What is the mole fraction of C2H6O2 in 12. 7 molal aqueous solution ?

Answers

Answer 1

The mole fraction of C₂H₆O₂ in 12. 7 molal aqueous solution is 12.7.

What is mole fraction?

In chemistry, a mole fraction is the ratio of the moles of one component in a solution or other mixture to the sum of the moles of all the components.

The ratio of the moles of any component to the sum of the moles of all the other components in the mixture is known as the mole fraction. Each gas's partial pressure in a mixture of gases is calculated by multiplying its mole fraction by its total pressure.

The number of solute molecules divided by the sum of the solute molecules and the solvent molecules is known as the mole fraction. This is equal to how many moles of solute there are in a liter of solvent, expressed in molal. If the molal equivalent C₂H₆O₂ is 12.7 this means, all that is in the solution is solute. Hence the mole fraction of C₂H₆O₂ is 12.7.

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Related Questions

In the equation 2K(s) + 2H2O(l) → 2K(OH)(aq) + H2(g), identify the physical state of each reactant and product

Answers

K can be found in solid form. Water exists as a liquid. KOH can be found in aqueous form. Hydrogen exists as a gas.

What is reactant and product?

Reactants are chemical compounds that engage in chemical reactions, resulting in the formation of new chemicals known as products. Products are the new compounds created as a result of the chemical reaction between reactants.

Reactant- The substances which participate in a chemical reaction, are called reactants. A chemical reaction describes the process by which atoms, the fundamental building blocks of matter, rearrange themselves to form new combinations. Reactants are raw materials that react with one another.

Product- A product is a substance that is present at the end of a chemical reaction. In the equation above, the zinc and sulfur are the reactants that chemically combine to form the zinc sulfide product.

Here,

K=solid

H₂O=liquid

KOH=aqueous

H₂=gas

K exist in solid form. H₂O exist in liquid form. KOH exist in aqueous form. H₂ exist in gas form.

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A 70g chunk of metal at 180C was dropped in a bucket containing 400g of water at 25C. The final temperature of the mixture was 28C. What is the specific heat capacity of the metal

Answers

Thus, the metal has a mhm specific heat capacity of 2.472 Joel program degrees Celsius.

To calculate the temperature change (T), subtract the end temperature from the initial temperature. Multiply the temperature change by the sample's mass. Share the product's energy and heat output. The equation is C = Q / (T m). The amount of heat energy per unit mass needed to raise the temperature by one degree Celsius is known as the specific heat. The form given below, where c is the specific heat, is typically used to express the relationship between heat and temperature change. Let S represent the water's specific heat capacity. Consequently, the combined temperature of 50g of water at 20°C and 50g of water.

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Use atomic masses to demonstrate that the balance equation for the formation of iron(III) chloride obeys the law of conservation of mass. Fe + Cl2 → FeCl3

Answers

Using the law of the conservation of mass, the reactions can be shown to obey the law.

What is the  law of conservation of mass?

We need to know what the law of the conservation of mass says so that we can be able to know how we can be able to apply the law in the proper perspective. We have to know that the law says that total mass of the system would remain constant. The implication of this is that the mass before the reaction would be the same as the mass after the reaction. The mass of the substance must be able to add up in the system that is under study as we have one here.

Mass of the iron = 56 g

Mass of the chlorine = 35.5 g

Balanced reaction equation;

[tex]2Fe + 3Cl_{2} ---- > 2FeCl_{3}[/tex]

This is the  formation of the iron III chloride

Total mass on the right hand side = 2(56) + 6(35.5) = 325 g

Total mass on the left hand side = 2[56 + 3(35.5)] = 325 g

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Liquid hexane CH3CH24CH3 will react with gaseous oxygen O2 to produce gaseous carbon dioxide CO2 and gaseous water H2O. Suppose 7.76 g of hexane is mixed with 34. g of oxygen. Calculate the minimum mass of hexane that could be left over by the chemical reaction. Round your answer to 2 significant digits.

Answers

the minimum mass of hexane that could be left over by the chemical reaction is 17.2 grams of.

Hexane, a non-polar solvent having a boiling point of 68 degrees Celsius, is the one used to extract the oil from rice bran to produce rice bran oil (RBO). The International System of Units uses the mole (symbol: mol) as the unit of material quantity. How many elementary entities of a particular substance are present in an object or sample is determined by the quantity of that material.

