Calculate the pH at 25°C of a 0.49M solution of ethylammonium bromide C2H5NH3Br . Note that ethylamine C2H5NH2 is a weak base with a pKb of 3.19 . Round your answer to 1 decimal place.

Answers

Answer 1
Answer:

pH = 12.7

Step-by-step Explanation:

The first step is to write the chemical equation for the dissociation of ethylammonium bromide:

C2H5NH3Br + H2O ⇌ C2H5NH2 + H3O+ + Br-

We can then write the equilibrium constant expression, Kc:

Kc = [C2H5NH2][H3O+][Br-] / [C2H5NH3Br][H2O]

At equilibrium, the concentration of water is essentially constant, so we can simplify the expression:

Kc = [C2H5NH2][H3O+][Br-] / [C2H5NH3Br]

We can also write the expression for the base dissociation constant, Kb:

Kb = [C2H5NH2][OH-] / [C2H5NH3+]

The relationship between Kb and Kc is:

Kb x Ka = Kw

where Ka is the acid dissociation constant for water (1.0 x 10^-14 at 25°C) and Kw is the ion product constant for water (also 1.0 x 10^-14 at 25°C).

We can rearrange this equation to solve for Kb:

Kb = Kw / Ka = 1.0 x 10^-14 / 1.0 x 10^-14 = 1.0

Since Kb is defined as [C2H5NH2][OH-] / [C2H5NH3+], we can solve for [OH-]:

Kb = [C2H5NH2][OH-] / [C2H5NH3+]

[OH-] = Kb x [C2H5NH3+] / [C2H5NH2]

We can use the relation between [H3O+] and [OH-]:

Kw = [H3O+][OH-] = 1.0 x 10^-14

[H3O+] = Kw / [OH-]

[H3O+] = Kw / (Kb x [C2H5NH3+] / [C2H5NH2])

[H3O+] = (1.0 x 10^-14) / (1.0 x [C2H5NH3+] / [C2H5NH2])

We can then substitute in the concentration of ethylammonium bromide:

[H3O+] = (1.0 x 10^-14) / (1.0 x 0.49 / 1.0)

[H3O+] = 2.04 x 10^-13 M

The pH is defined as the negative logarithm of the concentration of hydronium ions:

pH = -log[H3O+]

pH = -log(2.04 x 10^-13)

pH = 12.7

Therefore, the pH of a 0.49 M solution of ethylammonium bromide at 25°C is 12.7 (rounded to 1 decimal place).

Related Questions

Which type of reaction will occur when equal volumes of 0.1 M HCl and 0.1 M NaOH are mixed 1. Neutralization2. Ionization3. Electrolysis4. Hydrolysis

Answers

When 0.1 M HCl and 0.1 M NaOH are combined in equal amounts, a process known as neutralisation will take place, producing water and a salt as byproducts.

In a neutralisation process, which takes place when an acid and a base are mixed, the H+ ions from the acid and the OH- ions from the base combine to generate water molecules. In this instance, when 0.1 M HCl and 0.1 M NaOH are combined in equal parts, they will react 1:1 to form water and the salt NaCl. The final mixture's pH will be 7, which is neutral. This is due to the fact that only water and salt are left after the reaction, totally consuming the H+ and OH- ions. A lot of industries, including industry, agriculture, and medicine, utilise this kind of reaction.

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If a second order reaction has an initial concentration of 2.91 M and a concentration of 1.38 M after 189 seconds, what is the rate constant k for the reaction? Your answer should have three significant figures (use scientific notation).

Answers

The rate constant k for the reaction is 3.84 x 10⁻³ s⁻¹.

What is the rate constant of the reaction?

The second-order rate law is expressed as:

rate = k [A]²

where;

k is the rate constant and [A] is the concentration of the reactant.

The integrated rate law for a second-order reaction is:

1/[A]t - 1/[A]0 = kt

where;

[A]t is the concentration of the reactant at time t, [A]0 is the initial concentration of the reactant, andk is the rate constant.

