The two sets of 2p orbitals can form a maximum of two σ bonds with each other.
When two atoms come together to form a molecule, the electron orbitals of the atoms can overlap. When two s-orbitals overlap, they form a sigma bond. Similarly, when two p-orbitals overlap, they can form a sigma bond as well.
In the case of the 2p orbitals, each set of orbitals has two lobes, one along the x-axis and the other along the y-axis. When two sets of 2p orbitals come together, the lobes can overlap in two ways to form two sigma bonds. These sigma bonds are formed by the overlap of the lobes along the x-axis and the lobes along the y-axis.
It is important to note that these are sigma bonds and not pi bonds since pi bonds are formed when the orbitals overlap sideways. Therefore, two sets of 2p orbitals can form a maximum of two sigma bonds with each other.
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Hi! The two sets of 2p2p orbitals can form a maximum of 3 σ (sigma) bonds with each other. This occurs when each of the three 2p orbitals from one atom overlaps with a corresponding 2p orbital from the other atom, resulting in three sigma bonds between the atoms.
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Carbon monoxide and oxygen react to produce carbon dioxide. If 75.3L of carbon monoxide and 38.0L of oxygen are used, how many grams of carbon dioxide could be made? Which molecule is the limiting reactants? How much is left over
Approximately 148.59 grams of carbon dioxide could be made.The remaining reactant, since [tex]O_2[/tex]is the limiting reactant, all the CO will not be completely consumed. There would be no CO leftover as it is completely consumed in the reaction.
To determine the grams of carbon dioxide produced, we need to identify the limiting reactant first. The balanced chemical equation for the reaction is:
2 CO +[tex]O_2[/tex] -> 2 [tex]CO_2[/tex]
To find the limiting reactant, we compare the number of moles of each reactant and determine which one is present in a lower amount relative to the stoichiometry of the reaction.
First, we convert the given volumes of gases to moles using the ideal gas law equation:
n = PV / RT
where:
n = number of moles
P = pressure
V = volume
R = ideal gas constant
T = temperature
Assuming the reaction takes place at standard temperature and pressure (STP), which is 273.15 K and 1 atm, we can use the values to convert the volumes to moles:
For carbon monoxide (CO):
n(CO) = (75.3 L) / (22.414 L/mol) = 3.36 moles
For oxygen (O2):
n(O2) = (38.0 L) / (22.414 L/mol) = 1.69 moles
According to the balanced equation, the stoichiometry of the reaction is 2:1 for CO to [tex]O_2[/tex]This means that for every 2 moles of CO, we need 1 mole of [tex]O_2[/tex]. In this case, the ratio of moles is 3.36:1.69, which shows an excess of CO.
To find the limiting reactant, we compare the mole ratio to the stoichiometry ratio. Since there is a surplus of CO, it is the excess reactant, and[tex]O_2[/tex]is the limiting reactant.
To determine the amount of carbon dioxide produced, we use the stoichiometry of the reaction. From the balanced equation, we know that for every 2 moles of CO, 2 moles of CO2 are produced.
Since[tex]O_2[/tex] is the limiting reactant, we use its moles to calculate the moles of [tex]Co_2[/tex]produced:
n([tex]CO_2[/tex]) = 2 * n([tex]O_2[/tex]) = 2 * 1.69 moles = 3.38 moles
Finally, we convert the moles of[tex]CO_2[/tex] to grams using the molar mass of carbon dioxide, which is 44.01 g/mol:
mass([tex]CO_2[/tex]) = n([tex]CO_2[/tex]) * molar mass([tex]CO_2[/tex] = 3.38 moles * 44.01 g/mol ≈ 148.59 grams
Therefore, approximately 148.59 grams of carbon dioxide could be made.
As for the remaining reactant, since [tex]O_2[/tex]s the limiting reactant, all the CO will not be completely consumed. To determine the amount of CO leftover, we subtract the moles of CO used from the initial moles of CO:
Remaining moles of CO = Initial moles of CO - Moles of CO used
Remaining moles of CO = 3.36 moles - 2 * 1.69 moles ≈ 0 moles
Thus, there would be no CO leftover as it is completely consumed in the reaction.
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if the combustion of 59.10 g of c4h10 produces 99.71 g of co2. what is the percent yield of the reaction? (assume oxygen is in excess.)