Hexane moles equal 29/86=0.34

41.3/32 = 1.30 moles of oxygen

One mole of hexane takes 9.5 moles of oxygen, as shown by the reaction.

In this case, oxygen is the limiting reagent.

Consumption of moles of hexane is 1.30/9=0.144

Hexane remaining in moles is equal to 0.20 to 0.34 moles.

Hexane mass remaining = 0.2*86=17.2 grams.

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6.
In Period 2, as the elements are considered from
left to right, there is a decrease in
BO
A.
ionization energy
B.
atomic masS
C.
metallic
character
D. nonmetallic character

Answers

The correct answer is Metallic character.

Please give brainliest I need one more!!!!!!!!!!!!

Do help me become a detective, would it matter if I chose triple science or not?

Answers

Answer:

no

Explanation:

Two liquids whose boiling points differ considerably can be separated from their mixture by​

Answers

Answer:

heating the mixture until one liqiid remains

Explanation:

This is because the liquids have different boiling points there fore meaning that one liquid will evaporate begore the other

heating the mixture until one liquid is left

N2 + 3H2 → 2NH3

How many moles of hydrogen, H2, are needed to react with 28 moles of nitrogen, N2?

(round the the tenth's place)

Answers

Taking into account the reaction stoichiometry, an amount of 84 moles of H₂ are needed to react with 28 moles of nitrogen.

Reaction stoichiometry

In first place, the balanced reaction is:

N₂ + 3 H₂  → 2 NH₃

By reaction stoichiometry, the following amounts of moles of each compound participate in the reaction:

N₂: 1 moleH₂: 3 molesNH₃: 2 moles

Mass of N₂ required

It can be applied the rule of three: If by reaction stoichiometry 1 mole of N₂ react with 3 moles of H₂, 28 moles of N₂ react with how many moles of H₂?

moles of H₂= (28 moles of N₂×3 moles of H₂)÷1 mole of N₂

moles of H₂= 84 moles

Finally, 84 moles of H₂ reacted.

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Please help : ) and please explain in answer

Answers

The transfer of energy doe not always affect the appearance of the lake because it can attain a form that is quite similar to the other. It can be because of conduction, convection, and radiation.

What are the processes of heat transference?

Heat transference can be described as a natural phenomenon that can be caused by conduction, convection, or radiation.

Convection can be defined as the transfer of energy in a given fluid such as, in this case, water. The energy transfer is due to particular molecular motion, energy is transferred by bulk, or macroscopic, the motion of the fluid.

Radiation can be defined as heat transfer through space due to electromagnetic radiation. Conduction can be defined as the transfer of energy between molecules due to direct contact.

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Determine the empirical formula for each
compound.
a.
ethylene (C,H,)
b.
ascorbic acid (CH,O)
C.
naphthalene (CH)

Answers

Ethylene C2H2 , ascorbic acid formula C₆H₈O₆, naphthalene Chemical formula C₁₀H₈.

What the empirical formula tells us?

The relative ratios of the various atoms in a compound are given by an empirical formula. The ratios are still valid at the molar level. H 2 O is made up of two hydrogen atoms and one oxygen atom. Similar to this, 1.0 mole of H2O is made up of 1.0 mole of oxygen and 2.0 moles of hydrogen.

What are the ascorbic acid ?

Originally known as hexuronic acid, ascorbic acid is an organic molecule having the formula C 6H 8O 6. Although impure samples may appear yellowish, it is a white solid. Water readily dissolves it, resulting in moderately acidic solutions. It is a gentle reducer.

There are two enantiomers (mirror-image isomers) of ascorbic acid, generally referred to as "l" (for "levo") and "d." (for "dextro"). The most prevalent isomer is the l one, which is a naturally occurring form of vitamin C (also known as a "vitamer") and is necessary for both humans and many other animals to survive. Scurvy is caused by vitamin C deficiency and used to be a serious condition affecting sailors on lengthy sea trips. Due to its antioxidant qualities, it is utilized as a nutritional supplement and food additive.

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3. Contrast the three size-dependent physical properties. Next, circle the property
that changes with location.
Mass
Size-Dependent Properties
Weight
Volume
Ligh Spice

Answers

Physical characteristics known as size dependant properties alter as an object's size does. Examples of qualities that depend on size include length, width, height, volume, and mass.

