It takes 120. s for the concentration of 1.00 M PH3 to decrease to 0.250 M. How much time is required for 2.00 M PH3 to decrease to a concentration of 0.350 M

Answers

Answer 1

150.83s is required for 2.00 M PH3 to decrease to a concentration of 0.350 M.

Using Rate Law:

[tex]Rate = \frac{d[PH_{3}] }{[PH_{3} ]}[/tex]

∫[tex]\frac{[PH_{3}] }{[PH_{3}]0} \frac{d[PH_{3}] }{[PH_{3}] } = k[/tex][tex]\int\limits^0_t {t}[/tex]

By solving,

[tex]ln[PH_{3} ] = ln[PH_{3}]_{0} - kt[/tex]

ln(2.50) = ln(1) - -k(120)

-1.38 = 0 - (-120k)

k = 0.01155[tex]s^{-1}[/tex]

Now, using the first order concentration time equation,

[tex]ln[PH_{3}] = ln[PH_{3}]_{0} - kt[/tex]

ln (0.350) = ln (2) - (-0.01155 t)

-1.049 = 0.693 - (-0.01155 t)

1.74 = 0.01155t

t = 150.83s

A rate law demonstrates the relationship between reaction rate and reactant concentration. The link between the reaction rate and the concentrations of each reactant is expressed by a rate law. The proportionality constant (k) connecting the rate of the reaction to reactant concentrations determines the specific rate constant (SRC).

Rate laws give a mathematical explanation of how variations in a substance's concentration can alter the rate of a chemical reaction. Since reaction stoichiometry cannot predict rate laws, they must be determined experimentally.

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Related Questions

a solution is made containing 4.6 g of sodium chloride per 250 g of water what is the percent by mass

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The percent by mass of the solution containing 4.6 g of sodium chloride per 250 g of water is 1.81%. This means that 1.81% of the total mass of the solution is made up of sodium chloride.

To calculate the percent by mass of a solution containing 4.6 g of sodium chloride per 250 g of water, we need to divide the mass of the solute (sodium chloride) by the mass of the solution and multiply by 100%. Mathematically, this can be expressed as:

Percent by mass = (mass of solute / mass of solution) x 100%

The mass of the solution is the sum of the mass of the solute (4.6 g) and the mass of the solvent (water, 250 g), which is:

Mass of solution = Mass of solute + Mass of solvent

Mass of solution = 4.6 g + 250 g

Mass of solution = 254.6 g

Substituting the values, we get:

Percent by mass = (4.6 g / 254.6 g) x 100%

Percent by mass = 1.81%

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What mass of platinum could be plated on a electrode from the electrolysis of Pt(NO3)2 solution with a current of o.500 A for 55.0 s

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0.111 g of platinum could be plated on the electrode under the given conditions. when electrolysis of Pt(NO3)2 solution with a current of o.500 A for 55.0 s.

To calculate the mass of platinum plated on the electrode, we will use the following terms: current (I), time (t), molar mass of platinum (M_Pt), Faraday's constant (F), and the stoichiometry of the reaction (n).

In this case, we have:
I = 0.500 A
t = 55.0 s
M_Pt = 195.08 g/mol (platinum)
F = 96485 C/mol (Faraday's constant)
n = 2 (from Pt(NO3)2, where 2 moles of electrons are required to reduce 1 mole of Pt)

First, find the total charge (Q) passed through the solution:
Q = I × t = 0.500 A × 55.0 s = 27.5 C

Now, use Faraday's law to find the moles of platinum plated:
Moles of Pt = (Q × n) / F = (27.5 C × 2) / 96485 C/mol = 0.000569 mol

Finally, find the mass of platinum plated:
Mass of Pt = Moles of Pt × M_Pt = 0.000569 mol × 195.08 g/mol = 0.111 g

Therefore, 0.111 g of platinum could be plated on the electrode under the given conditions.

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How many grams of radium may be formed by the passage of 1.71 amps for 2.21 hours through an electrolytic cell that contains a molten radium salt.

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The mass of radium formed by the passage of 1.71 A current for 2.21 hours through an electrolytic cell containing molten radium salt is 5.45 g.