Substituting the given values into the equation, we get:

1/1.38 - 1/2.91 = k(189)

0.7246 = k(189)

k = 0.7246/189

k = 3.84 x 10⁻³ s⁻¹ (to three significant figures in scientific notation)

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If a neutral object lost 2 electrons, what would it's charge be? would it be positive?

Answers

If a neutral object lost two electrons, it would have a positive charge.

Electrons are negatively charged subatomic particles that orbit around the positively charged nucleus in an atom. When an atom loses electrons, it becomes positively charged because the total negative charge from the electrons is reduced. The number of electrons in an atom determines its overall charge, and when electrons are lost, the atom's charge becomes more positive.

In this case, the neutral object would have a net positive charge equal to the number of protons in its nucleus, since it has lost two negatively charged electrons. Thus, the object would be positively charged after losing two electrons.

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what is oxygen friend and why would they be friend with oxygen

Answers

Answer:

oxygen friend

Explanation:

It is generally believed that the Earth's atmosphere did not contain oxygen until around 2500 million years ago (Mya) when oxygen-evolving photosynthetic bacteria arose. At around 800–500 Mya, the oxygen concentration increased sharply to reach the 21% we have today. So, it seems highly likely that life arose as anaerobic organisms, which then evolved to tolerate oxygen and finally, to use it as a terminal acceptor for the energy-producing oxidative processes in the respiration of aerobic bacteria and mitochondria in eukaryotic cells. The respiratory processes employed by typical aerobic organisms today have a wide range of mechanisms to deal with the troublesome side effects of living with a high oxygen concentration.

30 POINTS HELP FAST

A scientist is using potassium-40, which is a radioactive isotope of potassium, to find the absolute age of a fossil by radiometric dating. The scientist determines that about three-fourths of the original potassium-40 atoms in the fossil now remain in the fossil. What additional information is necessary for the scientist to determine the absolute age of the fossil? Question 2 options: the half-life of potassium-40 the identity of an index fossil the atomic mass of potassium-40 the total mass of the fossil "choose a b c or d"

Answers

The additional information necessary is: "the half-life of potassium-40." for the scientist to determine the absolute age of the fossil.

What is Radiometric Dating?

Radiometric dating is a method used to determine the absolute age of rocks and fossils based on the decay of radioactive isotopes. The rate of decay of a radioactive isotope is measured in terms of its half-life, which is the time it takes for half of the original parent atoms to decay into daughter atoms.

In this case, the scientist needs to know the half-life of potassium-40 in order to calculate the absolute age of the fossil. By knowing the half-life of potassium-40, the scientist can determine how much time has elapsed since the fossil was formed based on the proportion of parent and daughter atoms present in the fossil.

Therefore, the correct answer is: the half-life of potassium-40.

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How can scientists
use ionization
energy to learn more
about elements that
have not been
discovered yet?

Answers

The ionization energy, or ionization potential, is the energy required to completely remove an electron from a gaseous atom or ion. The closer and more tightly bound an electron is to the nucleus, the more difficult it will be to remove, and the higher its ionization energy will be.

based on what you understand about the density of co2, what do you suspect happened to the normal air after the co2 was released from the lake? group of answer choices the normal air was displaced by the heavier co2 the co2 was displaced by the heavier normal air the normal air stayed where it was originally

Answers

After the CO₂ was released from the lake, the normal air was displaced by the heavier CO₂. This option is correct.

CO₂, or carbon dioxide, is a gas that is slightly heavier than air. The density of CO₂  is approximately 1.98 kg/m³, whereas the density of air is around 1.2 kg/m³.

This means that CO₂  is denser than air and has a greater mass per unit volume. When CO₂ is released from a lake, it will displace the normal air in the surrounding area because of its higher density.