What are the physical characteristics of an object that rely on its size?

The amount or size of the material affects several physical properties of matter, including length, mass, volume, weight, and so forth. These characteristics of matter and their values change together with the size or quantity of the substance.

What is a characteristic of mass?

In physics, mass is a way to measure inertia, a fundamental property of all matter. In actuality, it is the resistance a body of matter provides to a change in its speed or location.

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What is the outcome when the arrangement of atoms changes in a substance?

Answers

When the arrangement of atoms changes in a substance, the properties of the substance can change as well. The different arrangements of atoms can lead to different chemical and physical properties.

For example, if the atoms of a substance are rearranged to form a new compound, the new compound will have different chemical properties than the original substance. A new compound may have a different color, odor, reactivity, or melting point than the original substance.

Changing the arrangement of atoms without changing the chemical composition can change the physical properties. For example, a crystalline solid has atoms or molecules arranged in a regular, repeating pattern. This arrangement gives the material unique properties such as density, melting point, and hardness. If the arrangement of atoms and molecules changes, the properties of solids can also change.

In summary, when the arrangement of atoms in a substance changes, the properties of the substance can also change. Different arrangements of atoms have different chemical and physical properties.

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How did the experiement with boiling water compare with the experiment in which magnesium was added to hydrochloric acid

Answers

In the experiment with boiling water and the experiment in which magnesium was added to hydrochloric acid both resulted in gas formation.

Hydrochloric acid and magnesium in a balanced chemical reaction

[tex]MgCl_{2}[/tex] + [tex]H_{2}[/tex] = Mg + 2HCl (g).

A gas is hydrogen . This reaction is exothermic (energy is released). New compounds are being produced due to chemical change.

Nothing new is created when water is heated to a boil. Heat is added in this endothermic reaction. Gas is steam. Both experiments a gas is released. One is a chemical change the other is a physical change. One is exothermic while other is endothermic.

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3. Magnesium is a metal.
a. Describe the structure and bonding in magnesium.
b. Why can magnesium conduct electricity when solid?
c. Why is magnesium malleable?

Answers

Yes, magnesium is a metallic element and is a member of the alkaline earth metals group.

What is  Magnesium?

Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a silvery-white, highly reactive metal that is essential for many biological processes. Magnesium is the eighth most abundant element in the Earth's crust and the fourth most abundant element in the human body.

It is an important component of many enzymes, proteins, and other molecules. Magnesium is found naturally in many foods, including green vegetables, nuts, and grains. Magnesium plays a role in maintaining normal muscle and nerve function, keeping a healthy immune system, regulating blood sugar levels, and helping to form strong bones.

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Photosynthesis Notes

1. Give the Greek root word meaning for photoautotroph.

2. What was von Helmont testing with his willow tree experiment? What was the result?

3. Define the law of conservation of mass.

4.

Describe the experiment used by Joseph Priestly to discover oxygen.

5. List the primary constituents of air.

a.

b.

C.

d.

e.

6. What did Jan Ingenhousz discover about plants?

7. Based on the work of Nicolas de Saussure, what are the two primary sources of mass for

plants?

8. Define photosynthesis-

9. Define potential energy-

Answers

Photoautotroph has been derived from the combination of three words, photo -meaning "light", autos- meaning "self", and troph meaning "nutrition".

Land plants and photosynthetic algae are both photoautotrophs. These species contain pigments that can capture light, like chlorophyll. Origin of the word: photo- (light) + auto (self) + troph (nourishment). Autotrophs known as photoautotrophs generate complex chemical substances like proteins, lipids, and carbohydrates by absorbing light. Photosynthesis is the name given to this light-mediated process.

An energy-rich carbohydrate like glucose is produced by plants using carbon dioxide, inorganic salts, and water during a process called photosynthesis. As a byproduct, oxygen is also produced, other than glucose. Land plants and photosynthetic algae are both photoautotrophs. These species contain pigments that can capture light, like chlorophyll.

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2POCl3(g)---> 2PCl3(g)+O2(g), deltaH_o=572 kJ, delta S_o=179 J/K
At what temperature (if any) would the decomposition of POCl3 become spontaneous?

Answers

At T=3195.53 Kelvin, decomposition of PoCl3 becomes spontaneous.

