g Calculate the theoretical yield (in grams) of your product if you start with 0.50 grams of E-stilbene. The molecular weight of E-stilbene is 180.25 g/mol, and the molecular weight of the product is 340.058 g/mol. 0.5109 grams 0.9433 g 0.2342 g 0.6312 g

Answers

Answer 1

Answer:

0.9433g

Explanation:

Theoretical yield is defined as the mass produced assuming all reactant reacts producing the product.

Assuming the reaction is 1:1, we need to find the moles of E-stilbene (Reactant). If all reactant reacts, the moles of E-stilbene = Moles of product.

Using the molar mass of the product we can find the theoretical yield as follows:

Moles E-stilbene:

0.50g * (1mol/180.25g) = 0.00277 moles = Moles Product

Mass Product = Theoretical yield:

0.00277 moles * (340.058g/mol) = 0.9433g


Related Questions

Which is the primary type of radiation from the sun that is absorbed by the ozone layer?
A. infrared radiatin
B. UV-B
C. X-rays
D. UV-C
E. UV-A

Answers

the answer to the question is B.UV-B

5. The Rf of ibuprofen was found to be 0.32 when t-butyl methyl ether was used as the development solvent. What effect would there be on the Rf of ibuprofen if acetone had been used to develop the TLC plate?

Answers

Answer:

The Rf value of ibuprofen increases

Explanation:

TLC involves the elution of a solute using a mobile phase(solvent). The stationary phase is made of an adsorbent such as silica.

The extent of interaction between the solute and the mobile phase affects the Rf value. The greater the interaction between the solute and the solvent, the greater the Rf value.

On the other hand, the polarity of the solvent and the solute also affects the Rf value. If the solvent is changed from t-butyl methyl ether to acetone, the Rf value for ibuprofen increases because ibuprofen is polar and acetone is also polar hence there is greater interaction between the solvent and solute.

Which one of the following reactions is NOT balanced?

2 CO + O2 + 2 CO2
2 SO2 + O2 +2 SO3
2 KNO3 + 10 K 5 K20 + N2
SF4 + 3 H2O → H2SO3 + 4HF

Answers

Answer:

co+ o2+ 2co2 is not balanced reaction

Which of the following was NOT explained by Dalton's atomic theory?
ANSWER:
A. the Law of Multiple Proportions
B. the difference between elements and compounds
C.?the difference between isotopes of an element
D. the Law of Conservation of Mass

Answers

Answer:

i think 1. law of muliple proportion

Explanation:

please like

g You observed the formation of several precipitates in the Reactions in Solution lab exercise. Identify the precipitate in each of the following reactions: a. The yellow precipitate formed in the reaction between KI and Pb(NO3)2 is . b. The white precipitate formed in the reaction between BaCl2 and H2SO4 is . c. The brown precipitate formed in the reaction between NaOH and FeCl3 is . d. The blue precipitate formed in the reaction between CuSO4 and NaOH is .

Answers

Answer:

For a: Lead iodide is a yellow precipitate.

For b: Barium sulfate is a white precipitate.

For c: Ferric hydroxide is a brown precipitate.

For d: Copper (II) hydroxide is a blue precipitate.

Explanation:

Precipitation reaction is defined as the reaction where a solid precipitate (solid substance) is formed at the end of the reaction. It is insoluble in water.

For the given options:

For (a):

The chemical reaction between KI and lead (II) nitrate follows:

[tex]2KI(aq)+Pb(NO_3)_2(aq)\rightarrow PbI_2(s)+2KNO_3(aq)[/tex]

The iodide of lead is generally insoluble in water. Thus, lead iodide is a yellow precipitate.

For b:

The chemical reaction between barium chloride and sulfuric acid follows:

[tex]BaCl_2(aq)+H_2SO_4(aq)\rightarrow BaSO_4(s)+2HCl(aq)[/tex]

The sulfate of barium is insoluble in water. Thus, barium sulfate is a white precipitate.

For c:

The chemical reaction between NaOH and ferric chloride follows:

[tex]3NaOH(aq)+FeCl_3(aq)\rightarrow Fe(OH)_3(s)+3NaCl(aq)[/tex]

The hydroxide of iron is insoluble in water. Thus, ferric hydroxide is a brown precipitate.