The amount of substance (in moles) formed during electrolysis can be calculated using Faraday's law, which states that the amount of substance (in moles) formed is directly proportional to the charge passed through the electrolyte. The equation for Faraday's law is:

n = (Q) / (zF)

Where:

n = amount of substance formed (in moles)

Q = charge passed through the electrolyte (in coulombs)

z = charge number or valency of the ion being reduced or oxidized

F = Faraday's constant (96,485 C/mol)

Given:

Current (I) = 1.71 A

Time (t) = 2.21 hours = 2.21 x 3600 seconds (converted to seconds)

Charge (Q) = I x t (current multiplied by time)

Charge number of radium ion (z) = 2 (since radium has a charge of +2)

Faraday's constant (F) = 96,485 C/mol

Molar mass of radium (Ra) = 226 g/mol

Plugging in the values and solving for n:

Q = 1.71 A x 2.21 x 3600 s = 13,268 C

n = (13,268 C) / (2 x 96,485 C/mol) = 0.0687 mol

The mass of radium formed can be calculated using the molar mass of radium:

Mass = n x molar mass of radium = 0.0687 mol x 226 g/mol = 5.45 g

So, the mass of radium formed by the passage of 1.71 A current for 2.21 hours through the electrolytic cell containing molten radium salt is 5.45 g.

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n testing an unknown for the ammonium ion, a student heats the beaker directly with a flame, inadvertently causing the solution to boil and spatter. How could this lead to an error in the determination

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The student's error of heating the beaker directly with a flame causing the solution to boil and spatter could lead to an error in the determination of the ammonium ion in the unknown.

When the ammonium ion, NH₄⁺, is heated, it undergoes thermal decomposition to form ammonia gas, NH₃, and water vapor. This reaction is exothermic, meaning it releases heat.

Therefore, when the student heated the beaker directly with a flame, it led to the decomposition of the ammonium ion, causing the formation of ammonia gas and water vapor. The spattering of the solution could result in a loss of ammonium ions or an incomplete reaction of the ammonium ions.

As a result, the amount of ammonium ions detected would be less than the actual amount present in the solution. This would lead to an error in the determination of the concentration of the ammonium ion in the unknown. It is essential to follow proper testing procedures to avoid errors and obtain accurate results.

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If a mineral is opaque, lustrous, malleable, and can conduct heat and electricity, it is a(n) ________. A) element B) gemstone C) radioactive element D) metal E) crystal

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If a mineral is opaque, lustrous, malleable, and can conduct heat and electricity, it is a metal.

The characteristics listed are typical of metals, which are good conductors of heat and electricity, are lustrous, and can be shaped by hammering or rolling without breaking (i.e., malleability). Gemstones are generally transparent or translucent, while crystals are more broadly defined as solids in which atoms or molecules are arranged in a regular, repeating pattern. Elements and radioactive elements are more general categories that could include metals but are not specific to this set of characteristics.

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The observations above suggest that the extra liquid you added to your beaker could have been: a. Pure water b. More of the solution that was in your beaker to start c. A highly concentrated solution of salt and sugar

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it seems that the extra liquid you added to your beaker could have been either a) pure water, b) more of the solution that was initially in your beaker, or c) a highly concentrated solution of salt and sugar.

To determine which option is correct, you can consider the changes observed in the beaker after adding the extra liquid. If the concentration of the solution remains unchanged, then option a) pure water is likely the correct answer, as it would dilute the solution evenly without affecting its composition.

If the concentration increases, then option c) a highly concentrated solution of salt and sugar might be correct, as it would increase the overall solute content in the beaker.

Finally, if the concentration remains the same but the volume increases, option b) more of the original solution could be the correct answer, as it would maintain the original composition while adding volume.

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chlorine dioxide is used as a disinfectant in municipal water-treatment plants. It decomposes in a first-order reaction with a rate constant of 0.0714 s^-1 If the initial concentration were 0.12M what wold the concentation be after 14.0s has elapsed

Answers

The first-order rate law equation for the decomposition of chlorine dioxide is given as:

ln([ClO2]t/[ClO2]0) = -kt

where [ClO2]t is the concentration of chlorine dioxide at time t, [ClO2]0 is the initial concentration, k is the rate constant, and t is the elapsed time.

Rearranging this equation, we get:

[ClO2]t = [ClO2]0 x e^(-kt)

Substituting the given values, we get:

[ClO2]t = ₍0.12 M₎ x e^(-0.0714 s^-1 x 14.0 s) = 0.064 M

Therefore, the concentration of chlorine dioxide after 14.0 seconds would be 0.064 M.

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True or False [2 pts]: A photon must have exactly the right energy to excite an electron from one energy level to another energy level.

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The given statement "A photon must have exactly the right energy to excite an electron from one energy level to another energy level" is false because a photon's energy needs to be equal to or greater than the difference in energy between the two levels to excite an electron to a higher energy level, not exactly the same amount.

A photon doesn't need to have exactly the same amount of energy as the difference between the two energy levels to excite an electron from one energy level to another. Instead, the photon's energy must be equal to or greater than the difference between the two energy levels.