The percent yield of the combustion reaction is 55.70%.
To calculate the percent yield of the reaction, you'll first need to determine the theoretical yield and then compare it to the actual yield.
1. Calculate the molar mass of C₄H₁₀ (butane) and CO₂:
C₄H₁₀: (4 x 12.01) + (10 x 1.01) = 58.12 g/mol
CO₂: (1 x 12.01) + (2 x 16.00) = 44.01 g/mol
2. Calculate the moles of C₄H₁₀:
59.10 g C₄H₁₀ * (1 mol C₄H₁₀ / 58.12 g) = 1.017 mol C₄H₁₀
3. Use the balanced equation to determine the moles of CO₂ produced theoretically:
C₄H₁₀ + 13/2 O₂ -> 4 CO₂ + 5 H₂O
1.017 mol C₄H₁₀ * (4 mol CO₂ / 1 mol C₄H₁₀) = 4.068 mol CO₂
4. Calculate the theoretical yield of CO₂:
4.068 mol CO₂ * (44.01 g / 1 mol CO₂) = 179.03 g CO₂
5. Determine the percent yield:
Percent yield = (Actual yield / Theoretical yield) x 100
Percent yield = (99.71 g CO₂ / 179.03 g CO₂) x 100 = 55.70%
So, the percent yield of the reaction is 55.70%.
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A solution is made by dissolving 22 grams of sodium hydroxide in water. The sodium
hydroxide solution is then titrated against an unknown solution of oxalic acid. If it takes
14.9 mL of the acid to reach the end point, what is the concentration of the oxalic acid?
NaOH + H₂C₂O → H₂O + Na₂C₂O₁
To find the concentration of the unknown oxalic acid solution, we need to use the balanced chemical equation for the reaction:NaOH + H₂C₂O → H₂O + Na₂C₂O₁
From the equation, we can see that the mole ratio between sodium hydroxide (NaOH) and oxalic acid (H₂C₂O) is 1:1. First, we need to determine the number of moles of NaOH used in the titration. The molar mass of NaOH is 22.99 + 16.00 + 1.01 = 40.00 g/mol. Therefore, the number of moles of NaOH is:moles of NaOH = mass of NaOH / molar mass of NaOH
= 22 g / 40 g/mol
= 0.55 mol
Since the mole ratio between NaOH and H₂C₂O is 1:1, the number of moles of H₂C₂O is also 0.55 mol.Now, we can determine the concentration of the oxalic acid solution using the volume of the acid used in the titration. The volume is given as 14.9 mL, which is equivalent to 0.0149 L. concentration of oxalic acid (C) = moles of H₂C₂O / volume of H₂C₂O
= 0.55 mol / 0.0149 L
≈ 36.91 mol/L.Therefore, the concentration of the unknown oxalic acid solution is approximately 36.91 mol/L.
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in sih4, could d orbitals be used to form the bonds? if so, which d orbitals?
In SiH4, the bonding occurs through the overlap of the hybridized orbitals of silicon and the 1s orbitals of hydrogen. The hybridization of the silicon atom in SiH4 is sp3, meaning that it has four hybrid orbitals. These hybrid orbitals are formed by the mixing of one 3s and three 3p orbitals of silicon.
The d orbitals of silicon are not involved in the bonding in SiH4. This is because the energy of the d orbitals is higher than that of the hybridized orbitals, and thus, they are not available for bonding. Additionally, the size of the silicon atom is such that the 3s and 3p orbitals are the ones that best overlap with the hydrogen 1s orbitals to form the sigma bonds.
In summary, the bonding in SiH4 occurs through the hybridization of the 3s and 3p orbitals of silicon, which form four sp3 hybrid orbitals. The d orbitals are not involved in bonding because their energy is higher than that of the hybridized orbitals.
In SiH4, the central atom is silicon, which is in the third period of the periodic table. Silicon has an electron configuration of [Ne] 3s² 3p², meaning it has access to the 3s and 3p orbitals for bonding. SiH4 forms four single bonds with hydrogen atoms in a tetrahedral structure. These bonds involve the overlap of silicon's 3s and 3p orbitals with the 1s orbitals of the hydrogen atoms.