What is meant by spontaneous?

In chemistry, spontaneous processes is one that occurs without addition of external energy. Spontaneous process can occur quickly or slowly, because spontaneity is not related to the kinetics or reaction rate.

Spontaneous reaction happens in given set of conditions without interruptions whereas the nonspontaneous reaction occurs with the help of external agents like heat or energy.

Given, ∆H=572KJ and ∆S=0.179J/K

According to thermodynamical concept;

As, T=∆H/∆S,

=572/0.179

= 3195.53 Kelvin

We know, change in Gibbs free energy (∆G)=0 ; which shows that reaction is in equilibrium.

Above this temperature the reaction becomes spontaneous and moves in  forward direction.

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7.92g of FeSO4 • 6H2O is equal to how many molecules?

Answers

7.92g of FeSO4 • 6H2O is equal to 1.55 x 10^23 molecules.

What is molecules?

Molecules are the smallest units of matter that can exist by themselves. They are composed of two or more atoms that are held together by chemical bonds. Molecules can be found in the air we breathe, the water we drink, and the food we eat. They can also be found in living organisms, like plants and animals. Molecules can be made of a variety of different atoms, such as oxygen, carbon, nitrogen, and hydrogen. They also come in different shapes and sizes, depending on the types of atoms they are composed of.

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Problem that can be caued by both the complete and incomplete
combution of methane in a ga fire

Answers

Oxidation of methane to soot:

CH4(g)+O2(g)⟶C(s)+2H2O(g)

Among the hydrocarbons is methane, CH4(g). Only the elements carbon (C) and hydrogen (H) are present in the complex. When methane burns with too much oxygen, it produces water vapor and carbon dioxide gas CO2(g) (g). Complete combustion is defined as combustion with extra oxygen.

Methane can be partially oxidized into a variety of compounds when it is burned inefficiently, including CO, methanol, formic acid, formaldehyde, and higher hydrocarbons.

Carbon monoxide is an extremely toxic gas. It is invisible and odorless. Without anybody being aware of it, malfunctioning gas fireplaces or boilers can poison the air in a room by emitting carbon monoxide.

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The complete question is

Problems that can be caused by both the complete and incomplete

combustion of methane in a gas fire.

Organic compounds form the basis of?

Answers

Answer:

1. carbon

Explanation:

carbon atoms bound to one another and other atoms by covalent bonds and found in the cells of living organisms. Hydrogen, oxygen and nitrogen are typical elements which, in addition to carbon, make up organic compounds.

the answer is carbon

A scientist is studying the liquid shown here. She thinks the liquid is a mixture.
Describe an investigation she could do to demonstrate that the liquid is in fact a
combination of substances.
100
1300
200
100
800-m

Answers

Answer:

You have not shown the liquid which is to be shown, please show us

calculate the mass of .00566 mol of germanium, show work.

Answers

1 mol of germanium = molar mass = 72.630 grams.

(0.00566 mol Ge) x (72.630 grams/1 mol Ge) = 0.410 grams age

What is the name of the systematic approach that scientists use to understand the natural world?
a law
the scientific method
a hypothesis
a theory

Answers

It would be due to the scientific method

Hope this helps :)

select all that apply. please i will mark you brainliest.

Answers

Answer:

The 2nd option

An extremely efficient enzyme has a ____ KM and a ____ kcat.

Answers

An extremely efficient enzyme has a small KM and a large kcat.

The conversion rate at the lowest substrate concentration is measured in kcat/km. This interpretation is accurate. kcat/Km is a good indicator of an enzyme's effectiveness since it takes into account both the enzyme's maximum rate, kcat, and its affinity for its substrate (Km).The turnover number, or the number of molecules that may be created per second per active site, of an enzyme is provided by the formula k c a t / kM.Because the substrate concentration is almost usually much greater than the Km, in many situations, enzymes are only better when they have a larger kcat. It seems disingenuous to me to use the ratio when this is plainly the case, yet it still happens much too frequently. It could serve as a useful benchmark when compared to enzymes in particular situations.

complete question:An extremely efficient enzyme has a _____ KM and a _____ kcat.