For d:

The chemical reaction between NaOH and copper sulfate follows:

[tex]CuSO_4+2NaOH\rightarrow Cu(OH)_2+Na_2SO_4[/tex]

The hydroxide of copper is insoluble in water. Thus, copper (II) hydroxide is a blue precipitate.

(a) The yellow precipitate formed in the reaction between KI and Pb(NO3)2 would be PbI2 according to the equation:

[tex]Pb(NO_3)_2(aq) + 2KI(aq) ---> PbI2(s) + 2KNO_3(aq)[/tex]

(b) The white precipitate formed in the reaction between BaCl2 and H2SO4 would be  BaSO4 according to the equation:

   [tex]BaCl_2 (aq) + H_2SO_4 (aq) ---> BaSO_4 (s) + 2 HCl (aq)[/tex]

(c) The brown precipitate formed in the reaction between NaOH and FeCl3 would be Fe(OH)3 according to the equation:

[tex]FeCl_3 (aq) + NaOH (aq) ---> Fe(OH)_3 (s) + NaCl (aq)[/tex]

(d) The blue precipitate formed in the reaction between CuSO4 and NaOH would be Cu(OH)2 according to the equation:

[tex]CuSO_4(aq) + 2 NaOH (aq) ---> Cu(OH)_2 (s) + Na_2SO_4 (aq)[/tex]

More on precipitation reaction can be found here: https://brainly.com/question/24846690

You are asked to prepare a buffer solution with a pH of 3.50. The following solutions, all 0.100 M, are available to you: HCOOH, CH3COOH, H3PO4 , NaCHOO, NaCH3COO, and NaH2PO4.  What would be the best combination to make the required buffer solution? Select one:
a. NaH2PO4 and NaCHOO  
b. H3PO4 and NaH2PO4
c. NaH2PO4 and HCOOH
d. CH3COOH and NaCH3COO e. HCOOH and NaCHOO
can someone helo me with this​

Answers

Answer:

e. HCOOH and NaCHOO

Explanation:

For a buffer solution, both an acid and its conjugate base are required.

With the information above in mind, we can discard options a) and c), as those combinations are not of an acid and its conjugate base.

Now it is a matter of comparing the pKa (found in literature tables) of the acids of the remaining three acids:

H₃PO₄ pKa = 2.12CH₃COOH pKa = 2.8HCOOH pKa = 3.74

The acid with the pKa closest to the desired pH is HCOOH, so the correct answer is e. HCOOH and NaCHOO

Which statement is about population density

Answers

Explanation:

Population density is defined as the number of people present per square kilometre. Population density of India according to 2011 census is 382 persons per square kilometres.

why do people who do a lot of physical work need more carbohydrate?

Answers

Answer:

A person doing physical work needs lots of good carbohydrates to keep their energy levels up and proteins to repair a muscle that might get wear and tear from overexertion. Carbohydrate will help the person work for more extended periods.

what class of organic compound is formed when cyclopentanone reacts with ethylamine in the presence of trace acid

Answers

The question is incomplete, the complete question is;

What functional group results when cyclopentanone reacts with ethylamine in the presence of trace acid? A) cyanohydrin B) semicarbazone C) imine D) enamine E) oxime

Answer:

imine

Explanation:

An imine is an unsaturated amine. An imine contains the carbon- nitrogen double bond.

Imines are obtained when a carbonyl compound is condensed with NH3 or an amine. The reaction involves several steps in its mechanism.

Since cyclopentanone is a ketone (carbonyl compound) and ethylamine is an amine,in the presence of trace acid, condensation of the two compounds occur to yield an imine

Give the symbol for an element that is:__________

a. a halogen: _______________
b. an alkali metal: _______________
c. a noble gas: _______________
d. an alkaline earth metal : ____________

Answers

a. Br, Cl, F

b. Na, K, Ba

c. He, Ar, Ne

d. Ca, Ba, Mg

Answer:

a. halogen : F ,Cl ,Br l ,At

b an alkali metal: Na,Li, Rb, Cs

c. a noble gas: He, Ne, Kr, Ar

d. an alkaline earth metal: Be,Mg,Ca, Sr

hope it helps

stay safe healthy and happy...

In the context of small molecules with similar molar masses, arrange the intermolecular forces by strength.

a. London dispersion forces
b. hydrogen bonding
c. dipole-dipole interactions

Answers

Answer:

Hydrogen bonding - London dispersion forces - dipole-dipole interactions

Strongest ----> Weakest

Explain what happens when water reacts with sodium metal. Support your answer with the relevant

equation.​

Answers

Sodium metal reacts rapidly with water to form a solution of sodium hydroxide (NaOH) and hydrogen gas (H2). This reaction is exothermic.