D orbitals are not involved in the bonding of SiH4. Silicon does have empty 3d orbitals, but they do not participate in bonding as the energy difference between 3d and 3s/3p orbitals is significant. The 3s and 3p orbitals of silicon are sufficient to accommodate the four bonding electron pairs with hydrogen atoms, making the use of d orbitals unnecessary in SiH4.
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A student obtains the following data:
mass of evaporating dish 25.87 g
mass of dish with mixture sample 28.4 g
mass of beaker 146.36 g
mass of beaker with dried salt 147.10 g
mass of evaporating dish with dried sand ???
however, this student spills her sand sample out of the evaporating dish before weighing it. if the student believes in the law of conservation of mass, what should have been the mass, in grams, of the evaporating dish with the sand in it?
The mass, in grams, of the evaporating dish with the sand in it should be 123.02 g. According to the law of conservation of mass, if the student spills her sand sample out of the evaporating dish before weighing it, the mass of the evaporating dish with the sand in it should still be the same as before the spillage.
Let the mass of the evaporating dish with dried sand be "x" g.
The mass of the mixture of sample and evaporating dish = 28.4 g
The mass of the evaporating dish = 25.87 g
Therefore, the mass of the sample = (28.4 - 25.87) g = 2.53 g
The mass of the beaker with the dried salt = 147.10 g
The mass of the beaker = 146.36 g
Therefore, the mass of the dried salt = (147.10 - 146.36) g = 0.74 g
Now, the mass of the evaporating dish with dried sand is equal to:
Mass of beaker + mass of the mixture - Mass of the beaker with dried salt - Mass of evaporating dishMass of the evaporating dish with dried sand = 147.10 g + 2.53 g - 0.74 g - 25.87 g = 123.02 g
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Modern drug discovery often starts with a large library of compounds. These library studies are important because a. Select one: cancerous tissue is much more difficult to target than foreign invaders. b. the search will definitely yield a new candidate drug. c. the search may yield a number of possible framework pieces to build into a good drug. d. old drugs will never be effective against new targets.
The answer to the question is c. The library studies may yield a number of possible framework pieces to build into a good drug.
Modern drug discovery is a complex and time-consuming process that involves screening large libraries of compounds to identify potential candidates for further development. While the ultimate goal is to find a new drug that is effective against a specific disease or condition, it is often the case that the initial screening process yields multiple compounds that may be useful in developing a new drug.
This process is essential for addressing evolving health challenges and improving therapeutic options. While not every search guarantees a new candidate drug, the possibility of finding multiple framework pieces makes these studies valuable in drug discovery.
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Determine the partial pressure and number of moles of each gas in a 16. 75L vessel at 30 degree C containing a mixture of xenon and neon gases only. The total pressure in the vessel is 7. 10 atm, and the mole fraction of xenon is 0. 721.
What is the partial pressure of xenon?
What is the partial pressure of neon?
What is the number of moles of xenon?
What is the number of moles of neon?
The partial pressure of xenon is 5.103 atm and neon is 1.997 atm. The number of moles of xenon is 4.883 moles and neon is 1.012 moles.
We can calculate the partial pressure of xenon using its mole fraction:
Total pressure P(total) = 7.10 atm
Volume (V) = 16.75 L
Temperature (T) = 30 °C = 273.15 + 30 = 303.15 K
Mole fraction of xenon (Xe) = 0.721
P(xe) = Xe × P(total)
= 0.721 × 7.10 atm
= 5.103 atm
Next, we can calculate the partial pressure of neon:
P(ne) = (1 - Xe) × P(total)
= (1 - 0.721) × 7.10 atm
= 1.997 atm
PV = nRT.
For xenon:
n(xe) = (P(xe) × V) / (R × T)
(5.103 atm * 16.75 L) / (0.0821 L·atm/(mol·K) × 303.15 K)
= 4.883 moles
For neon:
n_ne = (P(ne) × V) / (R × T)
= (1.997 atm × 16.75 L) ÷ (0.0821 L·atm/(mol·K) × 303.15 K)
= 1.012 moles.
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Match the magnitude of the equilibrium constant Kc with the correct description of the reaction system.
small Kc =
intermediate Kc =
large Kc =
The magnitude of the equilibrium constant Kc determines the direction and extent of a reaction.