The normal air stayed where it was originally, and it did not displace the heavier CO₂  since CO₂ is heavier than air.

So, the correct option is "the normal air was displaced by the heavier CO₂ ."

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how many chirality centers are there in an aldohexose?a. 3b. 4c. 5d. 6

Answers

There are 4 chirality centers in an aldohexose. The correct answer is option b.

Aldohexoses are six-carbon monosaccharides with a carbonyl functional group (aldehyde group) and five other carbon atoms, each of which is associated with an alcohol functional group in their straight-chain form. The carbonyl carbon, which is referred to as the anomeric carbon, determines the stereochemistry and the cyclic form of aldohexoses.

Chirality centers are carbon atoms that have four distinct substituents bonded to them, resulting in the ability to exist as stereoisomers. These stereoisomers are mirror images of each other and cannot be superimposed upon each other.Therefore, it is important to count the number of chirality centers present in the aldohexose structure.

There are four chirality centers in aldohexose, which are present at carbon atoms 2, 3, 4, and 5.

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Atoms can't be broken into smaller pieces and still retain the properties of that element. True or False?​

Answers

true

Explanation:

Atoms cannot be subdivided, created, or destroyed. Atoms of different elements can combine in simple whole number ratios to form chemical compounds.

Answer:

true

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Determine the overall reaction and its standard cell potential at 25 �C for the reaction involving the galvanic cell made from a half-cell consisting of a silver electrode in 1 M silver nitrate solution and a half-cell consisting of a zinc electrode in 1 M zinc nitrate. Is the reaction spontaneous at standard conditions?

Answers

The reaction involved in the galvanic cell made from a half-cell consisting of a silver electrode in 1 M silver nitrate solution and a half-cell consisting of a zinc electrode in 1 M zinc nitrate is given as follows:2 Ag(s) + Zn2+ (aq) → Zn(s) + 2 Ag+ (aq)The standard cell potential at 25 °C for the given reaction can be determined using the following formula: E°cell

= E°cathode - E°anodeHere, the E°cathode and E°anode represent the standard reduction potentials of cathode and anode respectively. The values of these standard reduction potentials can be obtained from the standard reduction

potentials table.Using the values of standard reduction potentials from the table, we have:E°cell = E°Ag+ / Ag - E°Zn2+ / Zn= +0.80 V - (-0.76 V)= +1.56 VThe reaction is spontaneous at standard conditions because the calculated standard

cell potential is positive (+1.56 V). Therefore, the reaction will proceed spontaneously from left to right direction.The bolded non-consecutive keywords are: spontaneous, standard conditions, galvanic cell, reduction potentials.

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what is the mass of potassium nitrate that will dissolve in 25g of water at 20° C?

a. 0.3g
b. 7.5g
c. 4g
d. 25g
e. 30g

Answers

Answer:

7.5g is the mass of potassium nitrate that will dissolve in 25g of water at 20° C?

The answer is 4g. At 20° C, the solubility of potassium nitrate in water is 3.7 g per 100 g of water, which means that about 4 g of potassium nitrate will dissolve in 25 g of water.

What is solubility?

Solubility is the ability of a substance to dissolve in a liquid or other solvent. It is a measure of the maximum amount of substance that can be dissolved in a given amount of solvent. Solubility can be affected by factors such as temperature, pressure, and the type of solvent used. In general, the more soluble a substance is, the more easily it will dissolve. Solubility is an important factor in the formulation of many products, such as pharmaceuticals, cosmetics, and food products. It is also used in the manufacture of detergents, paints, and inks. Solubility can be determined experimentally, by measuring the amount of a substance that can be dissolved in a given volume of solvent. The solubility of a substance can also be calculated using equations that take into account the temperature and pressure of the system. Understanding solubility is important for determining the effectiveness of drugs, the shelf life of food products, and the environmental impact of certain chemicals.