Equation:

2Na + 2H²0 --------}- 2NaOH + H²

If 0.250 L of a 5.90 M HNO₃ solution is diluted to 2.00 L, what is the molarity of the new solution?

Answers

Answer:

0.74 M

Explanation:

From the question given above, the following data were obtained:

Molarity of stock solution (M₁) = 5.90 M

Volume of stock solution (V₁) = 0.250 L

Volume of diluted solution (V₂) = 2 L

Molarity of diluted solution (M₂) =?

The molarity of the diluted solution can be obtained by using the dilution formula as illustrated below:

M₁V₁ = M₂V₂

5.90 × 0.250 = M₂ × 2

1.475 = M₂ × 2

Divide both side by 2

M₂ = 1.475 / 2

M₂ = 0.74 M

Thus, the molarity of the diluted solution is 0.74 M

Calculate the osmotic pressure of 5.0g of sucrose ssolution in 1L. Answer should be in Torr

Answers

Answer: The osmotic pressure of 5.0g of sucrose solution in 1 L is 271.32 torr.

Explanation:

Given: Mass = 5.0 g

Volume = 1 L

Molar mass of sucrose = 342.3 g/mol

Moles are the mass of a substance divided by its molar mass. So, moles of sucrose are calculated as follows.

[tex]Moles = \frac{mass}{molarmass}\\= \frac{5.0 g}{342.3 g/mol}\\= 0.0146 mol[/tex]

Hence, concentration of sucrose is calculated as follows.

[tex]Concentration = \frac{moles}{Volume (in L)}\\= \frac{0.0146 mol}{1 L}\\= 0.0146 M[/tex]

Formula used to calculate osmotic pressure is as follows.

[tex]\pi = CRT[/tex]

where,

[tex]\pi[/tex] = osmotic pressure

C = concentration

R = gas constant = 0.0821 L atm/mol K

T = temperature

Substitute the values into above formula as follows.

[tex]\pi = CRT\\= 0.0146 \times 0.0821 L atm/mol K \times 298 K\\= 0.357 atm (1 atm = 760 torr)\\= 271.32 torr[/tex]

Thus, we can conclude that the osmotic pressure of 5.0g of sucrose solution in 1 L is 271.32 torr.

Suppose an electron is transferred from a potassium atom to an unknown halogen atom. For which of the following halogen atoms would this process require the least amount of energy?
A. Cl
B. Br
C. I

Answers

Answer:

Cl

Explanation:

Electronegativity is the ability of an electron to attract electrons.

Now, due to the fact that halogens need just one more electron to become stable in their outermost shell, it means all halogens are electronegative.

However, the smaller the atomic number, the bigger the charge density and thus the more electronegative.

Thus, it is the halogen element with the highest atomic number further down the periodic table that will have the least electro negativity and thus require highest amount of energy to attract other electrons.

Thus, since chlorine (Cl) has the least atomic number of 17, then it means that it will be the one that will easily accept the electrons the most from other elements. Therefore the process of transferring electrons from potassium to chlorine will take the least amount of energy.

Based on the equations below, which metal is the least active? Pb(NO3)2(aq) + Ni (s) --> Ni(NO3)2 (aq)+ Pb(s) Pb(NO3)2(aq) + Ag(s) --> No reaction Cu(

Answers

Answer:

Ni

Explanation:

An active metal is a highly reactive metal. Active metals are found high up in the activity series.

Active metals react with other metals that are lower than them in the activity thereby displacing the lower metals from a solution of their salts. This is what may have happened in the other two reactions.

Ni is the most active metal listed in the question since it can react a compounds with Pb(NO3)2(aq) to liberate Pb metal.

Under certain conditions, the substance mercury(II) oxide can be broken down to form mercury and oxygen. If 32.2 grams of mercury(II) oxide react to form 29.8 grams of mercury, how many grams of oxygen must simultaneously be formed

Answers

Explanation:

This is a decomposition reaction. Firstly, you will want to write the chemical equation out and balance it.

[tex]2Hg_2O->4Hg+O_2[/tex] (The -> is supposed to be an arrow, sorry!)