How does the magnitude of Kc affect the direction and extent of a reaction?The equilibrium constant, denoted as Kc, is a numerical value that relates the concentrations of reactants and products at equilibrium in a chemical reaction. It is calculated using the concentrations of the species involved in the reaction. The magnitude of Kc indicates the relative abundance of products compared to reactants at equilibrium.
A small Kc value indicates that the concentration of products is low compared to reactants, suggesting that the reaction system predominantly favors the reactants. This means that the reaction proceeds more in the backward direction.
Conversely, a large Kc value suggests that the concentration of products is high compared to reactants, indicating that the reaction system predominantly favors the products. This implies that the reaction proceeds more in the forward direction.
An intermediate Kc value indicates that the reaction system is balanced, with comparable concentrations of products and reactants. This suggests that the reaction is proceeding in both the forward and backward directions to a significant extent.
the magnitude of Kc provides important information about the direction and extent of a reaction. It helps determine whether a reaction predominantly favors the reactants, products, or is in a balanced state at equilibrium.
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Calculate the specific heat ( in joules/ g. °C) if 2927 joules requiresd to raise the temperature of 55.9 grams of unknown metal from 27 °C to 95 Oc. Heat = mass XS.HXAT 0.42 0.077 O 0.77 0.39
The specific heat of the unknown metal is 0.42 J/g.°C, calculated by dividing the heat (2927 J) by the mass (55.9 g) and the temperature change.
How to calculate specific heat of unknown metal?To calculate the specific heat of the unknown metal, we can use the formula:
q = m * c * ∆T
where q is the amount of heat transferred, m is the mass of the metal, c is the specific heat of the metal, and ∆T is the change in temperature.
We are given that:
q = 2927 J
m = 55.9 g
∆T = 95°C - 27°C = 68°C
Substituting these values into the formula, we get:
2927 J = (55.9 g) * c * 68°C
Simplifying:
c = 2927 J / (55.9 g * 68°C)
c = 0.420 J/(g·°C)
Therefore, the specific heat of the unknown metal is 0.420 joules per gram per degree Celsius (J/g·°C).
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The ph of a 0.77m solution of 4-pyridinecarboxylic acid hc6h4no2 is measured to be 2.54. Calculate the acid dissociation constant Ka of 4-pyridinecarboxlic acid. Round your answer to 2 significant digits
The acid dissociation constant (Ka) of 4-pyridinecarboxylic acid is approximately 3.1, rounded to 2 significant digits.
To calculate the acid dissociation constant (Ka) of 4-pyridinecarboxylic acid (HC₆H₄NO₂), we can use the pH value and the concentration of the acid.
The pH of a solution is related to the concentration of hydronium ions (H₃O⁺) in the solution. In this case, the pH of the solution is given as 2.54, indicating the concentration of H₃O⁺ ions.
To find the concentration of H₃O⁺ ions, we need to convert the pH to a molar concentration of H₃O⁺ using the formula:
[H₃O⁺] = [tex]10^(^-^p^H^)[/tex]
[H₃O⁺] = [tex]10^(^-^2^.^5^4^)[/tex]
Now, since the acid is a monoprotic acid and fully dissociates, the concentration of the acid (HC₆H₄NO₂) is equal to the concentration of H₃O⁺ ions.
Therefore, the concentration of the acid is 10^(-2.54) M.
The general equation for the dissociation of a weak acid, HA, is:
HA ⇌ H⁺ + A⁻
Where HA represents the acid, H⁺ represents the hydronium ion, and A⁻ represents the conjugate base.
The acid dissociation constant (Ka) is given by the expression:
Ka = [H⁺] * [A⁻] / [HA]
Since the concentration of the acid is equal to the concentration of H⁺, and assuming complete dissociation, the equation simplifies to:
Ka = [H⁺]² / [HA]
Ka = ([H₃O⁺]²) / [HC₆H₄NO₂]
Ka = [tex](10^(^-^2^.^5^4^))^2[/tex] / 0.77
Ka = [tex]10^(^-^2^.^5^4^*^2^)[/tex] / 0.77
Ka ≈ 2.4 / 0.77
Ka ≈ 3.1
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What is the strongest base, among the following? ClO^- ClO_2^- ClO_3^- ClO_4^- What is the weakest acid, among the following? HOI HOBr HOCl all are equivalent
Among the given options, (a) ClO⁻ is the strongest base and (a) HOI is the weakest acid.