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Look at the transition you drew for Element Y on the earlier slide. On a piece of paper, write out your calculation to find the energy of the photon emitted. Calculate the wavelength (in nm) of the photon emitted for Element Y. Calculate the frequency of the photon emitted for Element Y.

Answers

To calculate the energy of the photon emitted for Element Y, you can use the following equation:
E = hc/λ
where h is Planck's constant (6.626 x 10-34 Js), c is the speed of light (3 x 108 m/s), and λ is the wavelength of the photon (in meters).

To calculate the wavelength of the photon emitted for Element Y, you can use the following equation:
λ = hc/E
where h is Planck's constant (6.626 x 10-34 Js), c is the speed of light (3 x 108 m/s), and E is the energy of the photon (in Joules)

To calculate the frequency of the photon emitted for Element Y, you can use the following equation:
f = c/λ
where c is the speed of light (3 x 108 m/s), and λ is the wavelength of the photon (in meters).

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A sample of iron wire reacts with oxygen to form iron(III) oxide. If 3.58g of the wire yields 5.00g of the iron(III) oxide, calculate the percentage purity of the iron.

How do I do this question? Thanks!

Answers

Answer:

We can start by finding the amount of iron used in the reaction:

Iron (Fe) is the limiting reagent since it is completely used up in the reaction.

Molar mass of Fe = 55.845 g/mol

Moles of Fe = mass / molar mass = 3.58 g / 55.845 g/mol = 0.064 moles

The balanced chemical equation for the reaction is:

4Fe + 3O2 → 2Fe2O3

From the equation, we can see that 4 moles of Fe react with 3 moles of O2 to produce 2 moles of Fe2O3.

Moles of Fe2O3 produced = mass / molar mass = 5.00 g / (2 x 159.69 g/mol) = 0.01567 moles

Since 4 moles of Fe reacts with 2 moles of Fe2O3, the theoretical yield of Fe2O3 from 0.064 moles of Fe is:

Theoretical yield of Fe2O3 = (0.064 mol Fe) x (2 mol Fe2O3 / 4 mol Fe) x (2 x 159.69 g/mol Fe2O3) = 12.746 g

The percentage purity of iron is:

Percentage purity = (actual yield / theoretical yield) x 100%

Percentage purity = (5.00 g / 12.746 g) x 100% = 39.26% (rounded to two decimal places)

Therefore, the iron wire is 39.26% pure.

A triglyceride that loses a fatty acid is called a ____.

Answers

A triglyceride that loses a fatty acid is called a diglyceride or diacylglycerol. This occurs when the triglyceride molecule undergoes a process called hydrolysis.

Hydrolysis breaks the ester bond between one of the fatty acids and the glycerol backbone, releasing a free fatty acid and forming a diglyceride.

This process is essential in the metabolism and digestion of fats in our bodies, as it allows the body to break down complex fat molecules into simpler components that can be absorbed and utilized for energy or other biological functions.

In addition, diglycerides play important roles in cell signaling and membrane structure, serving as essential building blocks for various cellular components.

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which type of radioactive emission is considered the most dangerous?

Answers

Gamma radiation are the most dangerous type of radioactive emission as they are the most energetic and can penetrate the human body and damage cells. Alpha particles can cause both short-term and long-term health effects, such as cancer.