We see that there's only 1mol of Oxygen made in the products, we can do some simple math to solve for the amount of grams of Oxygen produced according to the amount of the reactant (Hg2O).

[tex]32.2gHg_2O*\frac{1molHg_2O}{417.18gHg_2O}*\frac{1molO_2}{2molHg_2O}*\frac{32gO_2}{1molO_2}[/tex]

I want to break this down, just in case:

The 417.18gHg2O is the molecular mass of the molecule (so I doubled Hg and added 16 to it to get this number).

As we can see in the chemical equation, 1mol Hg2O produces 2mol O because Oxygen is a diatomic molecule (so there will always be two of it when it's by itself).

And finally, in 1mol O2 there are 32g of O2.

** When you do math like this, always make sure that all of your units cancel out except for the units you're looking for. For example, here we're looking for the grams of Oxygen, so after everything else cancels out, we should only have grams O2.

So, 1.23gO2 should be your answer.

What is the empirical formula for a compound if 300.00 g of it is known to contain 82.46224 g of molybdenum, 45.741 g of chlorine and the rest is bromine

Answers

Answer:

MoClBr₂

Explanation:

First we calculate the mass of bromine in the compound:

300.00 g - (82.46224 g + 45.741 g) = 171.79676 g

Then we calculate the number of moles of each element, using their respective molar masses:

82.46224 g Mo ÷ 95.95 g/mol = 0.9594 mol Mo45.741 g Cl ÷ 35.45 g/mol = 1.290 mol Cl171.79676 g Br ÷79.9 g/mol = 2.150 mol Br

Now we divide those numbers of moles by the lowest number among them:

0.9594 mol Mo / 0.9594 = 11.290 mol Cl / 0.9594 = 1.34 ≅ 12.150 mol Br / 0.9594 = 2.24 ≅ 2

Meaning the empirical formula is MoClBr₂.

Suppose that you move from a Suppose that you move from a town near the ocean to a town in the mountains. To what atmospheric changes would your body need to adjust? town near the ocean to a town in the mountains. To what atmospheric changes would your body need to adjust?

Answers

Answer:

all I can say is town near the ocean atmospheric changes will be cooler, warm, sea breeze, and fresh healthy air. Then when it comes to the mountain lot of change firstly there's a dry air

Choose the correct statement. A) The cathode is the electrode where the oxidation takes place. B) The cathode is the electrode where the reduction takes place. C) Both oxidation and reduction may take place at the cathode, depending on the cell. D) The cathode is always positive

Answers

B. The cathode is the electrode where the reduction takes place took test

How many ozone molecules can each chlorine atom in the stratosphere destroy

Answers

Answer:

100,000

Explanation:

Chlorine can be prepared in the laboratory by the reaction of manganese dioxide with hydrochloric acid, HCl(aq) , as described by the chemical equation

MnO2(s)+4HCl(aq)⟶MnCl2(aq)+2H2O(l)+Cl2(g)

How much MnO2(s) should be added to excess HCl(aq) to obtain 185 mL Cl2(g) at 25 °C and 745 Torr ?

mass of MnO2:

Answers

Answer:

0.605 g

Explanation:

MnO₂(s) + 4HCl(aq) ⟶ MnCl₂(aq) + 2H₂O(l) + Cl₂(g)

First we calculate how many Cl₂ moles need to be produced, using the PV=nRT formula:

P = 745 Torr ⇒ 745 / 760 = 0.980 atmV = 185 mL ⇒ 185 / 1000 = 0.185 Ln = ?R = 0.082 atm·L·mol⁻¹·K⁻¹T = 25 °C ⇒ 25 + 273.16 = 298.16 K

Inputting the data:

0.980 atm * 0.185 L = n * 0.082 atm·L·mol⁻¹·K⁻¹ * 298.16 Kn = 0.00696 mol

Then we convert 0.00696 moles of Cl₂ to MnO₂ moles:

0.00696 mol Cl₂ * [tex]\frac{1molMnO_2}{1molCl_2}[/tex] = 0.00696 mol MnO₂

Finally we convert 0.00696 moles of MnO₂ to grams, using its molar mass:

0.00696 mol MnO₂ * 86.94 g/mol = 0.605 g

The Bohr model of the atom explains why emission spectra are discrete. It could also be used to explain the photoelectric effect. Which is a correct explaination of the photoelectric effect according to the model

Answers

Answer:

photoelectric effect, phenomenon in which electrically charged particles are released from or within a material when it absorbs electromagnetic radiation. The effect is often defined as the ejection of electrons from a metal plate when light falls on it.