A) small; small

B) small; large

C) large; large

D) large; small

E) kcat and KM do nothing to predict the efficiency of an enzyme

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A 0.95 M solution of 10.0 mL Al(OH)3 is neutralized using a 2 M solution of H2SO4. How much H2SO4 was needed

Answers

H2SO4 has a molecular weight of 98 g/mole. 98% concentrated sulfuric with a density of 1.84 g/mL is the usual source.

We would need 98 g for a 1 M solution in 1 L, but because this is for 500 mL, just 49 g of H2SO4 will be needed. Common concentrations of sulfuric acid are 78, 93, or 98 percent. Pure anhydrous sulfuric acid does not exist in nature due to its affinity for water. 35% sulfuric acid Fertilizers like ammonium sulfate and super-phosphate of lime are produced using solution. In the production of hydrochloric acid, sulfate salts, synthetic detergents, dyes & pigments, and medications, it is frequently employed.

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Human population growth in 2018 was 1. 7%. If this rate of growth remains constant, in what year will the human population double?

Answers

Human population growth will Double time and that will be 41.17 years

Human growth can be defined as;

The growth and development are positively influenced by factors, like parental health and genetic composition.

Population growth is the increase in the number of humans on Earth.

Human population has grown exponentially over the past century. It has done so largely by producing large amounts of food, and learning how to control disease.

We can find what year the human population would double using the rule of 70. This is given as;

Double time = 70 / rate(r)

Double time = ?

Rate = 1.7%

Inserting into the equation;

Double time = 70 / 1.7

Double time =41.17 years

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Are used for energy storage to build structures and as signal molecules to help cells communicate with each other

Answers

Yes, carbohydrates are used for energy storage to build structures, and as signal molecules to help cells communicate with each other.

Carbohydrates and functions

Carbohydrates are molecules that consist of carbon, hydrogen, and oxygen atoms and can be broken down by the body to provide energy. They are used to build the structural components of cells, such as the cell walls and membranes, and are also used as signal molecules between cells. As signal molecules, they can help cells communicate with each other and respond to changes in the environment.

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salt brine in known to deteriorate steel piping system. what substance can be used to counteract ther corrosuve effects

Answers

Steel piping systems have a history of degrading under salt brine. It is possible to neutralize their corrosive effects by using sodium dichromate.

For melting snow and ice on sidewalks, parking lots, and roads, salt brine is a practical liquid solution. When the salt content of the water reaches a certain proportion, salt brine is produced in tanks that circulate certain volumes of water and rock salt. After that, the solution is pumped into holding tanks in order to be used. In order to address particular temperature ranges of a storm and improve the application's efficacy, other components like calcium or magnesium may be added.

In advance of winter weather, surfaces are pre-treated with salt brine. If Salt Brine is used ahead of a winter storm, it will start to function as soon as the first snowflake falls and assist prevent the accumulation of snow and ice on the pavement.

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Is 1g equal to 1 mol?

Answers

Depending on the question you have,maybe yes maybe no go and try it on this rule MOLES=MASS/MOLAR MASS and you’ll find out

How many times more acidic is a solution with a pH of 2 compared with one with a pH of 5 Explain.

Answers

pH is a logarithmic scale.This implies that the acidity (H + concentration) changes by 10 times for each pH variation of one digit. For instance, a pH 4 solution contains 10 times more H + than a pH 5 solution. Since a pH 3 solution is 100 times more acidic than a pH 5 solution, it will contain 100 times more hydrogen ions (H +).

What is the pH scale?

A water-based solution is described by its pH value. In general, an acidic solution is one with a small pH value, and an alkaline solution is one with a larger pH value (more basic). Since the pH scale is symmetrical around 7, a solution with a pH of 7 is completely neutral (neither acidic nor basic). Figure 1 displays a few instances of typical compounds and where they fall on the pH scale.

The concentration of hydrogen ions (H+) in a solution is directly measured by the pH value of the solution. Acids have high H+ concentrations, which results in low pH levels. There is hardly any H+ in bases. Large pH values, greater than pH 7, are present in basic liquids.