Out of alpha, beta and gamma radiation, the most dangerous type of radioactive emission is gamma radiation. This is because gamma rays are penetrating, high-energy rays that can easily penetrate the human body and cause damage to cells and DNA. Gamma radiation, unlike alpha and beta radiation, can penetrate the body's skin and tissue, exposing internal organs to radiation. When gamma rays are absorbed by living cells, they can ionize atoms and molecules, causing damage to DNA and other genetic material in the cell. High doses of gamma radiation can cause immediate symptoms such as radiation sickness and even death. Gamma radiation is frequently emitted by unstable radioactive atoms like uranium and plutonium, which are used in nuclear power plants and nuclear weapons. Workers in these industries and anyone exposed to a nuclear accident or bomb are at a higher risk of exposure to gamma radiation. Alpha radiation is a type of ionizing radiation that is emitted by certain types of unstable atoms. Alpha particles are relatively large and have a short range, so they can be stopped by a sheet of paper or the outer layer of human skin. Beta radiation is a type of ionizing radiation that is emitted by certain types of unstable atoms. Beta particles are much smaller than alpha particles, and they can travel through the human body farther than alpha particles. Gamma radiation is a type of electromagnetic radiation, similar to X-rays, but with higher energy and frequency. Gamma rays are produced by the decay of unstable atomic nuclei and are highly penetrating, meaning they can easily pass through solid objects.

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a sample of helium gas has a volume of 620. ml at a temperature of 500. k. if we decrease the temperature to 100. k while keeping the pressure constant, what will the new volume be?

Answers

The new volume of the helium gas sample will be  124 ml. This is due to the fact that when the temperature decreases while the pressure remains constant, the volume of a gas will increase.


According to Charles’s law, the volume of a given gas at a constant pressure is directly proportional to its absolute temperature. Therefore, a decrease in temperature, while holding constant the pressure of the helium gas, would result in a decrease in volume.

A constant pressure is the one under which the pressure of a substance remains unchanged as the temperature and/or volume of the substance change. Charles's law may be used to explain the properties of gases, particularly with constant pressure since it states that the volume of a given mass of a gas is directly proportional to its absolute temperature, provided that its pressure remains constant. It's written as:V1/T1 = V2/T2; whereV1 = 620 ml; T1 = 500K; T2 = 100KLet's put the values in the formula given above. The [tex][tex]620/T1 = V2/100V2 = 62,000/500V2 = 124 ml[/tex].[/tex]Therefore, the new volume of helium gas at a temperature of 100K would be 124 ml.

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A balloon has a volume of 800.0 mL on a day when the temperature is 308 K. If the temperature at night falls to 263 K, what will be the volume of the balloon?

Answers

The volume of the balloon at a temperature of 263 K will be approximately 683.1 mL.

What will be the volume of the balloon?

Charles's Law states that the volume of a gas is directly proportional to its absolute temperature at constant pressure.

This means that the volume and temperature of a gas are directly proportional to each other as long as the pressure is constant.

It is expressed as:

V₁/T₁ = V₂/T₂

Where V₁  and T₁ are the initial volume and temperature, V₂ is the final volume, and T₂ is the final temperature.

Given that:

V₁ = 800.0 mLT₁ = 308 KT₂ = 263 K

Solving for V₂, we get:

V₂ = V₁T₂ / T₁

V₂ = ( 800 × 263 ) / 308

V₂ = 210400 / 308

V₂ = 683.1 mL

Therefore, the volume is  683.1 mL.

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ksp for calcium carbonate is 3.0 × 10–9. if you mix together 100 ml of 0.010 m calcium chloride with 100 ml of 1.0 × 10–5 m solution of potassium carbonate, will a precipitate form?

Answers

Yes, a precipitate will form if you mix together 100 mL of 0.010 m calcium chloride with 100 mL of 1.0 x 10-5 m solution of potassium carbonate.

This is because the Ksp (solubility product constant) for calcium carbonate is 3.0 x 10-9. This means that when the concentrations of calcium and carbonate ions become too high, they will no longer be soluble and a precipitate will form. To understand this better, consider the following reaction:

CaCl2 (aq) + CO3 (aq) --> CaCO3 (s) + 2Cl- (aq).

This equation shows that calcium ions (Ca2+) from the calcium chloride solution will react with carbonate ions (CO3-) from the potassium carbonate solution to form solid calcium carbonate (CaCO3) and chloride ions (Cl-). When the concentrations of calcium and carbonate ions in the solution become too high, a precipitate will form as calcium carbonate.