If the photon has more energy than the required amount, the excess energy will be transferred to the electron as kinetic energy. This process is called the photoelectric effect, which is the emission of electrons from a material when light of sufficient frequency (or energy) shines on it.

Therefore, a photon with a higher frequency (or energy) than the required amount can excite an electron to a higher energy level. The electron will then have excess kinetic energy, which can be transferred to surrounding atoms or molecules as heat.

Conversely, a photon with less energy than the required amount will not be able to excite the electron to a higher energy level. In summary, a photon's energy needs to be equal to or greater than the difference in energy between the two levels to excite an electron to a higher energy level, but it doesn't need to be exactly the same amount..

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N2O5 decomposte in the solvent CCl4 as follows: 2N2O3 → 4NO2 + O2 The specific rate constant for the first-order decomposition at 45 C is 6.32x10* s. (a) What is the concentration of N2O5 remaining after 2.00 hr if the initial concentration of N2O5 is 0.500 M? (b) How much time is required for 90% of N2O5 to disappear?

Answers

(a) To solve for the concentration of N2O5 remaining after 2.00 hours, we can use the first-order rate equation:

ln([N2O5]t/[N2O5]0) = -kt

Where [N2O5]t is the concentration of N2O5 at time t, [N2O5]0 is the initial concentration of N2O5, k is the rate constant, and t is the time. Rearranging the equation, we get:

[N2O5]t = [N2O5]0*e^(-kt)

Plugging in the values given, we get:

[N2O5]t = 0.500*e^(-(6.32x10^(-5)*2.00*3600))

[N2O5]t = 0.284 M

Therefore, the concentration of N2O5 remaining after 2.00 hours is 0.284 M.

(b) To solve for the time required for 90% of N2O5 to disappear, we can use the same first-order rate equation and solve for the time it takes for [N2O5]t/[N2O5]0 to equal 0.1 (since 90% has disappeared, only 10% remains):

ln(0.1) = -kt

Solving for t, we get:

t = -ln(0.1)/k

Plugging in the value for k, we get:

t = -ln(0.1)/(6.32x10^(-5))

t = 3.44x10^4 seconds

Therefore, it takes approximately 3.44x10^4 seconds, or 9.56 hours, for 90% of N2O5 to disappear.

In summary, the specific rate constant for the first-order decomposition of N2O5 in CCl4 at 45 C is 6.32x10^-5 s^-1. Using the first-order rate equation, we were able to solve for the concentration of N2O5 remaining after 2.00 hours and the time it takes for 90% of N2O5 to disappear. It is important to note that this reaction is dependent on the concentration of N2O5 and is not affected by the concentration of CCl4.

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Which human activity is a major reason for the increasing amounts of the atmospheric greenhouse gas, carbon dioxide

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Burning fossil fuels is a major human activity that is responsible for the increasing amounts of atmospheric greenhouse gas, carbon dioxide.

When fossil fuels like coal, oil, and natural gas are burned to produce energy for transportation, heating, and electricity, carbon dioxide is released into the atmosphere. This carbon dioxide traps heat from the sun in the Earth's atmosphere, contributing to the greenhouse effect and global climate change. Other human activities like deforestation and agriculture also contribute to the increasing levels of atmospheric carbon dioxide by reducing the number of trees and plants that absorb carbon dioxide through photosynthesis.

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what is the ph of a 0.300 m solution of aniline (c₆h₅nh₂, kb = 4.3 × 10⁻¹⁰)?

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The pH of a 0.300 M solution of aniline is 9.39.

The pH of a 0.300 M solution of aniline can be calculated using the relationship between the dissociation constant (Kb) and the ionization constant (Ka) of the acid-conjugate base pair. Since aniline is a weak base, it will react with water to produce the anilinium ion ([tex]C_6H_5NH_3^+[/tex]) and hydroxide ion (OH-).
The Kb value for aniline can be used to calculate the Ka value, which is [tex]1.9 * 10^{-5}[/tex]. From this, the pKa can be calculated as 4.72. Using the equation pH = pKa + log([A-]/[HA]), where [A-] is the concentration of the conjugate base ([tex]C_6H_5NH_2^-[/tex]) and [HA] is the concentration of the acid ([tex]C_6H_5NH_3^+[/tex]), the pH of the solution can be calculated to be approximately 9.39.

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Why does 100 mL of a 0.1 M solution of NaCl require a different amount of solid than 100 mL of a 0.1 M solution of CuSO4

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Even though both solutions have the same molarity, they "have different molecular weights, which means that the number of moles of each compound required to make a 0.1 M solution will be different".