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Other Questions
pls find the angle HAF in the diagram 11. Which of the following is a solution to theinequality c + 4 Solve for : -3(x+8)=30 Which of the following is NOT a way in which viruses differ from all other living things?a. they do not growb. they cannot respond to environment stimuli through metabolic changesc. they cannot self-replicated. they live inside host cells What is the synonym of harrow? At a student government fundraiser, a notebook costs $7 and a t-shirt costs $12. if the total received for 60 items was $540, how many notebooks were sold? a. 24 b. 30 c. 36 d. 40 The surface appearance of a material is called its O rock cycle O lava fracture luster The volume of a cylinder is 60 cubic centimeters. What is the number of cubic centimeters in the volume of the sphere it circumscribes What two coins add up to 30 cents but one isn't a nickel? The numerical coefficient of 3xy2 is 2 true or false A fluid flowing in a pipe has 1.05 in diameter. If the fluid has density, viscosity andvolumetric flow rate are 62.3 , 1.2 cP and 35 gpm respectively. Calculate: 3a) The velocity.b) Reynolds number ()[2]- Find the followinga) Drive an expression to find a pressure of methane gas at point B b) If the temperature of methane is 100 F, Calculate pressure ofmethane gas at point B.c) Calculate pressure of oil at point C.PA = 1, 000 psig [3]- If the water is pumped down one well and the displaced oil which flows up through well exit (see the fig below), drive an expression to find a pressure of inlet water Pw needed to displace oil when the water/oil interfacial tension is applied. A nurse is teaching a newly-diagnosed client with rheumatoid arthritis (RA) about pharmacologic therapy with disease-modifying antirheumatic drug (DMARD) therapy. Which statement should the nurse include in the teaching Which of the following graphs has a slope of negative twoRead the excerpt from The Secret Chimneys by Agatha Christie. Then, answer the question that follows.It was just after half-past eleven that he brought the car to rest in the road adjoining the park of Chimneys. Jumping out he scaled the wall easily enough, and set out towards the house. It took him longer than he thought, and presently he broke into a run. A great grey mass loomed up out of the darknessthe venerable pile of Chimneys. In the distance a stable clock chimed the three quarters.11:45the time mentioned on the scrap of paper. Anthony was on the terrace now, looking up at the house. Everything seemed dark and quiet."They go to bed early, these politicians," he murmured to himself.And suddenly a sound smote upon his earsthe sound of a shot. Anthony spun round quickly. The sound had come from within the househe was sure of that. He waited a minute, but everything was still as death. Finally he went up to one of the long French windows from where he judged the sound that had startled him had come. He tried the handle. It was locked. He tried some of the other windows, listening intently all the while. But the silence remained unbroken.In the end he told himself that he must have imagined the sound, or perhaps mistaken a stray shot coming from a poacher in the woods. He turned and retraced his steps across the park, vaguely dissatisfied and uneasy.He looked back at the house, and whilst he looked a light sprang up in one of the windows on the first floor. In another minute it went out again, and the whole place was in darkness once more.Which word best represents the mood of the passage?A-BoredB-MysteriousC-SillyWhich line(s) from the passage best reflects the mood you selected?D-"They go to bed early, these politicians," he murmured to himself.E- It was just after half-past eleven that he brought the car to rest in the road adjoining the park of Chimneys.F-He looked back at the house, and whilst he looked a light sprang up in one of the windows on the first floor. thirds and a y-intercept of 2? Explain how oil prices in the United States could be affected if the checkpoints in Asia and Africa were blocked. HELP Beginning from a depth of 35 feet below the surface, a whale swims upward and jumps to a height of less than 17 feet above the surface. Use an inequality to model the possible change in the number of feet, r, of the whale's elevation. The heat of fusion of a substance is 42. 5 J/g. How much energy is released when 40 g of this substance at its freezing point completely changes into a solid? Show your work. A. ) 1. 700B. ) 1. 06 C. ) 42. 5 D. ) 0 J In tenpin bowling, the height of each bowling pin must be 15 inches with an absolute deviation of 0.03125 inches find the minimum and maximum possible heights of the bowling pin. If a poet is discussing the type of meter in their poem, what are they MOST likely talking about? A. the pauses within lines marked by punctuation B. the repetition of a word at the beginning of each line C. a stylistic device that puts similar sounds together in a series D. the repetitive pattern of syllables The U.S. Constitution gives each branch of the federal government the ability to limit and restrict some actions of the other branches. This is an example of which American founding ideal? A. Checks and balances B. Representative democracy C. Federalism D. Separation of powers Why do you think American Indians were represented in history books in the manner described in the Councils letter? Use examples of their depictions from the text and explain what you believe the purpose of portraying American Indians this way was.