The Ksp for calcium carbonate is a measure of how much calcium and carbonate ions can be present in the solution before a precipitate forms. This means that if the concentrations of the calcium and carbonate ions become greater than 3.0 x 10-9 molar, a precipitate will form. The concentrations of the calcium and carbonate ions in the given solutions are 0.010 m and 1.0 x 10-5 m respectively, both of which are greater than the Ksp of calcium carbonate and hence a precipitate will form.

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what terms complete this analogy:_ is too strong base as _ is to weak base?
A. Partial dissociation; Full dissociation
B. Full dissociation; Partial dissociation
C. Arrhenius; Bronsted Lowry
D. Weak electrolyte, Strong electrolyte

Answers

The correct answer is D.

A strong base is a substance that completely dissociates into its ions in water, producing a high concentration of hydroxide ions (OH-). Similarly, a weak base is a substance that only partially dissociates into its ions in water, producing a low concentration of hydroxide ions (OH-).

The term that completes the analogy is "Weak electrolyte", which is a substance that only partially dissociates into its ions in water and conducts electricity poorly. A strong electrolyte, on the other hand, is a substance that completely dissociates into its ions in water and conducts electricity well.

Therefore, the analogy can be completed as follows:

"Strong base is to weak base as strong electrolyte is to weak electrolyte."

I hope it helped you :)

What is the apparent brightness of a star?

Answers

I suppose how dazzling the star appear to a meter here on Earth. On the opposing hand, a star's brightness refers to how much light is emitted from its surface.

What is a star's apparent and absolute brightness?

absolute magnitude: the amount of brightness a star would have at a given distance. The brightness of a galaxy seen from the Earth is known as its apparent magnitude.

What are apparent and actual brightness?

Because of this, the sample's name, "apparent" brightness, refers to the brightness of things as seen from our vantage point rather than their actual or "true" brightness. Astronomers must measure a star's luminosity, or absolute brightness, in to understand the precise amount of heat it emits.

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Why were dirigibles considered to be the wave of the future in travel?

Answers

Answer:

jkhihjijhbjbjk

In the early 20th century, dirigibles were considered to be the wave of the future in travel because they were capable of traveling long distances at high altitudes, which made them suitable for long-distance travel and exploration. They were also seen as a safer and more comfortable alternative to airplanes, which were still in their early stages of development. Additionally, dirigibles were capable of carrying large amounts of cargo and passengers, which made them attractive for commercial purposes. However, the development of airplanes and the Hindenburg disaster in 1937 led to a decline in the use of dirigibles for travel.

What volume of air is present in human lungs if 0.19 mol are present at 312K and 1.3 atm?
A. 0.066
B. 2.9L
C. 5.5L
D.3.7L

Answers

Answer:

The answer is D - 3.7 L.

2) What is the volume of 8. 9 * 10 ^ 25 atoms of neon gas?

Answers

The volume of Neon gas is 326.5 L in 8. 9 * 10 ^ 25 atoms as per the ideal gas law equation.

The given atoms of Neon gas =  8. 9 * 10 ^ 25

To calculate the volume of any gas we should use the ideal gas law equation.

PV = nRT

Here R is the universal gas constant.

To calculate the volume, we need to calculate the number of moles of neon gas. Avogadro's number is used to convert the number of atoms to moles:

1 mole of neon gas = 6.022 * 10^23 atoms of neon gas

The total number of moles of neon gas is:

8.9 * 10^25 atoms / 6.022 * 10^23 atoms/mol = 14.79 mol

Let's assume the temperature is 25°C  = 298 K

The pressure = 1 atm.

The value of R =  0.08206 Latm/(molK).

PV = nRT

V = (NRT) / P

V = (14.79 mol * 0.08206 Latm/(molK) * 298 K) / 1 atm

V = 326.5 L

Therefore we can conclude that the volume of Neon gas is 326.5 L.