The molecular weight of NaCl is 58.44 g/mol, while the molecular weight of CuSO4 is 159.61 g/mol.

To prepare a 0.1 M solution of NaCl, you would need to dissolve 0.1 moles of NaCl in enough water to make a final volume of 100 mL. This corresponds to 5.844 g of NaCl.

On the other hand, to prepare a 0.1 M solution of CuSO4, you would need to dissolve 0.1 moles of CuSO4 in enough water to make a final volume of 100 mL. This corresponds to 15.961 g of CuSO4.

Therefore, even though the molarity of the solutions is the same, the amount of solid required to make each solution is different due to the different molecular weights of NaCl and CuSO4.

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A monatomic ion with a charge of -2 has an electronic configuration of 1s22s22p63s23p64s23d104p65s24d105p6. This ion is a(n) anion . What is the chemical symbol of the noble gas this ion is isoelectronic with? . What is the formula of the ion? .

Answers

The chemical symbol of the noble gas is (S), and its formula is S²-.

The monatomic ion with a charge of -2 has gained 2 electrons, making the electronic configuration isoelectronic with that of a noble gas.

To determine which noble gas it is isoelectronic with, we count backwards from the last orbital filled. The last orbital filled is the 5p orbital, which contains 6 electrons. The noble gas with an electronic configuration that ends in 5p6 is Xenon (Xe).

The formula of the ion can be determined by removing the 2 valence electrons from the original configuration. This gives us

1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶, which is the electronic configuration of the ion. The ion is a negative anion, so it is likely to be a non-metal.

Looking at the electron configuration, we see that it has a completely filled 4s and 3d orbitals, as well as a completely filled 4p orbital.

This suggests that the ion is a member of the oxygen group (group 16) on the periodic table. The ion with this electron configuration is Sulfur (S), and its formula is S²-

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How many alkene C-H peaks would you expect to see in the 1H NMR spectrum of the citral starting material

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In the citral starting material, you can expect to see  5-6 alkene C-H peaks in the 1H NMR spectrum.

Citral is an unsaturated aldehyde with the chemical formula C10H16O. It contains a carbon-carbon double bond, which is characteristic of alkenes. In the 1H NMR spectrum of citral, we would expect to see peaks corresponding to the hydrogen atoms attached to the various carbon atoms in the molecule.

Since citral contains a carbon-carbon double bond, we would expect to see two distinct types of hydrogen atoms in the molecule: those attached to carbon atoms that are part of the double bond (i.e., the alkene C-H protons), and those attached to carbon atoms that are not part of the double bond (i.e., the non-alkene C-H protons).

The alkene C-H protons in citral would give rise to a characteristic peak in the 1H NMR spectrum that is typically seen in the range of 5-6 ppm (parts per million). The exact position of this peak would depend on the chemical environment of the double bond (i.e., the other atoms and functional groups surrounding it), and could vary slightly depending on the specific isomer of citral being analyzed.

Therefore, in the 1H NMR spectrum of citral, we would expect to see one or two peaks in the 5-6 ppm range corresponding to the alkene C-H protons. The exact number of peaks would depend on whether citral exists in one or more isomeric forms, each of which would have a slightly different chemical environment surrounding the double bond.

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Which gas has the same density at 316 °C and 1.50 atm that O2 gas has at 0°C and 1.00 atm? a. SO2 b. N2 c. NO2 d. CO2 e. CI2

Answers

The correct answer to the given question is option b. N2

The answer can be found by using the ideal gas law, which states:

PV = nRT

Where:

P = pressure

V = volume

n = number of moles

R = gas constant

T = temperature

Assuming that the volume and the number of moles are constant, the equation can be simplified to:

(P/T)1 = (P/T)2

Where subscripts 1 and 2 represent the initial and final conditions, respectively.

We can use this equation to find the temperature at which the density of the given gas is the same as that of O2 gas at 0°C and 1.00 atm. The molar mass of O2 is 32.00 g/mol.

Let's first convert the initial and final temperatures to Kelvin:

316 °C = 589 K

0°C = 273 K

Now, let's solve for the pressure of the given gas:

(P/T)1 = (P/T)2

(P/589) = (1.50/273) (using the values given in the question)

P = (1.50/273) * 589

P = 3.23 atm

Next, we can use the density equation:

density = (molar mass * pressure) / (gas constant * temperature)

For O2 at 0°C and 1.00 atm, the density is:

density = (32.00 g/mol * 1.00 atm) / (0.08206 Latm/molK * 273 K)

density = 1.43 g/L

Now we can solve for the temperature at which the density of the given gas is also 1.43 g/L:

1.43 = (molar mass * 3.23) / (0.08206 * T)

T = (molar mass * 3.23) / (0.08206 * 1.43)

T = 258 K = -15°C

Therefore, the gas that has the same density at 316°C and 1.50 atm that O2 gas has at 0°C and 1.00 atm is nitrogen gas (N2).