Calcium chloride and magnesium sulfate are common drying agents. What type of solvent should be dried with calcium chloride, and what type with magnesium sulfate

Answers

Answer: The type of solvent that should be dried with calcium chloride is esters while magnesium sulfate is diethyl ether

Explanation:

Drying agents are mainly hygroscopic substances that has the ability to absorb water on exposure to the atmosphere but not enough to form solutions. They are used in desiccators. Examples of drying agents include:

--> CALCIUM CHLORIDE: This is a compound of calcium that is found in soil water and sea water. It is prepared by the action of dilute hydrochloric acid on calcium trioxocarbonate(IV). The anhydrous salt is used in drying a wide variety of solvent including esters.

--> MAGNESIUM SULFATE: This is a slightly acidic drying agent. It works well in solvents like diethyl ether. It is a fast drying agent because it comes as a fine powder with a large surface area.

Question 65 pts
(07.02 MC)

During a reaction, ΔH for reactants is −750 kJ/mol and ΔH for products is 920 kJ/mol. Which statement is correct about the reaction? (5 points)

Group of answer choices

It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

It is exothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

It is exothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

Answers

Answer:

It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed

Explanation:

A reaction may be endothermic or exothermic. In an endothermic reaction, energy is absorbed by the process while in an exothermic process energy is given out by the process.

Recall that the enthalpy change of a reaction = enthalpy of products - enthalpy of reactants

Hence, where the energy required to break bonds in the reactants is less than the energy released when the products are formed, the reaction is endothermic.

For an endothermic reaction, the enthalpy change of the reaction is positive.

In this case, enthalpy of reaction = 920 - (-750) = 1670 kJ/mol

During a reaction, ΔH for reactants is −750 kJ/mol and ΔH for products is 920 kJ/mol. Which statement is correct about the reaction? (5 points)

Group of answer choices

It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

It is exothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

It is exothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

Answers

Answer: The statement it is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed, is true.

Explanation:

A chemical reaction in which heat energy  is released is called an exothermic reaction. For exothermic reactions, the value of [tex]\Delta H[/tex] is always negative.

A chemical reaction in which heat energy is absorbed is called an endothermic reaction. For endothermic reaction, the value of [tex]\Delta H[/tex] is always positive.

In endothermic reactions, energy required for breaking the bonds between reactants is less than the energy when products are formed due to which the value of [tex]\Delta H[/tex] remains positive.

Thus, we can conclude that the statement it is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed, is true.

It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed. The correct option is B.

The above reaction is endothermic because more energy is produced when new bonds form in the products (H = 920 kJ/mol) than is required to break bonds in the reactants (H = -750 kJ/mol).

In an endothermic process, more energy than is generated during bond creation is absorbed from the environment to dissolve existing bonds. This causes a net absorption of energy, which cools the system.

The reaction takes more energy than it releases, proving its endothermic nature, as seen by the positive difference between the energy needed to dissolve bonds and the energy released during bond formation.

Thus, the correct option is B.

For more details regarding endothermic process, visit:

https://brainly.com/question/28909381

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Your question seems incomplete, the probable complete question is:

During a reaction, ΔH for reactants is −750 kJ/mol and ΔH for products is 920 kJ/mol. Which statement is correct about the reaction? (5 points)

Group of answer choices

A. It is endothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

B. It is endothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

C. It is exothermic because the energy required to break bonds in the reactants is less than the energy released when the products are formed.

D. It is exothermic because the energy required to break bonds in the reactants is greater than the energy released when the products are formed.

A sample of hydrogen nitrate or nitric acid, HNO 3 contains 18.8 x 1022 molecules.
How much mass of nitric acid are in the sample?

Answers

Answer:

19.7 g.