As we move from left to right in the list, the negative charge on the oxygen atom increases, resulting in a greater ability to accept a proton. Therefore, ClO⁻ (hypochlorite ion) has the weakest negative charge and is the strongest base among the given options.
The weaker the acid, the stronger its conjugate base, so the weakest acid among the given options is HOI. This is because Iodine (I) is more electronegative than bromine (Br) and chlorine (Cl), which makes it more stable and less likely to donate a proton.
This results in HOI having a lower tendency to donate a proton and therefore being the weakest acid among the options. Additionally, the size of the iodine atom also contributes to the weaker acidic nature of HOI, as larger atoms tend to be less acidic due to the increased distance between the proton and the electronegative atom.
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Complete the table below. some binary molecular compounds name chemical formula tetraphosphorus heptasulfide phosphorus pentachloride tetraphosphorus trisulfide phosphorus trichloride
To complete the table with the binary molecular compounds, we need to provide their respective chemical formulas and names.
Starting with tetraphosphorus heptasulfide, the chemical formula is P4S7 and the name is tetraphosphorus heptasulfide. For phosphorus pentachloride, the chemical formula is PCl5 and the name is phosphorus pentachloride. Moving on to tetraphosphorus trisulfide, the chemical formula is P4S3 and the name is tetraphosphorus trisulfide. Lastly, for phosphorus trichloride, the chemical formula is PCl3 and the name is phosphorus trichloride.
It's important to note that binary molecular compounds are made up of nonmetallic elements, which is why they are named using prefixes to indicate the number of each element present. When writing the chemical formulas, we use the subscripts to represent the number of each element present in the compound.
In conclusion, the table below shows the binary molecular compounds with their respective chemical formulas and names.
| Compound Name | Chemical Formula |
|---------------|-----------------|
| Tetraphosphorus heptasulfide | P4S7 |
| Phosphorus pentachloride | PCl5 |
| Tetraphosphorus trisulfide | P4S3 |
| Phosphorus trichloride | PCl3 |
I hope this detailed answer gives you a clear understanding of the binary molecular compounds listed in the table.
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Which period 3 element has successive first through seventh ionization energies (kJ/mol) : Ei1 = 578; Ei2 = 1,817; Ei3 = 2,745; Ei4 = 11,575; Ei5 = 14,830; Ei6 = 18,376; and Ei7 = 23,293? A) Mg B) Cl C) S D) Al
To determine the element that has the given successive first through seventh ionization energies, let's analyze the provided values.
The ionization energy refers to the amount of energy required to remove an electron from an atom or ion. In general, as electrons are successively removed, the ionization energy tends to increase.
Looking at the given values:
Ei1 = 578 kJ/mol
Ei2 = 1,817 kJ/mol
Ei3 = 2,745 kJ/mol
Ei4 = 11,575 kJ/mol
Ei5 = 14,830 kJ/mol
Ei6 = 18,376 kJ/mol
Ei7 = 23,293 kJ/mol
We observe that there is a significant increase in ionization energy from the first to the second ionization (Ei1 to Ei2). This suggests that the first electron is relatively easily removed, likely indicating that the element is a metal.
Further, the subsequent ionization energies increase gradually but not dramatically. This indicates that it is becoming progressively more difficult to remove additional electrons.
Based on these observations, the element that matches this pattern is aluminum (Al), which is the correct answer choice D. Aluminum is a metal found in period 3 of the periodic table, and its ionization energies align with the given values.
Mg (answer choice A) is not the correct answer because its ionization energies are significantly lower and increase more gradually. Cl (answer choice B) and S (answer choice C) are nonmetals, and their ionization energies generally increase more dramatically.
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2NaOH + H2SO4 ——> 2 H2O + Na2SO4
How many grams of H2O is produced from a reaction that uses 6 moles of NaOH?
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The reaction of 6 moles of NaOH would produce approximately 216 grams of H2O.
The balanced chemical equation for the reaction between NaOH and H2SO4 is:
2NaOH + H2SO4 -> 2H2O + Na2SO4
From the equation, we can see that 2 moles of NaOH react to produce 2 moles of H2O.