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Write the structural formula for the product that forms when 1-methylcyclopentene reacts with KMnO4, OH-, heat, then H3O .

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The reaction between 1-methylcyclopentene and [tex]KMnO_4[/tex], OH-, heat, and [tex]H_3O[/tex] can lead to the formation of a number of different products depending on the reaction conditions and structural formula.

One possible product is the oxidation of 1-methylcyclopentene to form a hydroperoxide:

1-methylcyclopentene +  [tex]KMnO_4[/tex] + OH- → 1-methylcycloperoxyethane +  [tex]MnO_2[/tex] +  [tex]H_2O[/tex]

Another possible product is the oxidation of 1-methylcyclopentene to form a cycloalkene carboxylic acid:

1-methylcyclopentene +  [tex]KMnO_4[/tex] + OH- → 1-methylcyclohexenecarboxylic acid +  [tex]MnO_2[/tex] + [tex]H_2O[/tex]

A third possible product is the oxidation of 1-methylcyclopentene to form a carbonyl compound and an alcohol:

1-methylcyclopentene +  [tex]KMnO_4[/tex] + OH- → 3-methyl-2-butenal + [tex]MnO_2[/tex] +  [tex]H_2O[/tex]

It is important to note that these reactions can be complex and involve multiple steps, depending on the specific conditions. The final products will also depend on the reactant ratios and the reaction conditions.  

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The charge of the Cu atom in [Cu(NH3)4]2 is ______. (Enter your answer in the first answer box below as the charge followed by the number, for example, 1.) The coordination number of the Cu atom in [Cu(NH3)4]2 is ______. (Enter your answer in the second answer box below as a whole number with no sign, for example, 2.)

Answers

The charge of the Cu atom in [Cu(NH3)4]2 is +2. The coordination number of the Cu atom in [Cu(NH3)4]2 is 4.

Acid H2X gives two H ions. A 1.90 g sample of H2X reacts completely with 45.0 mL of 0.500 M NaOH solution. What is the molar mass of H2X

Answers

The molar mass of H2X is 42.2 g/mol.

First, we need to find the number of moles of NaOH used in the reaction:

45.0 mL * 0.500 mol/L = 0.0225 mol NaOH

Since H2X gives two H ions, the number of moles of H2X used in the reaction is equal to twice the number of moles of NaOH used:

2 * 0.0225 mol NaOH = 0.045 mol H2X

Next, we can use the mass and moles of H2X to calculate its molar mass:

Molar mass = mass / moles = 1.90 g / 0.045 mol = 42.2 g/mol

Therefore, the molar mass of H2X is 42.2 g/mol.

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Answer:

The molar mass of H2X is 169 g/mol.

Explanation:

The balanced chemical equation for the reaction between H2X and NaOH is:

H2X + 2 NaOH → 2 H2O + Na2X

From the equation, we can see that one mole of H2X reacts with 2 moles of NaOH to produce 1 mole of Na2X. Therefore, the number of moles of NaOH used can be calculated as:

moles of NaOH = volume of NaOH solution (L) × concentration of NaOH (mol/L)

moles of NaOH = 0.0450 L × 0.500 mol/L

moles of NaOH = 0.0225 mol

Since the stoichiometry of the reaction is 1:2 between H2X and NaOH, the number of moles of H2X used in the reaction is half of the moles of NaOH used:

moles of H2X = 0.0225 mol ÷ 2

moles of H2X = 0.01125 mol

The molar mass of H2X can be calculated by dividing the mass of the sample by the number of moles used:

molar mass of H2X = mass of sample (g) ÷ moles of H2X

molar mass of H2X = 1.90 g ÷ 0.01125 mol

molar mass of H2X = 169 g/mol

Therefore, the molar mass of H2X is 169 g/mol.

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If Spike was assigned BC, then he would combine 8.00 mL of ammonium chloride and 4.00 mL of ammonia to make his buffer.

a) true

b) false

Answers

The answer is true. Ammonium chloride and ammonia are commonly used to make a buffer with a pH range of 7.9-8.3.