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The epithelial cells of the proximal convoluted tubule are adapted for reabsorption by: a. having thin walls. b. having rugae folds that increase surface area. c. secreting enzymes that activate absorption of substances. d. having microscopic projections called microvilli.

Answers

Answer: d. possessing tiny protrusions known as microvilli. The proximal convoluted tubule's epithelial cells have microvilli on their surface, which increases their surface area and improves.

the efficiency of reabsorption of chemicals from the filtrate back into the circulation. The cells do not release enzymes to promote absorption, and the rugae folds and thin walls are not adaptations for reabsorption. The proximal convoluted tubule's epithelial cells are in charge of reabsorbing vital components from the glomerular filtrate, including glucose, amino acids, and electrolytes. Many microvilli, which are tiny finger-like projections on the surface of the cell that enhance the surface area accessible for reabsorption, are present in the cells, which enable them to perform this role. This modification makes it possible for chemicals to be reabsorbted more effectively as they move through the tubule. The rugae folds and thin walls, on the other hand, have little impact on reabsorption in the proximal convoluted tubule. In this region of the nephron, reabsorption likewise does not include enzyme secretion.

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If a flexible hot air balloon has a volume of 350,000 L of air at 40 degrees C and 1 atm,
how many moles of air are in the balloon?

How do I solve this?

Answers

If a flexible hot air balloon has a volume of 350,000 L of air at 40 degrees C and 1 atm, 13636 moles of air are in the balloon . This is taken out by ideal gas law.

What is ideal gas law?

The ideal gas law, also known as the general gas equation, is the state equation for a hypothetical ideal gas. Although it has several limitations, it is a good approximation of the behavior of many gases under many conditions. Benoît Paul Émile Clapeyron proposed it in 1834 as a combination of empirical Boyle's law, Charles' law, Avogadro's law, and Gay Lussac's law.

using the equation P × V= n × R × T

P = Pressure = 1 atm

V = Volume = 350000 L

n = moles

R = 0.082 L.atm.K⁻¹.mol⁻¹

solving for n ,

moles n =   13636 moles

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Which catastrophic events can be started due to an earthquake? Select all that apply.

A- landslide

B- tsunami

C- tornado

D- hurricane

Answers

Answer: A and B

Explanation:

i took the test hope it will help --_o

A culture of E. coli growing in a medium containing 15NH4Cl15NH4Cl is switched to a medium containing 14NH4Cl14NH4Cl for three generations (an eightfold increase in population). What is the molar ratio of hybrid DNA ( 15N14−N15N−14N ) to light DNA ( 14N14−N14N−14N ) at this point?

Answers

The switch from ¹⁵NH₄Cl to ¹⁴NH₄Cl for three generations (an eightfold increase in population) in a culture of E. coli will result in a molar ratio of hybrid DNA ( ¹⁵N-¹⁴N) to light DNA (¹⁴N-¹⁴N) of 3:1.

The reason for this is that during the first replication cycle in the ¹⁴NH₄Cl-containing medium, the hybrid DNA strands will split, and half of the daughter DNA molecules will contain a heavy ¹⁵N nitrogen atom and a light ¹⁴N nitrogen atom.
The remaining daughter DNA molecules will have two light ¹⁴N nitrogen atoms, resulting in a molar ratio of 1:1.

During the next replication cycle, the hybrid DNA strands, in the light ¹⁴NH₄Cl-containing medium, will split once again, and the resulting daughter DNA molecules will either have one heavy and one light nitrogen atom or two light nitrogen atoms. Thus there will be 2 hybrid DNA and 2 pure DNA with light nitrogen, resulting in the same molar ratio of 1:1.

In the next cycle, the 2 molecules with light nitrogen give 4 pure molecules and 2 more pure molecules come from the strand of each hybrid molecule. Thus there is a total of 6 pure molecules. The heavy nitrogen strand of the hybrids gives rise to 2 more hybrids. So, there is a total of 2 hybrids and 6 light nitrogen molecules, resulting in a molar ratio of 3:2.