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to realize this problem can be solved by using a molecules-moles-mass relationship, starting with the given molecules, using the Avogadro's number and the molar mass of nitric acid (63.01 g/mol):

[tex]18.8x10^{22}molec*\frac{1mol}{6.022x10^{23}molec}* \frac{63.01g}{1mol} \\\\=19.7g[/tex]

Regards!

aromatic compounds aliphatic compounds

Answers

Answer:

I hoped it helps you fod blessed:)

calculate the molarity in a 0.550 m solution of NaCl in water. Assume that the solution density is 1.03g/mol

Answers

Answer:

M=0.549M

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to perform this calculation by firstly assuming we have 1 kg of water as the solvent so that we have 0.550 moles of NaCl as well. Moreover, we realize we have 1000 grams of water and the correct mass of the solution can be calculated by converting 0.550 moles of NaCl to grams by using its molar mass:

[tex]m_{solute}=0.550mol*\frac{58.44 g}{1mol}= 32.14g\\\\m_{solution}=1000g+32.14g=1032.14g[/tex]

And subsequently, the volume in liters by using the density and the correct conversion factor:

[tex]V_{solution}=1032.14g*\frac{1mL}{1.03g} *\frac{1L}{1000mL} =1.002L[/tex]

Finally, the molarity will be:

[tex]M=\frac{0.550mol}{1.002L} =0.549M[/tex]

Regards!

Consider the titration of 30 mL of 0.030 M NH3 with 0.025 M HCl. Calculate the pH after the following volumes of titrant have been added: a) 0 mL; b) 10 mL; c) 20 mL; d)35 mL; e) 36 mL; f) 37 mL.

Answers

Answer:

a)10.87

b)9.66

c)9.15

d)7.71

e) 5.56

f) 3.43

Explanation:

tep 1: Data given

Volume of 0.030 M NH3 solution = 30 mL = 0.030 L

Molarity of the HCl solution = 0.025 M

Step 2: Adding 0 mL of HCl

The reaction:    NH3 + H2O ⇔ NH4+ + OH-

The initial concentration:  

[NH3] = 0.030M    [NH4+] = 0M    [OH-] = OM

The concentration at the equilibrium:

[NH3] = 0.030 - XM

[NH4+] = [OH-] = XM

Kb = ([NH4+][OH-])/[NH3]

1.8*10^-5 = x² / 0.030-x

1.8*10^-5 = x² / 0.030

x = 7.35 * 10^-4 = [OH-]

pOH = -log [7.35 * 10^-4]

pOH = 3.13

pH = 14-3.13 = 10.87

Step 3: After adding 10 mL of HCl

The reaction:

NH3 + HCl ⇔ NH4+ + Cl-

NH3 + H3O+ ⇔ NH4+ + H2O

Calculate numbers of moles:

Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles

Moles HCl = 0.025 M * 0.010 L = 0.00025 moles

Moles NH4+ = 0 moles

Number of moles at the equilibrium:

Moles NH3 = 0.0009 -0.00025 =0.00065 moles

Moles HCl = 0

Moles NH4+ = 0.00025 moles

Concentration at the equilibrium:

[NH3]= 0.00065 moles / 0.040 L = 0.01625M

[NH4+] = 0.00625 M

pOH = pKb + log [NH4+]/[NH3]

pOH =  4.75 + log (0.00625/0.01625)

pOH = 4.34

pH = 9.66

Step 3: Adding 20 mL of HCl

Calculate numbers of moles:

Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles

Moles HCl = 0.025 M * 0.020 L = 0.00050 moles

Moles NH4+ = 0 moles

Number of moles at the equilibrium:

Moles NH3 = 0.0009 -0.00050 =0.00040 moles

Moles HCl = 0

Moles NH4+ = 0.00050 moles

Concentration at the equilibrium:

[NH3]= 0.00040 moles / 0.050 L = 0.008M

[NH4+] = 0.01 M

pOH = pKb + log [NH4+]/[NH3]

pOH =  4.75 + log (0.01/0.008)

pOH = 4.85

pH = 14 - 4.85 = 9.15

Step 4: Adding 35 mL of HCl

Calculate numbers of moles:

Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles

Moles HCl = 0.025 M * 0.035 L = 0.000875 moles

Moles NH4+ = 0 moles

Number of moles at the equilibrium:

Moles NH3 = 0.0009 -0.000875 =0.000025 moles

Moles HCl = 0

Moles NH4+ = 0.000875 moles

Concentration at the equilibrium:

[NH3]= 0.000025 moles / 0.065 L = 3.85*10^-4M

[NH4+] = 0.000875 M / 0.065 L = 0.0135 M

pOH = pKb + log [NH4+]/[NH3]

pOH =  4.75 + log (0.0135/3.85*10^-4)

pOH = 6.29

pH = 14 - 6.29 = 7.71

Step 5: adding 36 mL HCl

Calculate numbers of moles:

Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles

Moles HCl = 0.025 M * 0.036 L = 0.0009 moles

Moles NH4+ = 0 moles

Number of moles at the equilibrium:

Moles NH3 = 0.0009 -0.0009 =0 moles

Moles HCl = 0

Moles NH4+ = 0.0009 moles

[NH4+] = 0.0009 moles / 0.066 L = 0.0136 M

Kw = Ka * Kb

Ka = 10^-14 / 1.8*10^-5

Ka = 5.6 * 10^-10

Ka = [NH3][H3O+] / [NH4+]

Ka =5.6 * 10^-10 =  x² / 0.0136

x = 2.76 * 10^-6 = [H3O+]

pH = -log(2.76 * 10^-6)

pH = 5.56

Step 6: Adding 37 mL of HCl

Calculate numbers of moles:

Moles of NH3 = 0.030 M * 0.030 L = 0.0009 moles

Moles HCl = 0.025 M * 0.037 L = 0.000925 moles

Moles NH4+ = 0 moles

Number of moles at the equilibrium:

Moles NH3 = 0.0009 -0.000925 =0 moles

Moles HCl = 0.000025 moles

Concentration of HCl = 0.000025 moles / 0.067 L = 3.73 * 10^-4 M

pH = -log 3.73*10^-4= 3.43

The pH of the solution in the titration of 30 mL of 0.030 M NH₃ with 0.025 M HCl, is:

a) pH = 10.86

b) pH = 9.66

c) pH = 9.15

d) pH = 7.70

e) pH = 5.56

f) pH = 3.43          

     

Calculating the pH a) 0 mL        

Initially, the pH of the solution is given by the dissociation of NH₃ in water.  

NH₃ + H₂O ⇄ NH₄⁺ + OH⁻     (1)

The constant of the above reaction is:

[tex] Kb = \frac{[NH_{4}^{+}][OH^{-}]}{[NH_{3}]} = 1.76\cdot 10^{-5} [/tex]   (2)

At the equilibrium, we have:  

   NH₃    +    H₂O   ⇄   NH₄⁺    +    OH⁻     (3)  

0.030 M - x                      x               x

[tex] 1.76\cdot 10^{-5}*(0.030 - x) - x^{2} = 0 [/tex]

After solving for x and taking the positive value:

x = 7.18x10⁻⁴ = [OH⁻]  

Now, we can calculate the pH of the solution as follows:

[tex] pH = 14 - pOH = 14 + log(7.18\cdot 10^{-4}) = 10.86 [/tex]

Hence, the initial pH is 10.86.

   

b) 10 mL

After the addition of HCl, the following reaction takes place:

NH₃ + HCl ⇄ NH₄⁺ + Cl⁻  (4)  

We can calculate the pH of the solution from the equilibrium reaction (3).            

[tex] 1.76\cdot 10^{-5}(Cb - x) - (Ca + x)*x = 0 [/tex] (5)  

Finding the number of moles of NH₃ and NH₄⁺

The number of moles of NH₃ (nb) and NH₄⁺ (na) are given by:

[tex] n_{b} = n_{i} - n_{HCl} [/tex]     (6)

[tex] n_{b} = 0.030 mol/L*0.030 L - 0.025 mol/L*0.010 L = 6.5\cdot 10^{-4} moles [/tex]          

[tex] n_{a} = n_{HCl} [/tex]   (7)

[tex] n_{a} = 0.025 mol/L*0.010 L = 2.5 \cdot 10^{-4} moles [/tex]

Calculating the concentrations of NH₃ and NH₄⁺

The concentrations are given by:

[tex] Cb = \frac{6.5\cdot 10^{-4} moles}{(0.030 L + 0.010 L)} = 0.0163 M [/tex]   (8)

[tex] Ca = \frac{2.5 \cdot 10^{-4} mole}{(0.030 L + 0.010 L)} = 6.25 \cdot 10^{-3} M [/tex]      (9)

Calculating the pH

After entering the values of Ca and Cb into equation (5) and solving for x, we have:  

[tex] 1.76\cdot 10^{-5}(0.0163 - x) - (6.25 \cdot 10^{-3} + x)*x = 0 [/tex]

x = 4.54x10⁻⁵ = [OH⁻]

Then, the pH is:

[tex] pH = 14 + log(4.54\cdot 10^{-5}) = 9.66 [/tex]

Hence, the pH is 9.66.

c) 20 mL  

We can find the pH of the solution from the reaction of equilibrium (3).