Ammonium chloride is an acidic salt that dissociates in water to form ammonium ions (NH4+) and chloride ions (Cl-). Ammonia is a weak base that accepts hydrogen ions (H+) from water to form ammonium ions (NH4+) and hydroxide ions (OH-). When ammonium chloride and ammonia are mixed together, the ammonium ions act as an acid and the ammonia molecules act as a base, resulting in a solution that resists changes in pH. This buffer solution is commonly used in biological and chemical experiments that require a stable pH environment.

In this scenario, Spike was assigned BC and was instructed to combine 8.00 mL of ammonium chloride and 4.00 mL of ammonia to make his buffer. By combining these two solutions, Spike will create a buffer with a pH within the desired range of 7.9-8.3, which will enable him to maintain a stable environment for his experiment. Therefore, the answer is true.

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Chrysoberyl is ___. Group of answer choices A light green-yellow form of Beryl very common throughout the world only formed in beryllium-poor environments

Answers

Chrysoberyl is Faceted to produce "cyclic twins" which is the correct option E.

Chrysoberyl is a beryllium aluminate mineral or gemstone with the chemical formula BeAl₂O₄. Chrysoberyl and beryl are two very distinct gemstones, despite the fact that their names are similar and they both contain beryllium. On the Mohs scale of mineral hardness, chrysoberyl, which ranks between corundum and topaz at 8.5, is the third-hardest naturally occurring gemstone that is often found.

Pegmatitic mechanisms result in the formation of chrysoberyl. Relatively low-density molten lava is created during melting in the Earth's crust and has the ability to ascend higher and reach the surface. Because water could not be integrated into the crystallisation of solid minerals, it grew increasingly concentrated in the molten rock as the primary magma body cooled.

As a result, the remaining magma is more abundant in water and uncommon elements that also do not fit into the crystal structures of the main minerals that form rocks. By lowering the temperature range before the magma solidifies fully, water allows the concentration of rare elements to advance to the point where they can create their own unique minerals.

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Complete question:

Chrysoberyl is

A light green-yellow form of Beryl

very common throughout the world

only formed in beryllium-poor environments

the 3rd hardest natural gemstone

Faceted to produce "cyclic twins"

A solution containing 15.0mL of 4.00MHNO3 is diluted to a volume of 1.00L. What is the pH of the solution

Answers

The pH of the diluted nitric acid solution is 1.22.

To calculate the pH of the solution, we need to first calculate the concentration of the diluted solution:

We know that the initial solution has a volume of 15.0 mL and a concentration of 4.00 M. We can use the dilution formula to find the final concentration:

M1V1 = M2V2

where M1 is the initial concentration, V1 is the initial volume, M2 is the final concentration, and V2 is the final volume.

Substituting the values given:

(4.00 M) x (15.0 mL) = M2 x (1000 mL)

M2 = (4.00 M x 15.0 mL) / 1000 mL

M2 = 0.060 M

So the final concentration of the diluted solution is 0.060 M.

To find the pH of this solution, we can use the equation:

[tex]pH = -log[H^+][/tex]

where [[tex]H^+[/tex]] is the hydrogen ion concentration.

We can use the fact that nitric acid ([tex]HNO_3[/tex]) is a strong acid and completely dissociates in water to form [tex]H^+[/tex] ions and [tex]NO_3^-[/tex] ions. Therefore, the hydrogen ion concentration is equal to the concentration of the nitric acid:

[[tex]H^+[/tex]] = 0.060 M

Substituting this into the pH equation, we get:

pH = -log(0.060)

pH = 1.22

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Oxygen and copper are produced during the electrolysis of a CuO solution. Which reaction occurs at the positive electrode

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The reaction that occurs at the positive electrode during the electrolysis of a CuO solution is:

2O²⁻→ O₂ + 4e⁻

During the electrolysis of a CuO solution, oxygen gas is produced at the positive electrode (also known as the anode). This is because the positive electrode attracts negatively charged ions, which are oxide ions (O²⁻), and causes them to lose electrons and form oxygen gas. The copper ions (Cu²⁺) from the CuO solution will be attracted to the negative electrode (also known as the cathode) and gain electrons, which will cause them to form solid copper metal.

So overall, the reaction at the positive electrode is 2O²⁻→ O₂ + 4e⁻.

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How much EDTA, glucose, and Tris would you need to make 345 mL of a 16 mM EDTA, 0.24% Glucose, 75 mM Tris solution

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The 345 mL of a 16 mM EDTA, 0.24% glucose, 75 mM Tris solution, you will need 16.98 g of EDTA, 0.828 g of glucose, and 3.152 g of Tris. Dissolve each compound in the appropriate amount of distilled water, adjust the pH to the desired value, and then bring the final volume up to 345 mL with distilled water.