Therefore, the molar ratio of hybrid DNA ( ¹⁵N-¹⁴N) to light DNA (¹⁴N-¹⁴N) of 3:1.

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Select all of the following molecules that contain stereocenters.-alkene with H wedges and CH3 dash-both 1,2-dimethylcyclohexane-cyclohexane with wedge-dash methyl

Answers

The stereocenter-containing molecule is:

1,2-dimethylcyclohexane (both carbons at position 1 and 2 are stereocenters as they have four distinct substituents connected to them)

(both carbons at position 1 and 2 are stereocenters as they have four different substituents attached to them)

Stereocenters are absent from the other compounds that were listed. Because the double bond does not include any substituents that are distinct from one another, the alkene with H wedges and the CH3 dash does not have stereocenters. As all of the carbons in cyclohexane are symmetric and do not have four separate substituents connected to them, the cyclohexane with wedge-dash methyl likewise lacks stereocenters., the only molecule in the list that contains stereocenters is 1,2-dimethylcyclohexane.

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one difference between first- and second-order reactions is that ____ . a) whereas the half-life of a second-order reaction does depend on it. the rate of a first-order reaction does not depend on reactant concentrations whereas b) th e rate of a second-order reaction does depend on reactant concentrations. the half-life of a first-order reaction depends on the initial concentration whereas the half-life of a second-order reaction does not depend on it. c) the rate of a first-order reaction depends on reactant concentrations whereas the rate of a second-order reaction does not depend on reactant concentrations

Answers

The correct option is C .The difference between first- and second-order reactions is that the rate of a first-order reaction depends on reactant concentrations, whereas the rate of a second-order reaction does not depend on reactant concentrations.

The order of a reaction is determined by the power to which the concentration of each reactant is raised in the rate law. A first-order reaction is a chemical reaction in which the rate of reaction is proportional to the concentration of only one reactant (unimolecular reaction), and the rate equation can be expressed in terms of the concentration of the reactant as d[A] /dt = - k[A], where [A] is the concentration of the reactant and k is the rate constant. Second-order reactions are chemical reactions in which the rate of reaction is proportional to the square of the concentration of one reactant, or proportional to the product of the concentrations of two reactants (bimolecular reaction).

However, The rate of a first-order reaction does not depend on the initial concentration of the reactant, whereas the half-life of a first-order reaction depends on the initial concentration. On the other hand, the rate of a second-order reaction does depend on reactant concentrations, whereas the half-life of a second-order reaction does not depend on the initial concentration.

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Which of the following indicates a spontaneous reaction under standard conditions? A) K = 8.6 x 10⁻². B) K = 7.9 x 10⁻⁸. C) K = 2.2 x 10².

Answers

A spontaneous reaction under standard conditions is indicated by the value of K being greater than 1. Thus, the answer to the given question is option C, K = 2.2 x 10².

Standard conditions- Standard conditions are a set of environmental conditions that are considered to be the standard conditions for conducting an experiment. They serve as a reference point to compare the effects of varying environmental conditions on the properties of a substance or the results of an experiment.

Standard conditions in chemistry are considered to be a temperature of 298K (25°C), a pressure of 1 atm (101.3 kPa), and a concentration of 1 mol/L (for solutions).

Spontaneous reaction- A spontaneous reaction is one that proceeds without any external force or intervention. That is, a spontaneous reaction proceeds without the need for energy input from an external source. In other words, it is an exothermic reaction where the products are more stable than the reactants.

The Gibbs free energy change of a spontaneous reaction is negative. The sign of ΔG indicates the spontaneity of a reaction. A negative value indicates that the reaction is spontaneous, whereas a positive value indicates that the reaction is non-spontaneous. The value of ΔG° is used to determine the spontaneity of a reaction under standard conditions.

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