 Calculating the concentrations of NH₃ and NH₄⁺

The concentrations are (eq 8 and 9):

[tex] Cb = \frac{0.030 mol/L*0.030 L - 0.025 mol/L*0.020 L}{(0.030 L + 0.020 L)} = 8.0\cdot 10^{-3} M [/tex]    

[tex] Ca = \frac{0.025 mol/L*0.020 L}{(0.030 L + 0.020 L)} = 0.01 M [/tex]    

Calculating the pH  

After solving the equation (5) for x, we have:

[tex] 1.76\cdot 10^{-5}(8.0\cdot 10^{-3} - x) - (0.01 + x)*x = 0 [/tex]

x = 1.40x10⁻⁵ = [OH⁻]

Then, the pH is:  

[tex] pH = 14 + log(1.40\cdot 10^{-5}) = 9.15 [/tex]

So, the pH is 9.15.

d) 35 mL

We can find the pH of the solution from reaction (3).

  Calculating the concentrations of NH₃ and NH₄⁺

[tex] Cb = \frac{0.030 mol/L*0.030 L - 0.025 mol/L*0.035 L}{(0.030 L + 0.035 L)} = 3.85\cdot 10^{-4} M [/tex]      

[tex] Ca = \frac{0.025 mol/L*0.035 L}{(0.030 L + 0.035 L)} = 0.0135 M [/tex]      

Calculating the pH  

After solving the equation (5) for x, we have:

[tex] 1.76\cdot 10^{-5}(3.85\cdot 10^{-4} - x) - (0.0135 + x)*x = 0 [/tex]

x = 5.013x10⁻⁷ = [OH⁻]      

Then, the pH is:  

[tex] pH = 14 + log(5.013\cdot 10^{-7}) = 7.70 [/tex]  

So, the pH is 7.70.

e) 36 mL  Finding the number of moles of NH₃ and NH₄⁺

[tex] n_{b} = 0.030 mol/L*0.030 L - 0.025 mol/L*0.036 L = 0 [/tex]    

[tex] n_{a} = 0.025 mol/L*0.036 L = 9.0 \cdot 10^{-4} moles [/tex]

                                   

Since all the NH₃ reacts with the HCl added, the pH of the solution is given by the dissociation reaction of the NH₄⁺ produced in water.

At the equilibrium, we have:                

NH₄⁺    +    H₂O   ⇄   NH₃    +    H₃O⁺

Ca - x                             x               x

[tex] Ka = \frac{x^{2}}{Ca - x} [/tex]  

[tex] Ka(Ca - x) - x^{2} = 0 [/tex]   (10)          

 

Calculating the acid constant of NH₄⁺

We can find the acid constant as follows:

[tex] Kw = Ka*Kb [/tex]

Where Kw is the constant of water = 10⁻¹⁴

[tex] Ka = \frac{1\cdot 10^{-14}}{1.76 \cdot 10^{-5}} = 5.68 \cdot 10^{-10} [/tex]  

Calculating the pH  

The concentration of NH₄⁺ is:

[tex] Ca = \frac{9.0 \cdot 10^{-4} moles}{(0.030 L + 0.036 L)} = 0.0136 M [/tex]      

After solving the equation (10) for x, we have:

x = 2.78x10⁻⁶ = [H₃O⁺]

Then, the pH is:  

[tex] pH = -log(H_{3}O^{+}) = -log(2.78\cdot 10^{-6}) = 5.56 [/tex]

Hence, the pH is 5.56.

f) 37 mL

Now, the pH is given by the concentration of HCl that remain in solution after reacting with NH₃ (HCl is in excess).

Calculating the concentration of HCl  

[tex] C_{HCl} = \frac{0.025 mol/L*0.037 L - 0.030 mol/L*0.030 L}{(0.030 L + 0.037 L)} = 3.73 \cdot 10^{-4} M = [H_{3}O^{+}] [/tex]      

Calculating the pH  

[tex] pH = -log(H_{3}O^{+}) = -log(3.73 \cdot 10^{-4}) = 3.43 [/tex]

Therefore, the pH is 3.43.

   

Find more about pH here:

brainly.com/question/491373

 

I hope it helps you!  

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