To make a 16 mM EDTA, 0.24% glucose, 75 mM Tris solution with a final volume of 345 mL, we first need to calculate the amount of each reagent required:

EDTA:

To make a 16 mM solution in 345 mL, we need to multiply the molarity by the volume and the molar mass of EDTA to get the number of moles required:

16 mM x 0.345 L x 292.24 g/mol = 16.98 g EDTA

Glucose:

0.24% glucose means 0.24 g glucose per 100 mL solution, so for 345 mL:

0.24 g/100 mL x 345 mL = 0.828 g glucose

Tris:

To make a 75 mM solution in 345 mL, we need to multiply the molarity by the volume and the molar mass of Tris to get the number of moles required:

75 mM x 0.345 L x 121.14 g/mol = 3.152 g Tris

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How can a medical examiner tell the difference between a death by suffocation and a death by carbon monoxide poisoning

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A medical examiner can differentiate between death by suffocation and death by carbon monoxide poisoning by conducting an autopsy and examining the body, as well as investigating the circumstances surrounding the death.

Autopsy: During an autopsy, the medical examiner will examine the body for physical signs of suffocation, such as bruises, petechiae (small red or purple spots on the skin caused by bleeding), or damage to the throat, lungs, and airways.

In cases of carbon monoxide poisoning, the medical examiner may look for signs such as cherry-red skin, mucous membranes, and organs, which can indicate high levels of carbon monoxide in the bloodstream.

Toxicology: The medical examiner may also conduct toxicology tests to detect the presence of carbon monoxide in the blood. High levels of carbon monoxide can indicate carbon monoxide poisoning.

Circumstances of death: The medical examiner will also investigate the circumstances surrounding the death, such as whether the victim was found in an enclosed space or near a source of carbon monoxide, such as a car or generator. In cases of suffocation, the circumstances may suggest that the victim was intentionally or accidentally smothered or strangled.

In summary, a combination of physical examination, toxicology tests, and investigation of the circumstances surrounding the death can help a medical examiner differentiate between death by suffocation and death by carbon monoxide poisoning.

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What is the final volume in milliliters when 0.546 L of a 34.7 % (m/v) solution is diluted to 21.5 % (m/v)

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The final volume in milliliters when 0.546 L of a 34.7 % (m/v) solution is diluted to 21.5 % (m/v) is 883 milliliters.

To solve this problem, we can use the formula:

C1V1 = C2V2

where C1 and V1 are the initial concentration and volume, and C2 and V2 are the final concentration and volume.

Given:

C1 = 34.7 % (m/v)

V1 = 0.546 L

C2 = 21.5 % (m/v)

Let's first convert the initial and final concentrations to their respective mass per volume units (g/mL).

For C1:

34.7 % (m/v) = 34.7 g/100 mL = 0.347 g/mL

For C2:

21.5 % (m/v) = 21.5 g/100 mL = 0.215 g/mL

Now, we can plug in the values into the formula:

0.347 g/mL x 0.546 L = 0.215 g/mL x V2

Solving for V2, we get:

V2 = (0.347 g/mL x 0.546 L) / 0.215 g/mL

V2 = 0.883 L

Finally, we convert the volume to milliliters:

V2 = 0.883 L x 1000 mL/L

V2 = 883 mL

Therefore, the final volume is 883 milliliters.

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The age of a piece of wood from an archeological site is to be determined using the Carbon-14 method. The activity of the sample is measured to be 0.407 times the Carbon-14 activity of living plants. What is the age of the sample in years

Answers

The age of the piece of wood from the archeological site, using the Carbon-14 method,  is approximately 8,263 years.

How to determine the age of wood using Carbon-14 method?

The Carbon-14 method is a radiometric dating technique used to determine the age of organic materials, such as wood, charcoal, and bone, that are up to about 50,000 years old. The method is based on the fact that Carbon-14, a radioactive isotope of Carbon, is formed in the upper atmosphere by cosmic ray bombardment of Nitrogen-14, and it subsequently decays with a half-life of about 5,700 years.

To determine the age of the piece of wood using the Carbon-14 method, we need to use the following formula:

Age = ([tex]t_{1/2}[/tex] / ln(2)) * ln([tex]A_{o}[/tex] / A)

Where:
- Age is the age of the sample in years
- [tex]t_{1/2}[/tex] is the half-life of Carbon-14, which is 5,730 years
- ln is the natural logarithm function
- [tex]A_{o}[/tex] is the initial activity of Carbon-14 in living plants (1.0)
- A is the activity of the sample (0.407)

Step 1: Substitute the given values into the formula:

Age = (5730 / ln(2)) * ln(1.0 / 0.407)

Step 2: Calculate the natural logarithms:

Age = (5730 / 0.6931) * ln(2.4549)

Step 3: Calculate the result:

Age ≈ 8263 years

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The rate of decay for a particular type of radioactive particle is relatively constant, and can be represented using the equation Where t is time, N is the mass of the sample, and is the half-life (time it takes for half of the initial sample to decay). The half-life of Carbon-14 is about 5730 years. How many years would it take a 1000 gram sample to decay to only 400 grams

Answers



It would take approximately 11460 years for a 1000 gram sample of Carbon-14 to decay to only 400 grams.