To calculate the grams of H2O produced, we need to know the molar mass of H2O, which is approximately 18.015 g/mol.
Since 2 moles of NaOH react to produce 2 moles of H2O, we can set up the following proportion:
2 moles of NaOH / 2 moles of H2O = 6 moles of NaOH / x grams of H2O
Cross-multiplying and solving for x, we have:
(2 moles of H2O * 6 moles of NaOH) / 2 moles of NaOH = x grams of H2O
(12 moles of H2O) / 2 = x grams of H2O
6 moles of H2O = x grams of H2O
Since 1 mole of H2O is approximately 18.015 g, we can calculate the grams of H2O:
6 moles of H2O * 18.015 g/mole ≈ 108.09 g
Therefore, approximately 108.09 grams of H2O is produced from a reaction that uses 6 moles of NaOH.
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The industry demand is Q = 1000 – 40P. The monopolist cost function is C = 0.2Q2 + 10Q + 150. At the equilibrium, what is the consumers’ surplus?
The industry demand is Q = 100 – 2P. The monopolist cost function is C = 0.01Q2 + Q + 100. What is the monopolist’s equilibrium price?
The industry demand is Q = 200 – 5P. The monopolist cost function is C = 0.8Q2 + 30Q + 200. What is the monopolist’s equilibrium quantity of production?
The industry demand is Q = 200 – 5P. The monopolist cost function is C = 0.8Q2 + 30Q + 200. What is the monopolist’s equilibrium price?
The industry demand is Q = 100 – 2P. The monopolist cost function is C = 0.01Q2 + Q + 100. What is the monopolist’s equilibrium quantity of production?
The industry demand is Q = 100 – 2P. The monopolist cost function is C = 0.01Q2 + Q + 100. At the equilibrium, what is the firm’s profit?
The industry demand is Q = 1200 – 10P. The monopolist cost function is C = 0.5Q2 + 5Q + 1200. What is the monopolist’s equilibrium price?
The industry demand is Q = 200 – 5P. The monopolist cost function is C = 0.8Q2 + 30Q + 200. At the equilibrium, what is the consumers’ surplus?
Consumers' surplus is $19,600, equilibrium price is $22, equilibrium quantity is 58.125, equilibrium price is $28.75, equilibrium quantity is 56, Firm's profit at equilibrium is 312.5 - 2.25P². The monopolist's equilibrium price and quantity of production is $3312.50. The consumer surplus at equilibrium is $4875.
Consumers' surplus at equilibrium
Industry demand: Q = 1000 - 40P
Monopolist cost function: C = 0.2Q^2 + 10Q + 150
Equilibrium:
Q = 1000 - 40P = 0.2Q² + 10Q + 150
Solving for Q and P, we get Q = 140, P = 15
At this equilibrium, consumers' surplus = 1/2 * (1000-140) * (1000-2*15) = $19,600
Monopolist's equilibrium price
Industry demand: Q = 100 - 2P
Monopolist cost function: C = 0.01Q² + Q + 100
Profit-maximizing output level: MR = MC
MR = d(TR)/dQ = d(P*Q)/dQ = P
MC = d(C)/dQ = 0.02Q + 1
P = MC
100 - 2P = 0.02Q + 1
Substituting Q = 50 - P/2, we get P = $22
Monopolist's equilibrium quantity
Industry demand: Q = 200 - 5P
Monopolist cost function: C = 0.8Q^2 + 30Q + 200
Profit-maximizing output level: MR = MC
MR = d(TR)/dQ = d(P*Q)/dQ = P
MC = d(C)/dQ = 1.6Q + 30
P = MC
200 - 5P = 1.6Q + 30
Substituting Q = (200-5P)/1.6, we get Q = 58.125
Monopolist's equilibrium price
Using the same demand and cost functions as in (3), we can substitute the equilibrium quantity Q = 58.125 into the demand equation to solve for P:
Q = 200 - 5P
58.125 = 200 - 5P
P = $28.75
Monopolist's equilibrium quantity
Using the same demand and cost functions as in (2), we can substitute the equilibrium price P = $22 into the demand equation to solve for Q:
Q = 100 - 2P
Q = 100 - 2($22)
Q = 56
Firm's profit at equilibrium
Industry demand: Q = 100 - 2P
Monopolist cost function: C = 0.01Q² + Q + 100
Profit = TR - TC
TR = P*Q = (100-2P)*Q
TC = C = 0.01Q² + Q + 100
Profit = (100-2P)*Q - (0.01Q² + Q + 100)
Substituting Q = 50 - P/2, we get Profit = 312.5 - 2.25P²
To find the firm's profit, we need to subtract the total cost (C) from the total revenue (TR). The total revenue is simply the price (P) times the quantity (Q), which we found to be 50 units.
TR = P x Q = $95 x 50 = $4750
Total cost (C) can be found by plugging in the equilibrium quantity (Q=25) into the cost function
C = 0.5(25)² + 5(25) + 1200 = $1437.50
So the firm's profit is
Profit = TR - C = $4750 - $1437.50 = $3312.50
Therefore, the firm's profit at the equilibrium price and quantity is $3312.50.
To find the consumer surplus, we need to find the area between the demand curve and the equilibrium price (P=95). We can break the area into a triangle and a rectangle.
The height of the triangle is the difference between the equilibrium price (P=95) and the y-intercept of the demand curve (which is 100). So, the height is
Height = 100 - 95 = 5
The base of the triangle is the equilibrium quantity (Q=50). So, the area of the triangle is
Area of triangle = 1/2 x base x height = 1/2 x 50 x 5 = $125
The area of the rectangle is the difference between the equilibrium quantity (Q=50) and the quantity at which the demand curve intersects the y-axis (which is 100). So, the width of the rectangle is
Width = 100 - 50 = 50
The height of the rectangle is the equilibrium price (P=95). So, the area of the rectangle is
Area of rectangle = width x height = 50 x 95 = $4750
Therefore, the total consumer surplus is the sum of the areas of the triangle and rectangle
Consumer surplus = Area of triangle + Area of rectangle = $125 + $4750 = $4875
Therefore, the consumer surplus at the equilibrium price and quantity is $4875.
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A solution is made by dissolving 45.5 g of Ba(NO₂)₂ in 500.0 mL of water. Using Kb(NO₂⁻) = 2.2 × 10⁻¹¹, determine the pH of the solution.
The pH of the solution is approximately 8.74.
Ba(NO₂)₂ dissociates in water to produce Ba²⁺ and 2 NO₂⁻ ions. The NO₂⁻ ion can act as a weak base and undergo hydrolysis to produce OH⁻ ions:
NO₂⁻ + H₂O ⇌ HNO₂ + OH⁻
The equilibrium constant for this reaction is given by Kb(NO₂⁻) = [HNO₂][OH⁻] / [NO₂⁻]. We are given the mass of Ba(NO₂)₂ and the volume of water, so we can calculate the molarity of the solution: moles of Ba(NO₂)₂ = 45.5 g / 167.327 g/mol = 0.272 mol
Molarity = 0.272 mol / 0.500 L = 0.544 M
Since each Ba(NO₂)₂ molecule produces 2 NO₂⁻ ions, the initial concentration of NO₂⁻ is twice the molarity of Ba(NO₂)₂:
[NO₂⁻]i = 2 * 0.544 M = 1.088 M
At equilibrium, some of the NO₂⁻ ions will have reacted with water to form HNO₂ and OH⁻ ions. Let x be the concentration of OH⁻ ions produced by the hydrolysis of NO₂⁻. Then the concentration of HNO₂ is also x, and the concentration of NO₂⁻ remaining is [NO₂⁻]i - x.
The equilibrium constant expression for the hydrolysis reaction can be written as: Kb = [HNO₂][OH⁻] / [NO₂⁻] = x² / ([NO₂⁻]i - x)
Substituting the given values, we get: 2.2 × 10⁻¹¹ = x² / (1.088 - x). Solving for x using the quadratic formula, we get: x = 5.45 × 10⁻⁶ M
The concentration of OH⁻ ions is 5.45 × 10⁻⁶ M, so the pOH of the solution is: pOH = -log(5.45 × 10⁻⁶) = 5.26. Since pH + pOH = 14, the pH of the solution is: pH = 14 - pOH = 8.74
Therefore, the pH of the solution is approximately 8.74.
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