Using the given equation, we can solve for the time it takes for a radioactive sample to decay to a certain mass. In this case, we are given the initial mass (1000 grams) and the final mass (400 grams), and we want to find the corresponding time.

We can set up the equation as follows:

400 grams = 1000 grams * (1/2)^(t/5730)

Simplifying, we can divide both sides by 1000:

0.4 = 0.5^(t/5730)

Taking the natural logarithm of both sides:

ln(0.4) = (t/5730) * ln(0.5)

Solving for t:

t = (5730 * ln(0.4)) / ln(0.5)

Using a calculator, we get t ≈ 11460 years. Therefore, it would take approximately 11460 years for a 1000 gram sample of Carbon-14 to decay to only 400 grams.

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A current of 4.82 A is passed through a Sn(NO3)2 solution. How long, in hours, would this current have to be applied to plate out 6.70 g of tin

Answers

Therefore, the current would have to be applied for 9.96 hours to plate out 6.70 g of tin.

The amount of tin deposited on the electrode is directly proportional to the quantity of electricity that passed through the circuit. The formula that relates the amount of substance deposited with the electric current and time is:

mass = (current x time x atomic mass) / (valence electrons x Faraday's constant)

We can rearrange this formula to solve for time:

time = (mass x valence electrons x Faraday's constant) / (current x atomic mass)

Substituting the given values, we have:

time = (6.70 g x 2 x 96485 C/mol) / (4.82 A x 118.71 g/mol) = 9.96 hours

So, the current would have to be applied for 9.96 hours to plate out 6.70 g of tin.

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How many moles of carbon dioxide are produced when 18.6 g of HF are reacted with an excess amount of sodium carbonate

Answers

0.4645 moles of carbon dioxide are produced when 18.6 g of HF are reacted with an excess amount of sodium carbonate.

To answer this question, we first need to write out the balanced chemical equation for the reaction between HF and sodium carbonate:
2HF + Na₂CO₃ -> 2NaF + CO₂ + H₂O
From this equation, we can see that for every 2 moles of HF that react, 1 mole of CO₂ is produced.
To determine the number of moles of HF in 18.6 g, we need to use the molar mass of HF, which is 20.01 g/mol:
moles of HF = mass / molar mass = 18.6 g / 20.01 g/mol = 0.929 moles
Since there is an excess amount of sodium carbonate, all of the HF will be consumed in the pressure reaction, so we can use the ratio of 2 moles HF to 1 mole CO₂ to calculate the number of moles of carbon dioxide produced:
moles of CO₂ = 0.929 moles HF x (1 mole CO₂ / 2 moles HF) = 0.4645 moles

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A solid having a mass of 7.89 g was added to 87.4 g of water at 19.5 oC in a calorimeter. After the solid dissolved and thoroughly mixed with the water, the temperature of the aqueous mixture increased by 5.7 oC. What is the heat of the aqueous mixture (qmix) in units of J

Answers

The heat of the aqueous mixture (q_mix) is approximately 2270 Joules.

To find the heat of the aqueous mixture (q_mix) in Joules, we need to use the formula:

q_mix = m × c × ΔT

where m is the mass (in grams), c is the specific heat capacity (in J/g°C), and ΔT is the change in temperature (in °C).

For water, the specific heat capacity (c) is 4.18 J/g°C. In this problem, we have the mass of water (87.4 g), the initial temperature (19.5 °C), and the temperature change (5.7 °C).

First, let's calculate the total mass of the aqueous mixture (water + solid):

Total mass = 87.4 g (water) + 7.89 g (solid) = 95.29 g

Next, let's find the final temperature of the mixture:

Final temperature = Initial temperature + Temperature change = 19.5 °C + 5.7 °C = 25.2 °C

Now, we can use the formula to calculate the heat of the aqueous mixture (q_mix):

q_mix = (95.29 g) × (4.18 J/g°C) × (5.7 °C) ≈ 2270 J

The heat of the aqueous mixture (q_mix) is approximately 2270 Joules.

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